Occurrence of arsenic in brown rice and its relationship to soil properties from Hainan Island, China

The acquaintance of arsenic concentrations in rice grain is vital in risk assessment. In this study, we determined the concentration of arsenic in 282 brown rice grains sampled from Hainan Island, China, and discussed its possible relationships to the considered soil properties. Arsenic concentrations in the rice grain from Hainan Island varied from 5 to 309 μg/kg, with a mean (92 μg/kg) lower than most published data from other countries/regions and the maximum contaminant level (MCL) for As_i in rice. The result of correlation analysis between grain and soil properties showed that grain As concentrations correlated significantly to soil arsenic speciation, organic matter and soil P contents and could be best predicted by humic acid bound and Fe-Mn oxides bound As fractions. Grain arsenic rises steeply at soil As concentrations lower than 3.6 mg/kg and gently at higher concentrations.     

Impact of land use on the biodiversity integrity of the moist sub-biome of the grassland biome, South Africa

South Africa's moist grassland harbours globally significant biodiversity, supplies essential ecosystem services, supports crop and livestock agriculture, forestry and settlement, yet is poorly conserved. Ongoing transformation and limited opportunity for expanding the protected area network require instead that biodiversity conservation is 'mainstreamed' within other land uses. This exercise sought to identify the relative compatibility of 10 land uses (conservation, livestock or game ranching, tourism/recreation, rural settlement, dryland cropping, irrigated cropping, dairy farming, plantation forestry, and urban settlement) with maintaining biodiversity integrity. This was assessed using 46 indicators for biodiversity integrity that covered landscape composition, structure, and functioning. Data was integrated into a single measure per land use through application of the analytic hierarchy process, with supporting information gained from interviews with experts. The rank order of importance amongst indicators was landscape structure, functioning and composition. Consistent differences among land uses for all three categories revealed two clear groupings. Conservation, livestock or game ranching had the lowest impact and retained substantial natural asset, while that for tourism/recreation was intermediate. All other land uses had a severe impact. Impact on biodiversity integrity depended mainly on the extent of transformation and fragmentation, which accounted for the greatest impact on habitats and species, and impairment of landscape functioning. It is suggested that a strategic intervention for maintaining biodiversity integrity of moist grassland is to support livestock or game ranching and limit ongoing urban sprawl.     

Factors influencing wastewater management performance: case study of housing estates in suburban Bangkok, Thailand

As population densities have risen and settlements become increasingly crowded, wastewater effluent volumes have, not unexpectedly, also risen. The adverse impacts of effluent from housing estates (HEs) in suburban areas of Thailand, served by local wastewater management (WWM) systems, are of particular concern. Because of this problem, which reflects the poor performance of WWM systems, it has become increasingly important that the pivotal factors that hinder WWM improvements be identified and effective solutions be proposed and implemented. The goal of the research described in this paper was to determine the critical factors influencing WWM performance at HEs in suburban Bangkok, using multiple regression analysis. Three significant factors encompassing financial, social, institutional and general aspects were identified for each type of WWM system (community centralized and onsite). For the community centralized system, the key factors were house price, type of organization managing the HE, and the attitudes of the organization. For onsite systems, the three factors were total number of house units, direct experience with water pollution and percentage of occupied houses. These findings reflect the importance of having a WWM that employs an integrated approach rather than focusing on specific aspects in isolation from other factors. WWM performance could be improved if significant factors indicating high priority concerns were to be identified and properly applied. Addressing the priority concerns could, consequently, contribute to the development of appropriate environmental management measures, plans, and policies related to HE WWM.     

Adsorption models of Cs radionuclide and Sr (II) on some Egyptian soils

Distribution of cesium (¹³⁴Cs and ¹³⁷Cs) and strontium (Sr-II) between soil/water phases depends on many factors such as concentration of these ions between phases, the cation exchange capacity (CEC) of the soil as well as its clay content, chemical composition (especially Na, K, Ca, and Mg ions), grain size distribution, calcite, iron oxide content, and organic coatings. Distribution coefficients (Kd) of cesium (labeled with ¹³⁷Cs) and strontium were measured on the grain size distributions ≥32 μm of four soil samples. These soils were obtained from four different locations within Inshas site in Egypt and three groundwater samples were obtained from the same site locations. X-ray diffraction showed that the soil samples consisted mainly of quartz mixed with the minor amounts of kaolonite and clay minerals. Sorption experiments were carried out at strontium aqueous concentrations range 10⁻⁷ to 10⁻⁴ mol l⁻¹. The CEC and Kds for cesium and strontium were measured at the same metal concentrations range. Distribution coefficients of cesium were found to be influenced by the composition of the soil, while the distribution coefficients of strontium were found to depend on calcium concentrations in the soil/groundwater system. The aim of this study was to determine the safety assessment of disposal ¹³⁷Cs radionuclide and Sr(II) in the aquifer regions inside the Inshas site. Sequential extraction tests showed that, strontium was associated with the carbonate fractions and majority of cesium was sorbed on the iron oxides and the residue.     

江苏省低碳竞争力评价探讨

如何评价区域的低碳竞争力水平,是制定低碳政策的重要先决条件.构建了包括低碳经济竞争力、低碳环境竞争力和低碳社会竞争力3个方面的江苏省低碳竞争力评价指标体系,并采用灰关联分析方法和熵理论建立了低碳竞争力的评价模型,对该省2002-2010年间的低碳竞争力进行了评价.评价结果表明,2002-2010年间江苏省的低碳竞争力总体波动不大,需要构建区域低碳发展模式以提高其竞争力水平.最后,基于波特的“钻石模型”竞争理论,从低碳能源、低碳技术、低碳产业、低碳治理、低碳社会和碳汇6个方面提出了进一步提高江苏省低碳竞争力的具体措施.     

