Importance of the National Petroleum Reserve–Alaska for Aquatic Birds

We used data from aerial surveys (1992–2010) of >100,000 km² and ground surveys (1998–2004) of >150 km² to estimate the density and abundance of birds on the North Slope of Alaska (U.S.A.). In the ground surveys, we used double sampling to estimate detection ratios. We used the aerial survey data to compare densities of birds and Arctic fox (Vulpes lagopus), the major nest predator of birds, on the North Slope, in Prudhoe Bay, and in nearby areas. We partitioned the Prudhoe Bay oil field into 2 × 2 km plots and determined the relation between density of aquatic birds and density of roads, buildings, and other infrastructure in these plots. Abundance and density (birds per square kilometer) of 3 groups of aquatic birds—waterfowl, loons, and grebes; shorebirds; and gulls, terns, and jaegers—were highest in the National Petroleum Reserve–Alaska (NPRA) and lowest in the Arctic National Wildlife Refuge. Six other major wetlands occur in the Arctic regions of Canada and Russia, but the largest population of aquatic birds was in the NPRA. Aquatic birds were concentrated in the northern part of the NPRA. For example, an area that covered 18% of the NPRA included 53% of its aquatic birds. The aerial surveys showed that bird density was not lower and fox density was not higher in Prudhoe Bay than in surrounding areas. Density of infrastructure did not significantly affect bird density for any group of species. Our results establish that the NPRA is one of the most important areas for aquatic birds in the Arctic. Our results and those of others also indicate that oil production, as practiced in Prudhoe Bay, does not necessarily lead to substantial declines in bird density or productivity in or near the developed areas. Prioridades para la Conservación de Aves en el Norte de Alaska     

Differences in physical properties and CO2 gasification reactivity between coal char and petroleum coke

This paper mainly investigated the physical properties and gasification reactivity of coal char and petroleum coke, separately at the high temperature pyrolysis (950–1400 °C) with slow heating rate and pyrolysis pressure of the atmospheric pressure and at the pressurized pyrolysis (the atmospheric pressure to 3 MPa) with rapid heating rate and the pyrolysis temperature of 950 °C. Some significant differences in those between coal chars and petroleum coke were found. The high temperature pyrolysis caused more easily the graphitization of petroleum coke than that of coal char, especially in the higher temperature range. The increasing pyrolysis temperature resulted in the decrease of surface areas of coal char and the increase of surface areas of petroleum coke. As the pyrolysis pressure was elevated from the atmospheric pressure to 3 MPa, surface areas of petroleum coke initially increased and then decreased, while those of coal chars presented an opposite tendency. The increasing pyrolysis temperature was adverse to the gasification activity of coal chars and was favorable for the gasification activity of petroleum coke. Also, the effects of the pyrolysis pressure on the gasification activity of coal char and petroleum coke were significantly different. The gasification activity of petroleum coke was obviously lower than that of coal chars, and even lower than that of the natural graphite.     

Recovery of different waste vegetable oils for biodiesel production: A pilot experience in Bahia State,Brazil

In Brazil, and mainly in the State of Bahia, crude vegetable oils are widely used in the preparation of food. Street stalls, restaurants and canteens make a great use of palm oil and soybean oil. There is also some use of castor oil, which is widely cultivated in the Sertão Region (within the State of Bahia), and widely applied in industry. This massive use in food preparation leads to a huge amount of waste oil of different types, which needs either to be properly disposed of, or recovered. At the Laboratorio Energia e Gas-LEN (Energy & Gas lab.) of the Universidade Federal da Bahia, a cycle of experiments were carried out to evaluate the recovery of waste oils for biodiesel production. The experiences were carried out on a laboratory scale and, in a semi-industrial pilot plant using waste oils of different qualities. In the transesterification process, applied waste vegetable oils were reacted with methanol with the support of a basic catalyst, such as NaOH or KOH. The conversion rate settled at between 81% and 85% (in weight). The most suitable molar ratio of waste oils to alcohol was 1:6, and the amount of catalyst required was 0.5% (of the weight of the incoming oil), in the case of NaOH, and 1%, in case of KOH.The quality of the biodiesel produced was tested to determine the final product quality. The parameters analyzed were the acid value, kinematic viscosity, monoglycerides, diglycerides, triglycerides, free glycerine, total glycerine, clearness; the conversion yield of the process was also evaluated.     

