示踪实验确定河流纵向离散系数的单纯形加速法

应用单纯形加速法结合实例求出福建闽江干流富屯溪洋口段纵向离散系数ＤＬ＝２．６２ｍ＾３／ｓ。研究结果表明,该法用于估计非线性模型参数优于“非线性逼近法”。由于单纯形法寻优过程不需要计算目标函数的偏导数,不受模型复杂程度的限制,因而计算简便,可广泛应用于环境,生态模型的拟合和参数估计。     

Identification Model of Pollutant Sources and Total Emission Control

提出了建立污染物来源的识别模式的初步设想。论述了如何应用该模式进行污染物排放总量控制的监督管理和检验总量控制中负荷分配的合理性。为加强环境管理工作提供了一条新的思路。      

Evaluation of the effect of meteorological data resolution on Lagrangian particle dispersion simulations using the ETEX experiment

This paper presents results from a series of numerical experiments designed to evaluate operational long-range dispersion model simulations, and to investigate the effect of different temporal and spatial resolution of meteorological data from numerical weather prediction models on these simulations. Results of Lagrangian particle dispersion simulations of the first tracer release of the European Tracer Experiment (ETEX) are presented and compared with measured tracer concentrations. The use of analyzed data of higher resolution from the European Center for Medium-Range Weather Forecasts (ECMWF) model produced significantly better agreement between the concentrations predicted with the dispersion model and the ETEX measurements than the use of lower resolution Navy Operational Global Atmospheric Prediction System (NOGAPS) forecast data. Numerical experiments were performed in which the ECMWF model data with lower vertical resolution (4 instead of 7 levels below 500 mb), lower temporal resolution (12 h instead of 6 h intervals), and lower horizontal resolution (2.5° instead of 0.5°) were used. Degrading the horizontal or temporal resolution of the ECMWF data resulted in decreased accuracy of the dispersion simulations. These results indicate that flow features resolved by the numerical weather prediction model data at approximately 45 km horizontal grid spacing and 6 h time intervals, but not resolved at 225 km spacing and 12 h intervals, made an important contribution to the long-range dispersion.     

常州市老城区水体有机污染分布特征及原因初探

为了老城区河道的合理整治,采用总有机碳（TOC）分析仪对常州市老城区3条河流及区域内浅层地下水的14个采样点水样进行3个月的总有机碳含量检测。老城区水环境受到不同程度的有机污染,某些地下水的TOC含量高于地表水,原因为地表水补给地下水,且老城区水体污染源主要来源于周边地区的生活污水,并受到关河、雨水等的影响,这为常州市老城区水污染治理提供了依据。     

线源扩散的快速模拟

提出了一种计算风向与线源成任意角时任意长地面线源大气扩散的简化模式。通过与数值积分方法计算结果的比较表明,模式的最大相对误差在风向与线源平行时最大,但不超过18％。随风向与线源夹角的增大,相对误差迅速减小,当夹角大于5°时,已小于2％。为城镇公路网大气扩散的快速、准确模拟提供了新手段。     

Dual-reaction-center catalytic process continues Fenton’s story

• Dual-reaction-center (DRC) system breaks through bottleneck of Fenton reaction. • Utilization of intrinsic electrons of pollutants is realized in DRC system. • DRC catalytic process well continues Fenton’s story. Triggered by global water quality safety issues, the research on wastewater treatment and water purification technology has been greatly developed in recent years. The Fenton technology is particularly powerful due to the rapid attack on pollutants by the generated hydroxyl radicals (•OH). However, both heterogeneous and homogeneous Fenton/Fenton-like technologies follow the classical reaction mechanism, which depends on the oxidation and reduction of the transition metal ions at single sites. So even after a century of development, this reaction still suffers from its inherent bottlenecks in practical application. In recent years, our group has been focusing on studying a novel heterogeneous Fenton catalytic process, and we developed the dual-reaction-center (DRC) system for the first time. In the DRC system, H₂O₂ and O₂ can be efficiently reduced to reactive oxygen species (ROS) in electron-rich centers, while pollutants are captured and oxidized by the electron-deficient centers. The obtained electrons from pollutants are diverted to the electron-rich centers through bonding bridges. This process breaks through the classic Fenton mechanism, and improves the performance and efficiency of pollutant removal in a wide pH range. Here, we provide a brief overview of Fenton’s story and focus on combing the discovery and development of the DRC technology and mechanism in recent years. The construction of the DRC and its performance in the pollutant degradation and interfacial reaction process are described in detail. We look forward to bringing a new perspective to continue Fenton’s story through research and development of DRC technology.     

