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排序方式: 共有214条查询结果,搜索用时 62 毫秒
51.
为研究废弃印刷电路板(PCB)在回收加热拆解电子元件过程中所产生的气体排放物的主要成分,使用自行设计的废弃PCB拆解装置进行拆解实验,采用傅里叶红外光谱(FTIRS)、气相色谱-质谱(GC/MS)、离子色谱(IC)和电感耦合等离子体质谱(ICP-MS)等分析方法,对实验过程所收集到的气体产物进行成分分析.结果表明,废弃PCB的基板在加热过程中发生了初步分解,基板上的溴化环氧树脂发生了O—C、C—C、C—Br键的断裂,产生了苯酚、2,6-二溴苯酚等有机物;伴随有机气体逸出的还有废弃PCB在加热过程所释放的含有大量S、N、Cl、Br等元素的无机酸性气体;而连续的熔锡过程还使得PCB与焊料中的Sn、Pb、Sb、Hg、Cd、Cr等重金属产生烟尘逸出. 相似文献
52.
Shunli Zhang Eric Forssberg Bo Arvidson William Moss 《Resources, Conservation and Recycling》1998,23(4):225-241
The amount of electronic scrap which contains a substantial portion of non-ferrous metals, primarily copper and aluminum, has been growing. The present study is directed toward aluminum recovery by a newly developed eddy current separator. The investigation on shredded personal computer and printed circuit board scrap demonstrates that the High-Force® eddy-current separator will be applicable for this purpose. It has been shown that, by a single pass of the materials on the High-Force® eddy-current separator, an aluminum concentrate out of personal computer scrap can be obtained with a purity of 85%, while maintaining a recovery in excess of 90%, with the feed rate being up to 0.3 kg/min. 相似文献
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Non‐ortho substituted polychlorinated biphenyl (PCB) congeners can account for the majority of the dioxin‐like toxicity in environmental samples, yet analysis for these congeners is difficult because other PCB congeners co‐elute with them in most Chromatographic methods. An automated method was developed which incorporates a porous graphitic carbon (PGC) column which is commercially available. Non‐ortho substituted congeners were successfully separated from interfering PCB congeners. Recoveries of non‐ortho substituted congeners were consistently reproducible (CV < 9%) when chicken eggs were fortified with individual congeners. 相似文献
57.
Roman Schoula Jana Hajšloviá Pavel Gregor Vladimir Kocourek Vladimir Bencko 《毒物与环境化学》2013,95(1-2):263-274
The persistence of lipophilic organochlorine substances leads to their incorporation into the food chain and subsequent uptake by humans. Due to their use in the past, Czech and Slovak countries belong to the countries with a relatively high body burden of organochlorines. Levels of PCBs in human tissues based on the congener‐specific analysis are reported in this paper. Samples were analysed for the most abundant PCB congeners. Prevalent persistent organochlorine pesticides and their isomers/metabolites have also been included. The present study is focused on following areas: i) distribution of analysed substances in the various human tissue samples from selected regions of the Czech and Slovak Republic and ii) comparison with the results from other foreign and local studies. 相似文献
58.
将传统的中和法和絮凝法相结合,采用中和—絮凝法回收硝酸型褪锡废水中的锡,考察了反应终点体系pH、碱液浓度、絮凝剂浓度等因素对锡回收效果的影响。实验结果表明,在NaOH溶液浓度为6 mol/L、反应终点体系pH为0.8、聚丙烯酰胺溶液质量浓度为3 g/L的工艺条件下,可得到干基锡含量54.6%(w)的高品位锡泥。与传统的单一中和/絮凝法相比,采用中和—絮凝法不仅可以有效提高生产效率,而且减少了碱液和絮凝剂用量,回收锡之后体系中大量的硝酸可进一步回收利用。 相似文献
59.
我国正在研制专用于销毁高浓度多氯联苯(PCBs)的焚烧炉,主要处理废旧的含(PCBs)的电力电容器和变压器,应用可靠准确的监测方法测定了试验性焚烧炉渣、烟灰排气和废水中的二口恶口英(dioxins),类二口恶口英多氯联苯(dioxinlikePCBs)和PCBs含量,结果表明该炉试烧高浓度PCBs时,焚毁率可以达到99.9999%,炉渣中的2,3,7,8TCDD毒性当量为87.86pgTEQ/g,烟灰中残留二口恶口英和类二口恶口英的总2,3,7,8TCDD毒性当量为47.23ngTEQ/g. 相似文献
60.
Twenty-four congeners of polychlorinated biphenyls (PCBs) were measured in 83 air samples and 20 elastic sealants samples of apartments with PCB-containing sealants. In addition, PCBs were measured in 21 air samples from reference apartments located in an uncontaminated section of the same estate. The PCBtot levels in the air of the contaminated section were 168-3843 ng m−3 (mean: 1030 ng m−3), while the mean levels in the reference apartments were 6.03 ng m−3. The sum of the 24 measured PCB congeners in sealants from the contaminated section was 187-221 680 mg kg−1. Principal component analysis revealed four groups among the sealant samples with different congener compositions, only two of which were clearly similar to known PCB mixtures, while two were not. Significant correlations and intercorrelations were observed between the lower chlorinated congeners in air and sealant, e.g. for PCB 28air and 28seal (p = 0.04) and for PCB 28air and 52air, 52seal. However, no correlation was observed between the lower chlorinated congeners and the sums of PCB (∑PCB6 or ∑PCB24) or the higher chlorinated congeners. Analysis of air concentrations in relation to questionnaire data indicated that the indoor air levels could be reduced by increased cleaning and airing frequencies. 相似文献