全文获取类型
收费全文 | 1544篇 |
免费 | 74篇 |
国内免费 | 396篇 |
专业分类
安全科学 | 95篇 |
废物处理 | 77篇 |
环保管理 | 136篇 |
综合类 | 777篇 |
基础理论 | 312篇 |
污染及防治 | 444篇 |
评价与监测 | 146篇 |
社会与环境 | 24篇 |
灾害及防治 | 3篇 |
出版年
2024年 | 1篇 |
2023年 | 13篇 |
2022年 | 26篇 |
2021年 | 39篇 |
2020年 | 37篇 |
2019年 | 41篇 |
2018年 | 37篇 |
2017年 | 48篇 |
2016年 | 53篇 |
2015年 | 49篇 |
2014年 | 69篇 |
2013年 | 186篇 |
2012年 | 104篇 |
2011年 | 135篇 |
2010年 | 85篇 |
2009年 | 105篇 |
2008年 | 95篇 |
2007年 | 109篇 |
2006年 | 114篇 |
2005年 | 90篇 |
2004年 | 57篇 |
2003年 | 86篇 |
2002年 | 56篇 |
2001年 | 43篇 |
2000年 | 57篇 |
1999年 | 39篇 |
1998年 | 42篇 |
1997年 | 37篇 |
1996年 | 37篇 |
1995年 | 28篇 |
1994年 | 27篇 |
1993年 | 28篇 |
1992年 | 15篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有2014条查询结果,搜索用时 31 毫秒
1.
在饮用水输配系统中,来源于管壁生物膜的有机物可能耗氯并生成消毒副产物(DBPs),包括二氯乙腈(DCAN)与二氯乙酰胺(DCAcAm)等高毒性含氮DBPs(N-DBPs).研究考察管网常见的细菌与其胞外聚合物(EPS)以及模拟管壁生物膜氯化与氯胺化后DCAN与DCAcAm的生成,并与天然有机物(NOM)和水源水有机物进行比较.结果显示,铜绿假单胞菌、恶臭假单胞菌与藤黄微球菌与氯反应生成的DCAN、DCAcAm浓度分别为1.48~2.02、0.21~0.38μg·mg~(-1)(mg~(-1)以TOC计),高于同反应条件下NOM的生成量;相比于氯化反应,3株细菌细胞氯胺化生成的DCAN与DCAcAm浓度明显更低.3株菌的EPS也是氯与氯胺化反应生成DCAN与DCAcAm的前体物,且其氯胺化反应生成的DCAcAm浓度高于氯化反应生成的.与NOM、水源水相比,模拟管壁生物膜氯化后生成的N-DBPs与三氯甲烷(TCM)浓度比更高,表明生物膜有机物比NOM与水源水有机物更倾向生成DCAN与DCAcAm类N-DBPs,且模拟管壁生物膜氯胺化的DCAcAm生成量高于氯化反应的,说明管壁生物膜有机物是供水管网系统中DCAN与DCAcAm类N-DBPs的重要前体物. 相似文献
2.
Few studies have been carried out to connect nutrient recovery as struvite from wastewater and sustainable utilization of the recovered struvite for copper and zinc immobilization in contaminated soil. This study revealed the effect of struvite on Cu and Zn immobilization in contaminated bio-retention soil in the presence of commonly exuded plant organic acids. The research hypothesis was that the presence of both struvite and organic acids may influence the immobilization of Cu and Zn in soil. The outcome of this research confirmed that more than 99% of Cu and Zn was immobilized in bio-retention filter media by struvite application. Water-soluble Cu and Zn concentrations of struvite treated soil were less than 1.83 and 0.86 mg/kg respectively, and these concentrations were significantly lower compared to the total Cu and Zn content of 747.05 mg/kg in the contaminated soil. Application of struvite to Cu- and Zn-contaminated soil resulted in formation of compounds similar to zinc phosphate tetrahydrate (Zn3(PO4)2?4H2O) and amorphous Cu and Zn phases. Struvite was effective in heavy metal remediation in acidic soil regardless of the presence of Ca impurities in struvite and the presence of plant organic acids in soil. Overall, this study revealed that struvite recovered from wastewater treatment plants has potential for use as an amendment for heavy metal remediation in contaminated bio-retention soil. 相似文献
3.