Accident consequence calculation of ammonia dispersion in factory area

With the widespread use of ammonia in the process industry, more and more accidents were caused by ammonia leakage and dispersion. The dispersion of ammonia is determined by its physical properties, release source conditions and atmospheric environment. Full-scale numerical simulation based on CFD theory was carried out to study the dispersion law of ammonia in a food factory. It was found that ammonia concentrated on the symmetric plane and showed an upward movement near the source. Moreover, the effect of pressure on the dispersion of ammonia was explored showing that the concentration of ammonia near the source increased with the increase of pressure, while the dispersion of ammonia far from the source is mainly influenced by wind field. Last but not the least, the dangerous area completely covers the obstacle region according to the harmful concentration, but the lethal concentration range and explosion range both only existed near the release source. Correspondingly, the concentration of ammonia in the region far from the symmetric plane can be regarded as a safe area. When the accident happens, one should stay away from the release source and evacuate towards the sides in a timely manner. We hope that this work can provide an effective method in predicting the impact of ammonia dispersion and can arouse concerns over the public safety.     

On the non-monotonic wind influence on flammable gas cloud from CFD simulations for hazardous area classification

Hazardous areas are defined as a result of a variety of variables as storage temperature, pressure, leak orifice size, physical properties of flammable substance, and wind characteristics. The potential formation of an explosive atmosphere must be accurately assessed to ensure process safety. Therefore, computational fluid dynamics (CFD) arises as an important tool for accurate predictions as recommended by the international standard IEC 60079-10-1 (2015). This study aims to analyze the influence of wind velocity magnitude and direction on the hazardous area classification. The authors evaluated the extent and volume for methane, propane, and hydrogen leakages from a CFD model. For each flammable gas, the wind velocity magnitude and direction were regularly varied. The outcomes show that the behavior of the plume size as the wind varies mainly depends on the gas concentration. Counter-flow wind directions lead to zero relative velocity closer to the release point, which concentrates the gas, and wind in the release direction promotes a higher dilution of the gas cloud increasing the hazardous extent while decreases the volume. As a consequence, the wind also influences the zone type, which was accurately predicted from CFD simulations and significant differences were found when compared to the standard analyses. These differences are, to some extent, related to the consideration of wind velocity effects on the gas jet release.     

基质固相分散-快速溶剂萃取-GC/MS法同时测定土壤中有机氯农药和多环芳烃

建立了基质固相分散-ASE提取-GC/MS法同时测定土壤中8种有机氯农药和16种多环芳烃的方法。对方法的线性、检出限、精密度、回收率及土壤质控样品进行了分析,结果表明,8种有机氯农药和16种多环芳烃线性良好,相关系数为0.997 5～0.999 8,方法检出限为0.39～1.57μg/kg,空白加标样品的相对标准偏差小于20%,实际土壤样品加标回收率为60.6%～125%,土壤质控样品结果均在范围内。该方法能够满足土壤中8种有机氯农药和16种多环芳烃的检测要求。     

四川省出川断面主要污染物通量及来源研究

以2001～2007年实测水文、水质数据为基础,计算了四川省主要出川断面高锰酸盐指数(CODMn)和氨氮(NH3-N)污染负荷通量;利用断面水质目标约束,通过污染负荷历时曲线,分析了区域水环境承载力;在基流分割的基础上,利用水文分割法,识别了区域污染物的主要来源,为从源头上开展三峡水库水环境保护提供数据支撑。分析结果表明,各出川断面干流主要污染物(CODMn、NH3-N)大致在可接受的范围内,2001年以来,出川断面CODMn通量呈降低的趋势,有效的减缓了输入三峡库区的污染物总量,氨氮通量整体稳定。嘉陵江、涪江、渠江流域污染物来源主要为非点源,应重点加强面源的污染防控;长江干流为点面源混合型,简单的削减点源已不能保证高功能水体要求,应加强点源和面源污染的综合防控。