工矿商贸行业较大以上次生衍生事故分析研究

通过对2012~2015年6月全国工矿商贸行业发生的较大以上次生衍生事故行业分布、地域分布、时段分布、空间分布等特征的分析,归纳总结了次生衍生事故发生的规律和特点,根据事故致因理论,对次生衍生事故原因进行了分析,并提出对策措施,为降低工矿商贸次生衍生事故发生率、减少人员伤亡提供理论支撑。     

气质联用法测定空气中挥发性有机物的方法研究

通过美国Entech公司Summa罐采集大气样品,7100型大气预浓缩系统提取和富集样品中的挥发性有机物,省去了繁琐的有机物提取和净化工序,避免和有机溶剂接触,将样品直接输入气质联机进行分析。利用这种方法定性分析了某油罐区的大气成分．结果表明该地区大气中含有成分复杂的环己烷、苯和萘的衍生物,这些化合物的浓度远远大于居民区同类化合物的含量。     

分光光度法测定废水中草甘膦的探讨

探讨了亚硝基衍生化紫外分光光度法测定废水中草甘膦的适用性,考察了硫酸加入体积对亚硝化反应的影响,提出应根据样品碱度调整硫酸用量。方法与高效液相色谱法测定值的重现性较好,应用于实际废水中草甘膦测定的加标回收率为95%～105%,平行测定的RSD≤1.3%,检出限为0.069 mg/L,检测上限为50.0 mg/L,废水中可能存在的伯胺和叔胺类物质对测定无明显干扰。     

Larvicidal potential of different solvent extracts and oleanolic acid derivative from Coccinia indica against vector mosquitoes

The mosquito larvicidal activities of different solvent extracts (chloroform, ethyl acetate, and methanol) from the leaves of Coccinia indica were studied. Among the extracts tested, the methanol extract showed the highest larvicidal activity against early fourth instar larvae of Culex quinquefasciatus (LC₅₀?=?142?mg?L^?1), Aedes aegypti (LC₅₀?=?158?mg?L^?1) and Anopheles stephensi (LC₅₀?=?161?mg?L^?1) after 24?h of exposure period. The lowest larval mortality was observed with the ethyl acetate extract with the LC₅₀ values of 927, 872, and 730?mg?L^?1 against Cx. quinquefasciatus, Ae. aegypti, and An. stephensi, respectively. The chloroform extract showed the moderate larvicidal activity against the mosquito species tested with the LC₅₀ values from 446 to 546?mg?L^?1. A new triterpene was isolated from the methanol extract using bio-assay guided separation and identified as an oleanolic acid derivative by NMR, IR and mass spectral studies. The compound showed prominent larvicidal activity against Cx. quinquefasciatus, Ae. aegypti and An. stephensi with the LC₅₀ values of 5.6, 5.0, and 4.8?mg?L^?1, respectively. The results of the present investigation offer an opportunity for developing alternatives to rather expensive and environmentally hazardous organic insecticides.     

Metabolites of sulfur‐containing derivatives of the fungicides pentachloronitrobenzene and hexachlorobenzene in mammals,separated by capillary gas chromatography and identified by negative and positive Cl mass spectrometry

Biotransformation products of sulfur‐containing derivatives of pentachloronitro‐benzene and hexachlorobenzene in mammals, such as thiophenols, thioanisoles, phenols, anisoles and chlorinated benzenes have been identified by mass spectrometry of negative and positive ions produced by chemical ionisation. The capillary gas chromatograms of extracts from excreta of rats after application of N‐acetyl‐S‐(pentachlorophenyI)‐D,L‐cysteine, as well as of rabbits after application of S,S'‐(tetrachloro‐p‐phenylene)‐L,L'‐dicysteine, are shown.     

