酒石酸钾钠溶液对氨氮标准曲线的影响

通过对酒石酸钾钠溶液存放时间和保存条件的跟踪试验,发现该试剂的存放时间越长,绘制的氨氮标准曲线的截距就越大;并分析了在绘制氨氮标准曲线时显色液易浑浊和截距常常偏大的原因;就此提出了酒石酸钾钠溶液的有效期和保存方法,以进一步提高氨氮测定的准确度。     

Comparison of airborne and terrestrial gamma spectrometry measurements - evaluation of three areas in southern Sweden

The Geological Survey of Sweden (SGU) has been conducting airborne gamma spectrometry measurements of natural radioactivity in Sweden for more than 40 years. Today, the database covers about 80% of the country’s land surface. This article explores the first step of putting this data into use in radioactive source search at ground level. However, in order to be able to use the airborne background measurements at ground level, SGU data must be validated against terrestrial data. In this work, we compare the SGU data with data measured by a portable backpack system. This is done for three different areas in southern Sweden. The statistical analysis shows that a linear relationship and a positive correlation exist between the air and ground data. However, this linear relationship could be revealed only when the region possessed large enough variations in areal activity. Furthermore, the activity distributions measured show good agreement to those of SGU. We conclude that the SGU database could be used for terrestrial background assessment, given that a linear transfer function is established.     

苯酐生产氧化反应器组火灾爆炸危险性分析与对策

为预防苯酐生产中最危险部位氧化反应器组发生火灾、爆炸事故 ,详细分析了苯酐生产中氧化反应器组各部位的火灾、爆炸危险性 ,在危险性分析基础上 ,提出了可行的安全对策与措施 ,对苯酐装置的安全生产和管理具有重要的指导意义和参考价值     

钙钛矿CaFeO_3光催化降解大红染料废水性能的研究

用柠檬酸络合法制备钙钛矿型复合氧化物CaFeO3,并以其为光催化剂对水溶性染料进行光催化降解实验。讨论了光催化反应时间、催化剂投加量、光照强度、pH值、以及外加氧化剂(H2O2)等因素对光催化活性的影响。实验结果表明:在催化剂投加量0.4g,降解时间180min,pH值2,光照强度200W,H2O2的投加量5mL时,大红染料的降解率可达99.83%。     

污水处理厂电耗分析与控制

通过对焦作污水处理厂处理工艺特点的研究,分析了其电耗的组成和重点,提出了主要耗电环节的节电措施．每月节约电费12万元。     

Trophic mode and organics metabolic characteristic of fungal community in swine manure composting

Fungal trophic modes and substrates utilization ability was observed in composting. Fungi had the higher diversity and more trophic types in thermophilic phase. Fungi had the higher metabolic potential in fresh swine manure and mature production. Redox potential, organics and moisture are main factors impacting fungal community. Composting reduced pathogenic fungi and enrich dung saprotroph fungi in swine manure. The succession of fungal community, trophic mode and metabolic characteristics were evaluated in 60 days composting of swine manure by high-throughput sequencing, FUNGuild and Biolog method, respectively. The result showed that the fungal community diversity reached to the highest level (76 OTUs) in the thermophilic phase of composting, then sustained decline to 15 OTUs after incubation. There were 10 fungal function groups in the raw swine manure. Pathotroph-saprotroph fungi reached to 15.91% on Day-10 but disappeared on Day-60. Dung saprotroph-undefined saprotroph fungi grown from 0.19% to 52.39% during the treatment. The fungal community had more functional groups but the lower substrate degradation rates in the thermophilic phase. The fungal communities on Day-0 and Day-60 had the highest degradation rates of amino acids and polymers, respectively. Redundancy analysis showed that ORP (49.6%), VS/Ash (45.3%) and moisture (39.2%) were the main influence factors on the succession of fungal community in the swine manure composting process.     

含氰废水的氧化处理

介绍了处理含氰废水碱氯氧化法、双氧水氧化法、臭氧氧化法等几种氧化法的基本原理，并进行了对比分析。     

Arsenic removal from water employing heterogeneous photocatalysis with TiO2 immobilized in PET bottles

Arsenic oxidation (As(III) to As(V)) and As(V) removal from water were assessed by using TiO₂ immobilized in PET (polyethylene terephthalate) bottles in the presence of natural sunlight and iron salts. The effect of many parameters was sequentially studied: TiO₂ concentration of the coating solution, Fe(II) concentration, pH, solar irradiation time; dissolved organic carbon concentration. The final conditions (TiO₂ concentration of the coating solution: 10%; Fe(II): 7.0 mg l⁻¹; solar exposure time: 120 min) were applied to natural water samples spiked with 500 μg l⁻¹ As(III) in order to verify the influence of natural water matrix. After treatment, As(III) and total As concentrations were lower than the limit of quantitation (2 μg l⁻¹) of the voltammetric method used, showing a removal over 99%, and giving evidence that As(III) was effectively oxidized to As(V). The results obtained demonstrated that TiO₂ can be easily immobilized on a PET surface in order to perform As(III) oxidation in water and that this TiO₂ immobilization, combined with coprecipitation of arsenic on Fe(III) hydroxides(oxides) could be an efficient way for inorganic arsenic removal from groundwaters.