Sulphate leaching losses may reduce the long-term possibility of maintaining the S supply of crops in low input farming systems. The ability of catch crops (Italian ryegrass (Lolium multiflorum Lam), winter rape (Brassica napus L.) and fodder radish (Raphanus sativus L.)) to reduce soil sulphate concentrations in autumn and make it available to a succeeding crop was investigated in 1996–1998 on sandy loam soil in Denmark. All catch crops reduced soil sulphate concentrations in the autumn compared to bare soil. Especially, the cruciferous catch crops had the ability to deplete efficiently soil sulphate levels and thus, reduce the sulphate leaching potential. The S uptake in aboveground catch crop was 8, 22 and 36 kg S per ha for ryegrass, winter rape and fodder radish, respectively. In the following spring, sulphate levels of the autumn bare soil were low in the top 0.5 m and a peak of sulphate was found at 0.75–1 m depth. In contrast, where a fodder radish catch crop had been grown, high sulphate levels were present in the top 0.5 m, but only small amounts of sulphate were found at 0.5–1.5 m depth. In spring barley (Hordeum vulgare L.), that followed catch crops, S concentrations at heading and maturity revealed that the availability of soil S increased following winter rape and fodder radish, whereas there were indications that following ryegrass, the S availability was reduced compared to bare soil. This initial study showed that catch crops have a high potential for reducing sulphate leaching and may be used to synchronise S availability with plant demand in a crop rotation. 相似文献
4.
5.
通过田间试验,对装配GP-81扁扇型喷头的运5飞机在水稻和棉花上喷洒农药中的药液损失进行了分析,同时讨论了2,4-D丁酯对敏感作物的影响。结果表明,一元三次方程Y=b0+b1x2+b2x^2+b3x^3能很好地描述药液飘移与下风距离的关系,方程中的参数具有明确的实验意义;2,4-D丁酰对700m下风距离内的向日葵类高敏感植物有明显药害,对350m范围内的大豆等中等敏感植物也有药害;药液由于飘移和蒸 相似文献
6.
7.
8.
HydrolyticdynamicsofpesticideN'-(2,4-dimethylphenyl)-N-methylformamidineinaquaticsolution¥MoHanhong;YangKewu;AnFengchun;LiuYe... 相似文献
9.
10.
G.L. Feng J. Letey A.C. Chang M. Campbell Mathews 《Agriculture, ecosystems & environment》2005,110(3-4):219-229
Large scale dairy operations are common. In many cases the manure is deposited on a paved surface and then removed with a flushing system, after which the solids are separated, the liquid stored in ponds, and eventually the liquid applied on adjacent crop land. Management of liquid manure to maximize the fertilizer value and minimize water quality degradation requires knowledge of the interactive effects of mineralization of organic N (ON) to NH4+, crop uptake of mineral N, and leaching of NO3− on a temporal basis. The purpose of the research was to use the ENVIRO-GRO model to simulate how the amount of applied N, timing of N application, ON mineralization rates, chemical form of N applied, and irrigation uniformity affected (1) yields of corn (Zea mays) in summer and a forage grass in winter in a Mediterranean climate and (2) the amount of NO3− leached below the root zone. This management practice is typical for dairies in the San Joaquin Valley of California. The simulations were conducted for a 10-year period. Steady state conditions, whereby an equivalent amount of N applied in the organic form will be mineralized in a given year, are achieved more rapidly for materials with high mineralization rates. Both timing and total quantity of N application are important in affecting crop yield and potential N leaching. Major conclusions from the simulations are as follows. Frequent low applications are preferred to less frequent higher applications. Increasing the amount of N application increased both the crop yield and the amount of NO3− leached. Increasing irrigation uniformity increased crop yields but had variable effects on the amount of NO3− leached. A winter forage crop following a summer corn crop effectively reduced the leaching of residual soil N following the corn crop. 相似文献