气质联用法测定空气中挥发性有机物的方法研究

通过美国Entech公司Summa罐采集大气样品,7100型大气预浓缩系统提取和富集样品中的挥发性有机物,省去了繁琐的有机物提取和净化工序,避免和有机溶剂接触,将样品直接输入气质联机进行分析。利用这种方法定性分析了某油罐区的大气成分,结果表明该地区大气中含有成分复杂的环己烷、苯和萘的衍生物,这些化合物的浓度远远大于居民区同类化合物的含量。     

考虑环保效益的混合产品提供策略稳定性研究

当前,中国制造产业面临污染能耗大、全球竞争优势递减、人口红利消失、产品日趋同质化和客户需求日益个性化等产业困境。随着《中国制造2025》对服务型制造理念的推动,以实物产品为载体,衍生与产品相匹配的服务,并与产品构成“混合产品”来解决客户问题的观点逐渐被诸多企业认同和实践。在混合产品提供过程中,考虑到节约资源、保护环境和预防污染,以及生产者责任延伸制下的政府约束,制造企业能否通过调整混合产品提供策略以削减上述顾虑并落实生产者责任延伸制的要求?本文在耦合生产者责任延伸制和混合产品理论的基础上,发现考虑环保效益的混合产品策略主要受政府、制造企业和客户决策行为的影响,籍此,构建了“政府-企业-客户”三方演化博弈模型,探讨各主体采取不同行为决策时策略的演化路径,并以共享电动汽车为例,验证本文模型,得到一些发现:客户支付意愿能促进策略实现,但促进作用边际递减,为此要求企业服务衍生把握深度和广度,并强调政府引导供需交互的重要性;策略稳定性受制造企业间接收益影响,而服务和环境元素对间接受益的影响更为显著;制造企业服务衍生和客户支付行为之间存在意愿平衡点,为政府制定适度性的扶持政策提供参考;潜在损失的增加促使企业和客户积极参与考虑环保效益的混合产品提供策略;政府参与度的增加促进客户价值创造效用边际递增。研究结论为制造企业在生产者责任延伸制下合理地提供混合产品,政府引导市场客户与激励制造企业方面的政策制定,客户对混合产品消费观念的重塑提供了建议与理论指导。     

玉米叶片光谱弱差信息的重金属污染定性分析

不同重金属污染下的玉米叶片光谱响应存在细微差异。设计不同浓度的铜（Cu）和铅（Pb）污染实验,并测量不同浓度铜离子和铅离子胁迫下玉米叶片的光谱反射率、Cu含量、Pb含量及对应叶绿素含量。针对光谱弱差信息甄别的难点,结合光谱微分处理、光谱角、正切函数增强和波谱分段检测等构建一种甄别玉米叶片Cu、Pb胁迫的分段微分光谱角正切（segmentation derivative spectral angle tangent,SDSAT）模型。甄别玉米叶片不同生长程度的玉米叶片在Cu、Pb胁迫下的光谱响应差异,并通过区分玉米冠层Cu、Pb胁迫光谱的差异以验证该模型有效可行。实验结果表明,SDSAT模型甄别Cu、Pb胁迫玉米光谱主要差异在“紫光”“红边”和“近峰B”波段区间,这些差异也是鉴别Cu、Pb污染的定性分析标志,并可以根据模型测度结果分析玉米的污染程度。     

导数在计算矩中的应用

本文主要研究了应用数学分析中导数知识来求解统计学中的二项分布,泊松分布,几何分布的一、二阶矩.将这种方法加以推广,我们又提出了利用高阶导数求出伽玛(Gamma)分布,指数分布,正态分布的高阶矩.     

Prenatal diagnosis of partial trisomy 12q: clinical presentations and outcome

We present a pregnant woman with a fetus prenatally diagnosed as 46, XY,der(4) t(4;12) (q35.1; q21.2). This defect resulted from the unbalanced segregation of a paternal balanced translocation, t(4;12) (q35.1; q21.2). Prenatal ultrasound revealed borderline ventriculomegaly, a thick nuchal fold, pericardial effusion, arthrogryposis, a single umbilical artery, and micropenis. Fluorescence in situ hybridization (FISH) with whole chromosome painting probe and microarray-based comparative genomic hybridization analysis further confirmed chromosomal gain of terminal 12q. The woman had her pregnancy terminated at 20 weeks of gestational age. When compared with previously reported cases, the proband had characteristics common to the phenotypes of partial trisomy 12q, including an abnormal facial appearance and multiple anomalies. Additionally, this case had previously unreported phenotypes, such as arthrogryposis, a single umbilical artery, and a micropenis. Regarding the outcome of partial trisomy 12q, the fetuses carrying trisomies distal to 12q24 have a good chance of extended postnatal survival. In contrast, the cases with trisomies involving a larger amount of 12q likely die prenatally or within a few days after birth. Copyright © 2005 John Wiley & Sons, Ltd.