The impact of synthetic pyrethroid and organophosphate sheep dip formulations on microbial activity in soil

Sheep dip formulations containing organophosphates (OPs) or synthetic pyrethroids (SPs) have been widely used in UK, and their spreading onto land has been identified as the most practical disposal method. In this study, the impact of two sheep dip formulations on the microbial activity of a soil was investigated over a 35-d incubation. Microbial utilisation of [1-(14)C] glucose, uptake of (14)C-activity into the microbial biomass and microbial numbers (CFUs g(-1) soil) were investigated. In control soils and soils amended with 0.01% sheep dip, after 7d a larger proportion of added glucose was allocated to microbial biomass rather than respired to CO(2). No clear temporal trends were found in soils amended with 0.1% and 1% sheep dips. Both sheep dip formulations at 0.1% and 1% concentrations resulted in a significant increase in CFUs g(-1) soil and [1-(14)C] glucose mineralisation rates, as well as a decline in microbial uptake of [1-(14)C] glucose, compared to control and 0.01% SP- or OP-amended soils. This study suggests that the growth, activity, physiological status and/or structure of soil microbial community may be affected by sheep dips.     

A multi-stage sampling strategy for the delineation of soil pollution in a contaminated brownfield

A multi-stage sampling strategy, based on sequential Gaussian simulation, was presented to optimize the step-wise selection of a small numbers of additional samples to delineate soil pollution. This strategy was applied to a Belgian brownfield of 5.2 ha polluted with lead (Pb). Starting from an initial number of 240 samples in stage 1, additional samples were added, 25 per stage, and the reduction of the uncertainty in the Pb delineation was monitored. Twenty stages were used. Already in stage 6 a local optimum was found based on the median conditional coefficient of variation. An independent validation confirmed that this index was to be preferred over the median conditional variance. So for the brownfield considered our procedure indicated that 365 selected samples would have been sufficient, representing a gain of 70.7% in sampling effort compared to current practice which resulted in a sampling effort of 1245 samples.     

生产安全预警预报指标体系研究

分析生产安全预控指标体系建立的必要性,指出当前生产安全预控研究现状及存在的问题;提出建立生产安全预控指标的改进模式;基于生产安全预控研究现状,建立企业层面的生产安全预警指标体系和政府部门宏观决策层的生产安全预报指标体系;对现有的预警预报程序进行改进,设计从企业层面到国家层面的生产安全预警预报和控制程序,为生产安全指数的计算提供了依据。政府部门可通过自下(企业)而上(地区或国家)的程序依次计算安全指数,再由上而下查找问题,从而给出控制目标和措施。     

Distribution and variability of redox zones controlling spatial variability of arsenic in the Mississippi River Valley alluvial aquifer, southeastern Arkansas

Twenty one of 118 irrigation water wells in the shallow (25-30 m thick) Mississippi River Valley alluvial aquifer in the Bayou Bartholomew watershed, southeastern Arkansas had arsenic (As) concentrations (<0.5 to 77 microg/L) exceeding 10 microg/L. Sediment and groundwater samples were collected and analyzed from the sites of the highest, median, and lowest concentrations of As in groundwater in the alluvial aquifers located at Jefferson County, Arkansas. A traditional five-step sequential extraction was performed to differentiate the exchangeable, carbonate, amorphous Fe and Mn oxide, organic, and hot HNO(3)-leachable fraction of As and other compounds in sediments. The Chao reagent (0.25 M hydroxylamine hydrochloride in 0.25 M HCl) removes amorphous Fe and Mn oxides and oxyhydroxides (present as coatings on grains and amorphous minerals) by reductive dissolution and is a measure of reducible Fe and Mn in sediments. The hot HNO(3) extraction removes mostly crystalline metal oxides and all other labile forms of As. Significant total As (20%) is complexed with amorphous Fe and Mn oxides in sediments. Arsenic abundance is not significant in carbonates or organic matter. Significant (40-70 microg/kg) exchangeable As is only present at shallow depth (0-1 m below ground surface). Arsenic is positively correlated to Fe extracted by Chao reagent (r=0.83) and hot HNO(3) (r=0.85). Arsenic extracted by Chao reagent decreases significantly with depth as compared to As extracted by hot HNO(3). Fe (II)/Fe (the ratio of Fe concentration in the extracts of Chao reagent and hot HNO(3)) is positively correlated (r=0.76) to As extracted from Chao reagent. Although Fe (II)/Fe increases with depth, the relative abundance of reducible Fe decreases noticeably with depth. The amount of reducible Fe, as well as As complexed to amorphous Fe and Mn oxides and oxyhydroxides decreases with depth. Possible explanations for the decrease in reducible Fe and its complexed As with depth include historic flushing of As and Fe from hydrous ferric oxides (HFO) by microbially-mediated reductive dissolution and aging of HFO to crystalline phases. Hydrogeochemical data suggests that the groundwater in the area falls in the mildly reducing (suboxic) to relatively highly reducing (anoxic) zone, and points to reductive dissolution of HFO as the dominant As release mechanism. Spatial variability of gypsum solubility and simultaneous SO(4)(2-) reduction with co-precipitation of As and sulfide is an important limiting process controlling the concentration of As in groundwater in the area.     

清洁生产评价专题编制方法探讨

在环境影响评价报告中对清洁生产评价专题的编制不规范,缺少量化指标。以山东万得集团年产亿米高档染织面料项目的清洁生产评价为例,通过指标体系建立、评价方法确定、评价结果分析等,提出一种操作性强、可供借鉴的编制方法。