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101.
TiO2光催化技术在有害气体净化中的应用 总被引:2,自引:0,他引:2
主要介绍了TiO2光催化技术在有害气体净化中的应用、提高TiO2光化效率的方法以及影响TiO2光催化效率的因素。 相似文献
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Ag/Al2O3催化剂用于碳氢化合物选择性还原NO 总被引:6,自引:1,他引:6
比较了富氧条件下CH4、C3H8、C3H6和C2H5OH分别用作还原剂时,NO在Ag/Al2O3催化剂上的还原活性.结果表明, CH4和C3H8还原NO的活性很低,而C3H6和C2H5OH能有效地还原NO.在此基础上,研究了H2O和SO2对C3H6和C2H5OH在Ag/Al2O3催化剂上还原NO活性的影响.结果表明,H2O的存在会降低低温区的NO还原活性,而且这种影响是可逆的.将H2O 和SO2同时加入反应混合气,引起NO还原活性较大幅度降低,结合程序升温脱附实验结果,认为可能是由于存在SO2时,Ag/Al2O3催化剂吸附NO的能力降低. 相似文献
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《环境科学学报(英文版)》2023,35(4):396-407
Based on the experimental and theoretical methods, the NO selective catalytic oxidation process was proposed. The experimental results indicated that lattice oxygen was the active site for NO oxide over the -MnO2(110) surface. In the theoretical study, DFT (density functional theory) and periodic slab modeling were performed on an -MnO2(110) surface, and two possible NO oxidation mechanisms over the surface were proposed. The non-defect -MnO2(110) surface showed the highest stability, and the surface Os (the second layer oxygen atoms) position was the most active and stable site. O2 molecule enhanced the joint adsorption process of two NO molecules. The reaction process, including O2 dissociation and O=N-O-O-N=O formation, was calculated to carry out the NO catalytic oxidation mechanism over -MnO2(110). The results showed that NO oxidation over the -MnO2(110) surface exhibited the greatest possibility following the route of O=N-O-O-N=O formation. Meanwhile, the formation of O=N-O-O-N=O was the rate-determining step. 相似文献
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Experimental data are presented to test and validate a kinetic model for the oxidation of 2-chlorophenol wastewater by photo-assisted Fenton process. The data showed that this process had produced good effects under acidic conductions. Up to 90% 2-chlorophenol was removed after 90-minute reaction time with H2O2 of 25% CODCr. in, while in UV/H2O2 system ordy 16.8% 2-chlorophenol was removed after one hour treatment. The optimal pH in this reaction occurred between pH 3.0 and pH 4.0. The reaction kinetics for photo-assisted Fenton process experimented in this research was investigated. Kinetic models were proposed for the treatment of 2-chlorophenol wastewater. The reaction was found to follow the 2nd order. The equations of reaction kinetics are as follows:-d[RH]/dt=KRH[RH][H2O2]0exp(-KH2o2t);-d[CODCr]/dt=KCODCr[CODCr][H2O2]0exp(-K′t).The prediction of the models was found to be in a good agreement with experimental results, thus confimfing the proposed reaction mechanism. 相似文献
109.
The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity. 相似文献
110.
磁性吸附材料CuFe2O4吸附砷的性能 总被引:10,自引:1,他引:10
根据Cu(Ⅱ)和Fe(Ⅲ)都对砷有较强的亲和性,制备了同时含有Cu(Ⅱ)和Fe(Ⅲ)的、可用磁分离方法进行分离回收的磁性吸附材料CuFe2O4,并对其进行了表征及吸附砷的性能研究.结果表明,该吸附剂对砷的吸附能力与溶液pH有关,在弱酸性及中性条件下,吸附砷的能力最强,而对As(V)的吸附能力比对As(Ⅲ)更强些,在平衡浓度为10μg/L时,其吸附容量可达10mg/g左右,可以很容易地将水中浓度为1~20mg/L的As(V)降到10μg/L以下.实验考察了几种无机阴离子对吸附砷的影响,表明较高浓度(砷浓度的20倍)的硫酸盐对As(Ⅲ)和As(V)的吸附均有一定影响,盐酸盐及磷酸盐则影响不明显;负载的As(V)可较容易地用0.1mol/L NaOH洗脱下来,使吸附剂再生,而As(Ⅲ)则难以洗脱,这与2种价态砷的吸附机理不同有关. 相似文献