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221.
222.
Kay Grossmann Thuro Arnold Robin Steudtner Stefan Weiss Gert Bernhard 《Die Naturwissenschaften》2009,96(8):963-974
Low-temperature alteration reactions on uranium phases may lead to the mobilization of uranium and thereby poses a potential
threat to humans living close to uranium-contaminated sites. In this study, the surface alteration of uraninite (UO2) and uranium tetrachloride (UCl4) in air atmosphere was studied by confocal laser scanning microscopy (CLSM) and laser-induced fluorescence spectroscopy using
an excitation wavelength of 408 nm. It was found that within minutes the oxidation state on the surface of the uraninite and
the uranium tetrachloride changed. During the surface alteration process U(IV) atoms on the uraninite and uranium tetrachloride
surface became stepwise oxidized by a one-electron step at first to U(V) and then further to U(VI). These observed changes
in the oxidation states of the uraninite surface were microscopically visualized and spectroscopically identified on the basis
of their fluorescence emission signal. A fluorescence signal in the wavelength range of 415–475 nm was indicative for metastable
uranium(V), and a fluorescence signal in the range of 480–560 nm was identified as uranium(VI). In addition, the oxidation
process of tetravalent uranium in aqueous solution at pH 0.3 was visualized by CLSM and U(V) was fluorescence spectroscopically
identified. The combination of microscopy and fluorescence spectroscopy provided a very convincing visualization of the brief
presence of U(V) as a metastable reaction intermediate and of the simultaneous coexistence of the three states U(IV), U(V),
and U(VI). These results have a significant importance for fundamental uranium redox chemistry and should contribute to a
better understanding of the geochemical behavior of uranium in nature.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
223.
针对煤化行业高含氮焦化污水,采用厌氧氨氧化工艺进行脱氮污泥培养、驯化,对可能制约厌氧氨氧化菌生长的因素进行研究分析。结果发现:得出适宜于厌氧氨氧化污泥培养的水力停留时间、温度、p H及为保持污泥活性要求限制反应器进水氨氮和亚硝酸盐氮的最大负荷值。 相似文献
224.
The formation and spray coating, with Degussa P25 titanium dioxide (TiO2), of a room temperature curable resin to form a photocatalytically active material is described in this paper. The TiO2 surface layers produced have been characteristed with the aid of scanning electron microscope analysis. The photocatalytic activity of the samples tested using a gas phase continuous flow type photoreactor, the test pollutant being propene. Analysis of the test results indicates the potential of TiO2 coated polymers to form effective photocatalytic materials, with the potential to improve indoor air quality and reduce the energy consumption of ventilation systems. 相似文献
225.
226.
Zecong Yu Keke Xiao Yuwei Zhu Mei Sun Sha Liang Jingping Hu Huijie Hou Bingchuan Liu Jiakuan Yang 《Frontiers of Environmental Science & Engineering》2022,16(6):80