特种膜分离在废乳化液处理上的应用

目前国内乳化液处理普遍采用化学加药破乳,再后续生化处理的工艺,该方法投加大量化学药剂,产生二次固体危废,综合处置成本高。采用荷兰B&C特种超滤膜技术对乳化液浓缩破乳回收基础油,超滤产水后续生化处理的新工艺路线具有很好的工艺先进性。通过工艺运行数据显示,含油率1%~3%的乳化液,经过特种超滤浓缩破乳后浓缩液含油率可达15%~20%,超滤产水含油率小于50mg/L,COD为15000~20000mg/L,后续经厌氧和A/O生化+Fenton氧化后出水小于500mg/L,达到处理标准。     

Modelling performance variabilities in oil spill response to improve system resilience

The Environmental Defense Centers (EDCs) of Brazil provide response services following oil spill accidents. EDCs near affected areas rapidly organize and execute emergency response activities in order to minimize the environmental and economic impacts of spills. The current research applied ergonomic principles and methods (interviews, direct observation and focus groups) to describe common EDC system operations, and to identify constraints and conflicting procedural practices. Results of ergonomic field studies were modeled and analyzed using the Functional Resonance Analysis Method (FRAM), which can show how functional variability in planning, preparedness, execution, resources, economic and human factors affect the quality of emergency response activities. The FRAM analyses provide guidance for improving the resilience of oil spill emergency response systems.     

油气田开发建设对土壤的影响与减缓措施

油气田开发和建设过程中排放的废水、废气和固体废物直接或间接进入土壤环境中,会对土壤生态系统产生影响,本文对油田开发污染物进入土壤的途径及其在土壤上吸附／解吸的规律的分析,提出相应的油田环境的保护和治理措施。     

Total Organic Carbon,an Important Tool in an Holistic Approach to Hydrocarbon Source Fingerprinting

The identification and allocation of multiple hydrocarbon sources in marine sediments is best achieved using an holistic approach. Total organic carbon (TOC) is one important tool that can constrain the contributions of specific sources and rule out incorrect source allocations in cases where inputs are dominated by fossil organic carbon. In a study of the benthic sediments from Prince William Sound (PWS) and the Gulf of Alaska (GOA), we find excellent agreement between measured TOC and TOC calculated from hydrocarbon fingerprint matches of polycyclic aromatic hydrocarbons (PAH) and chemical biomarkers. Confirmation by two such independent source indicators (TOC and fingerprint matches) provides evidence that source allocations determined by the fingerprint matches are robust and that the major TOC sources have been correctly identified. Fingerprint matches quantify the hydrocarbon contributions of various sources to the benthic sediments and the degree of hydrocarbon winnowing by waves and currents. TOC contents are then calculated using source allocation results from fingerprint matches and the TOCs of contributing sources. Comparisons of the actual sediment TOC values and those calculated from source allocation support our earlier published findings (Boehm et al ., 2001) that the natural petrogenic hydrocarbon background in sediments in this area comes from eroding Tertiary shales and associated oil seeps along the northern GOA coast and exclude thermally mature area coals from being important contributors to the PWS background due to their high TOC content.     

Tar Balls: The End State

Tar balls are frequently reported as an indicator of the extent of the impact of a spill incident. The determination of the density of tar balls is basic to the shoreline cleanup assessment team (SCAT) process, and is frequently used by the media as an indication of oil pollution. The processes involved in the evolution of tar balls are not well understood and there is a paucity of literature on the science of tar ball formation.     

过滤器处理含聚采油污水滤料流失及改进技术研究

为解决石英砂过滤器处理聚驱污水过程中出现的滤料板结、反冲洗憋压、滤料流失问题,通过对石英砂过滤器进行了改造,利用搅拌装置破碎滤饼层,经现场测试,搅拌式石英砂过滤器反冲洗压力由原来的0.27~0.46Mpa降低到0.12~0.16 Mpa,滤料流失得以解决。在来水含油和悬浮固体平均41 mg/L和21 mg/L,总滤后水质含油达到5.8 mg/L以下,出水悬浮固体3.2 mg/L。油和悬浮固体去除率分别提高85%和86%。     

水解曝气生物滤池处理含油废水的试验研究(水解段)

针对含石油废水的特点,采用"水解-曝气生物滤池"两段式工艺对大庆油田经过滤后的含油废水原水进行处理,考察了水解段的运行效果,确定了水解段工艺的最优工况,并对影响系统运行效果的主要因素进行了深入的试验研究和理论分析。     

废轮胎热解油脱色工艺研究

为解决废旧轮胎热解油颜色过深和存在异味而无法直接利用问题,文章采用活性炭对热解油吸附脱色工艺,将液相中含有的杂质、色素、异味等舍弃物吸附于活性炭表面上,以达到精致的目的。试验表明:热解油活性炭吸附脱色技术的最佳工艺条件为炭粒度550~1 700μm、脱色温度为室温、吸附时间为300 min、振荡频率为150 r/min。并证明了平2均孔径、中孔孔容积和中孔比表面积为26.4、0.307 m L/g和280 m/g的烟煤基活性炭对热解油具有很好的脱色能力。     

砂土液化的灰色综合评判

通过研究砂土液化的主要影响因子，建立了砂土液化的灰色综合评判理论模型，并成功地将 该理论模型应用于实际工程中。通过对２６个实例的评判和与实际液化结果的比较，说明了本文方法 对砂上液化评判的有效性。     

用陶瓷膜做滤材处理含油废水的研究

本实验是以无机膜之一的陶瓷做滤材，对含油污水处理进行研究．探讨了含油种类与膜的性质、含油浓度和透过速度的关系及反冲洗对透过速度的影响．通过实验证明：轻质油比重油的透过速度大；油水中含油浓度对透过浓度影响不大；反冲洗会使透过速度得到恢复；浊度去除率可达９６％以上，陶瓷膜超滤法处理含油废水是可行的．