基于GJB 150A-2009的高温试验方法研究

介绍了GJB 150换版后的基本信息,以图表形式给出了高温对装备的影响及比重。对GJB150A-2009中的高温试验方法及剪裁指南进行了研究,对高温试验应用要点进行了分析,并以某型号电子装备为例,建立了其寿命期剖面和寿命期环境剖面。     

土壤中重金属检测样品前处理技术现状分析

土壤中重金属检测样品前处理是一个复杂且关键的步骤,对最终分析结果有重要的影响。文章对目前主要采用湿法消解(盐酸-硝酸-高氯酸-氢氟酸、王水/王水回流、反王水)、干灰化法消解与微波消解技术及其现状进行介绍,指出其各自的优势与存在问题,为土壤中重金属检测样品前处理技术的进一步探索研究提供参考。     

超高斯（分布）随机振动HALT试验剖面建立要点解析

本文介绍了超高斯（分布）随机振动HALT技术,对超高斯（分布）随机振动HALT试验剖面的建立提出了方法和建议,主要包括试验顺序的选择、应力强度的确定、步进量级的选择、驻留时间确定和试验停止原则等五方面,并总结了现场试验的要求和注意事项。     

振动试验中常见问题的分析

振动试验是装备环境试验不可缺少的部分,本文分析了试验条件的制定、试验夹具的设计和试验样品安装等振动试验中比较重要的环节,提出了振动试验实施过程中常见的几个问题,并结合实际操作经验给出了解决方案。     

The toxicity of composted sediments from Mediterranean ports evaluated by several bioassays

This work investigates the ecotoxicological evaluation of contaminated dredged sediments from French Mediterranean navy harbour (A), commercial port (B) and two composite specimens (C) and (D) coming from the mixture of A and B with other port sediments. The toxicity of elutriates from these sediments is estimated using embryo-toxicity test, Microtox® solid phase test, LuminoTox, phytotoxicity tests and genotoxicity test. Bioassay responses are not clearly correlated with chemical contamination in the whole sediment and vary as a function of tested organisms. The highest contaminated samples (A and C) are almost always more toxic than the less contaminated samples (B and D). Among composite sediments, the mixture effect with other sediments is not efficient to decrease toxicity in sample C, suggesting that other parameters influence toxicity level such as particle size or organic matter content. These parameters should be taken into consideration in order to improve the efficiency of the mixture process and produce composite sediments with low toxicity.     

一种采用可控复合技术的新型升温炉

在普通电加热炉的基础上,通过配备液化燃烧器加热装置,开发了一种可同时实施自动控制电加热和燃气加热复合升温的新型装配式试验炉。试验测试表明,该新型复合式升温方法能够很好地模拟ISO-834标准升(降)温曲线,同时具有电炉安全可靠、测控精度高、操作简便、无污染,以及液化气火焰升温快、容易控制并可真实模拟火灾的优点,因而具有良好的试验效果和经济效果,是一种实用的结构抗火试验设施。     

In-vivo passive sampling to measure elimination kinetics in bioaccumulation tests

The application of in-tissue passive sampling to quantify chemical kinetics in fish bioconcentration experiments was investigated. A passive sampler consisting of an acupuncture needle covered with a PDMS tube was developed together with a method for its deployment in rainbow trout. The time to steady state for chemical uptake into the passive sampler was >1 d, so it was employed as a kinetically limited sampler with a deployment time of 2 h. The passive sampler was employed in parallel with the established whole tissue extraction method to study the elimination kinetics of 10 diverse chemicals in rainbow trout. 4-n-nonylphenol and 2,4,6-tri-tert-butylphenol were close to or below the limit of quantification in the sampler. For chlorpyrifos, musk xylene, hexachlorobenzene, 2,5-dichlorobiphenyl and p,p′-DDT, the elimination rate constants determined with the passive sampler method and the established method agreed within 18%. Poorer agreement (35%) was observed for 2,3,4-trichloroanisole and p-diisopropylbenzene because fewer data were obtained with the passive sampling method due to its lower sensitivity. The work shows that in-tissue passive sampling can be employed to measure contaminant elimination kinetics in fish. This opens up the possibility of studying contaminant kinetics in individual fish, thereby reducing the fish requirements and analytical costs for the determination of bioconcentration factors.     

经济发展与农业面源污染关系的协整检验——基于三峡库区重庆段1992-2009年数据的分析

运用协整检验和Granger因果检验方法,考察了三峡库区重庆段1992-2009年经济发展与农业面源污染之间的相互关系。研究结果表明:①经济增长是影响三峡库区重庆段农业面源污染的主要原因,且种植业、养殖业和农村生活三大类污染源排放量与农村经济发展之间都具有协整关系;②短期内农业生产总值的变化引起三类农业污染源排放量的同方向变动,长期来看,农村经济发展对农业面源污染有减缓作用,这与传统的环境—经济增长库兹涅茨倒U型曲线所揭示的一般规律相同;③农业经济的发展和种植业、养殖业的污染排放量具有双向的因果关系,但是经济发展是农村生活污染排放量增长的原因,农村生活污染排放量不是经济增长的原因,它们之间是单向因果关系。因此,我们要密切关注库区经济增长对环境质量带来的负面效应,必须依赖科学技术进步,提高种植业中化肥、农药、农膜和秸秆等的利用率,根据当地农业发展的特点以及与河流的远近,规划好农业、林业、畜牧业的结构,大力发展环保型、生态型农业,以减轻农业面源污染,实现农业经济增长与保持环境质量之间的相互协调。     

国产脱硝催化剂在国电长源荆州电厂2×300MW机组上的应用

随着新火电厂大气污染物排放标准的出台,NOx排放标准提高,现有的脱硝技术难以满足要求,需要增加后端烟气脱硝处理技术.选择性催化还原法是较成熟的烟气脱硝技术,催化剂是SCR技术的核心.针对国内某催化剂在国电长源荆州电厂的应用情况,详细描述了催化剂的设计选型过程.运行结果表明,该催化剂完全可以满足长源荆州电厂的性能要求,说明国产脱硝催化剂的设计选型、生产以及运行等技术能力已达到要求.     

Uncertainty estimation in the analysis of pesticide residues in olive oil using data from proficiency tests

In this work we report the results for estimating the measurement uncertainty (MU) following up the application of two different approaches, relatively the top-down procedure, by using proficiency test data. We have focused the estimation on the olive oil matrix. We used the analytical data obtained from five selected editions of the Proficiency Tests (PTs, from 2007 to 2011) on pesticide residues in olive oil to estimate the MU. These PTs have been organized by Istituto Superiore di Sanità annually in cooperation with International Olive Council (IOC) since 1997. The number of participants in each trial ranged from 10 to 43. We used a total of 34 pesticide results. The expanded uncertainty U _(c) was calculated using a covering factor k = 2 for a confidence interval of 95%. In the approach 1, the within–laboratory reproducibility standard deviation is combined with estimates of the method and laboratory bias using PTs data. In the approach 2, the way of estimating the MU is based only on the bias that the laboratory has obtained participating in a sufficient number of the IOC proficiency tests. Comparing the relative expanded uncertainty based on these different approaches we notice values quite constant and close, from 42% to 48%. Moreover, these calculated expanded uncertainties are less than the default value of 50% (corresponding to a 95% confidence level), adopted from European guidance document SANCO based on the fit-for-purpose relative standard deviation (FFP-RSD).