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A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4. 相似文献
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Mehaffey MH Nash MS Wade TG Ebert DW Jones KB Rager A 《Environmental monitoring and assessment》2005,107(1-3):29-44
The Catskill/Delaware reservoirs supply 90% of New York City’s drinking water. The City has implemented a series of watershed protection measures, including land acquisition, aimed at preserving water quality in the Catskill/Delaware watersheds. The objective of this study was to examine how relationships between landscape and surface water measurements change between years. Thirty-two drainage areas delineated from surface water sample points (total nitrogen, total phosphorus, and fecal coliform bacteria concentrations) were used in step-wise regression analyses to test landscape and surface-water quality relationships. Two measurements of land use, percent agriculture and percent urban development, were positively related to water quality and consistently present in all regression models. Together these two land uses explained 25 to 75% of the regression model variation. However, the contribution of agriculture to water quality condition showed a decreasing trend with time as overall agricultural land cover decreased. Results from this study demonstrate that relationships between land cover and surface water concentrations of total nitrogen, total phosphorus, and fecal coliform bacteria counts over a large area can be evaluated using a relatively simple geographic information system method. Land managers may find this method useful for targeting resources in relation to a particular water quality concern, focusing best management efforts, and maximizing benefits to water quality with minimal costs.The United States Environmental Protection Agency through its Office of Research and Development funded and managed the research described here. It has been subjected to Agency’s administrative review and approved for publication as an EPA document. 相似文献
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Evaluation of Water Quality in the Chillán River (Central Chile) Using Physicochemical Parameters and a Modified Water Quality Index 总被引:4,自引:0,他引:4
Debels P Figueroa R Urrutia R Barra R Niell X 《Environmental monitoring and assessment》2005,110(1-3):301-322
The Chillán River in Central Chile plays a fundamental role in local society, as a source of irrigation and drinking water,
and as a sink for urban wastewater. In order to characterize the spatial and temporal variability of surface water quality
in the watershed, a Water Quality Index (WQI) was calculated from nine physicochemical parameters, periodically measured at
18 sampling sites (January–November 2000). The results indicated a good water quality in the upper and middle parts of the
watershed. Downstream of the City of Chillán, water quality conditions were critical during the dry season, mainly due to
the effects of the urban wastewater discharge. On the basis of the results from a Principal Component Analysis (PCA), modifications
were introduced into the original WQI to reduce the costs associated with its implementation. WQIDIR2 and WQIDIR, which are both based on a laboratory analysis (Chemical Oxygen Demand) and three (pH, temperature and conductivity), respectively,
four field measurements (pH, temperature, conductivity and Dissolved Oxygen), adequately reproduce the most important spatial
and temporal variations observed with the original index. They are proposed as useful tools for monitoring global water quality
trends in this and other, similar agricultural watersheds in the Chilean Central Valley. Possibilities and limitations for
the application of the used methodology to watersheds in other parts of the world are discussed. 相似文献
66.
汉江水质评价的化学计量学研究 总被引:4,自引:1,他引:4
运用因子分析法对汉江各主要水质断面进行水质因子分析及综合评价,通过各主因子的方差贡献及因子得分得出各水质因子的赋权值,从而对所取断面进行水质污染程度的综合评价、分析与排序。同时运用聚类分析法对汉江17个断面的水质污染相似性进行分析,给出分类处理结果。 相似文献
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测定电镀废水中铬(Ⅵ)的新光度法 总被引:3,自引:0,他引:3
在硝酸介质中,二甲基黄先显色而后在加热条件下褪色,铬( )能显著阻抑此褪色反应,且阻抑程度与铬( )含量相关,据此建立了测定痕量铬( )的新方法。方法检出限是1.55×10-10g/ml,线性范围0.1~1.2μg/10ml,用于电镀废水中铬( )的测定,结果满意。 相似文献