GC × GC--A New Analytical Tool For Environmental Forensics

Comprehensive two-dimensional gas chromatography, GC 2 GC, is a new analytical tool with a tremendous capability to separate and identify organic compounds in complex environmental samples. GC 2 GC uses two different chromatography columns coupled serially by a modulator to produce a volatility by polarity separation and distribute compound peaks across a two-dimensional retention time plane. The two-dimensional separation produces an order of magnitude more resolved peaks than traditional GC methods. The grouping or ordering of the peaks in the GC 2 GC chromatogram facilitates the identification of unknown compounds and the comparison of complex environmental samples. When a mass spectrometer detector is used, each resolved GC 2 GC peak yields a single-component, interference-free mass spectrum that leads to accurate matching with mass spectral libraries. GC 2 GC examination of marine sediment extracts identified a wide variety of chemical contaminants including polychlorinated biphenyls, p -nonylphenol isomers, polycyclic aromatic hydrocarbons, benzotriazoles, and the alkane, cycloalkane, alkylbenzene, alkylnaphthalene, and biomarker fractions of petroleum. The two-dimensional GC 2 GC chromatogram image permits rapid screening of the sediment extracts for these and other unknown contaminants.     

Optimization of biodiesel production from the waste cooking oil using response surface methodology

In this research, transesterification of the waste cooking oil has been studied. Response surface methodology (RSM) based on Box–Behnken design was used to investigate the effects of the main operating parameters, including the methanol to oil molar ratio, catalyst concentration, and reaction temperature, on the biodiesel yield. The results revealed that the catalyst concentration is the most important parameter. The maximum biodiesel yield under the optimized conditions was 99.38 wt.%. Thermogravimetric analysis (TGA) was used for the determination of biodiesel conversion and the results were compared with that of gas chromatography (GC) analysis, showing a very small difference. Furthermore, an empirical quadratic equation has been presented to show the relation between biodiesel conversion and product viscosity.     

石油野外作业工人体力劳动强度分级调查

据ＧＢ３８６９—８３标准对江汉油田测量、地震、钻井、井下四类野外作业３４名工人、２４个工种进行了体力劳动强度分级调查，其结果：测量作业为Ⅰ～Ⅱ级；钻井作业Ⅱ级占５／８，Ⅲ级占１／４；井下作业Ⅲ级占２／３；地震作业Ⅲ、Ⅳ级各占４／９、２／９。说明前两类基本属中等强度劳动，后两类大部分属重强度劳动。     

我国石油消费现状及其战略思考

石油是支撑经济发展和国防现代化的基本能源之一。在当今国际社会中 ,石油已成为世界政治、经济、军事和外交斗争的特殊武器 ,成为一国经济发展、社会稳定以及国家安全的重要保障条件。我国目前石油供需形势严峻 ,主要表现为 :石油储量接替准备不足 ,老油田稳产面临严峻形势 ;需求增长过快 ;对外依存度较高 ;运输和贮存能力较小等方面。石油的安全及其保障问题关系到我国的经济安全和国家安全 ,因此 ,有必要研究我国的石油消费现状及发展战略。笔者针对我国的石油消费现状 ,分析了目前我国石油战略中存在的问题 ,探讨了我国的石油战略。     

HSE管理体系的实践、问题与对策研究

介绍了HSE管理体系的概念和内涵及中国石油天然气集团公司 (CNPC)实施HSE管理体系的概况。分析了目前CNPC实施HSE管理体系所遇到的主要问题 ,其中包括观念问题、组织问题和技术问题。并针对这些问题提出了相应的解决思路和措施 ,其中包括 :管理层观念的确立 ,对职工持续的教育 ,对技术的重视以及对现有组织制度有碍于HSE实施的部分进行改革。     

油气田废水中石油类物质测定问题的探讨

本文针对油气田废水复杂多样的特点，对石油类物质测定方法的选择；标准油品的选定以及难萃取样品的处理方法等监测技术问题进行了探讨，旨在提高监测数据的准确性及可靠性。     

Wind energy development in California,USA

Windfarms have been developed rapidly in California in the last few years. The impetus has been a legislated goal to generate 10% of California's electricity by windpower by the year 2000, and generous state and federal tax incentives. Windpower is promoted as environmentally benign, which it is in traditional uses. The California program, however, is not traditional: it calls for centralized development of a magnitude sufficient to offset significant amounts of fossil fuels now used to generate electricity.Centralized windfarm development, as exemplified by the Altamont Pass, Tehachapi Mountains, and San Gorgonio Pass developments, involves major road building projects in erosion-sensitive terrain, effective closure of public lands, and other detrimental effects. A windfarm consisting of 200 turbines with 17-m rotors located in steep terrain 16 km from an existing corridor might occupy 235 ha and physically disturb 86 ha. With average annual wind speeds of 22.5 km/h, the farm would generate about 10×10⁶ kWh/year at present levels of capacity. This annual production would offset 1% of one day's consumption of oil in California. To supply 10% of the state's electricity (at 1984 production rates) would require about 600,000 turbines of the type in common use today and would occupy more than 685,000 ha. It is likely that indirect effects would be felt in much larger areas and would include increased air and water pollution resulting from accelerated erosion, degradation of habitat of domestic and wild animals, damage to archaeological sites, and reduction of scenic quality of now-remote areas of the state.