调度自动化系统实时信息分层分流构建

火灾作用下混凝土构件的承载能力总体不断下降且具有明显随机性,采用抗火可靠指标可较好地评估构件的火灾安全性。本文针对混凝土轴压柱的高温承载能力极限状态,考虑材料强度变异性导致的柱高温极限承栽力的随机性,以及高温下柱荷栽效应组合的随机性,采用JC法计算给出了ISO834标准升温曲线作用下不同受火时间对应的柱抗火可靠指标,讨论了主要参数对该可靠指标的影响规律;并根据我国现行建筑防火规范,通过分析和参照对比,初步提出了混凝土轴压柱抗火可靠指标的目标建议值。研究认为:(1)截面尺寸越小,柱抗火可靠指标随受火时间增加而下降的速率越快;(2)现行规范给出的截面(200×200)mm、(240×240)mm、(300×300)mm 3种柱在各自耐火极限时刻的抗火可靠指标较为接近,但截面(370×370)mm柱的抗火可靠指标却明显偏低;(3)混凝土轴压柱的目标抗火可靠指标建议取为1.6。     

火灾下约束钢柱临界温度的简化计算方法

在火灾条件下,约束钢柱轴力由于升温而增加,会导致在较低的温度下发生屈曲;但屈曲后,钢柱的轴向温度膨胀得到释放,轴力下降,因此屈曲后钢柱仍能继续承栽。本文通过计算长度系数将转动约束钢柱转换为铰支钢柱,给出了一种轴向约束钢柱在火灾升温条件下的临界温度的简化计算方法——轴力放大系数设计方法。此法通过轴力放大系数将轴向约束钢柱转化为无约束钢柱,再按无约束钢柱计算得到钢柱的临界温度。用验证过的有限元模型对简化计算方法进行了验证,计算结果表明简化方法吻合较好。     

约束高强度Q460钢柱抗火性能分析

为了研究高强度约束钢柱在火灾下的反应,根据高强度结构钢Q460在高温下的力学性能参数,建立了约束高强度钢柱受火分析模型,得到了高强度约束钢柱在火灾下的轴向位移、跨中挠度、最大应力以及临界温度。采用有限元分析对理论结果进行了验证,两者吻合很好。利用验证过的该文计算方法计算了2种荷栽比、长细比和约束刚度比条件下的高强钢柱的抗火性能;采用CECS200:2006的力学性能参数计算了约束普通钢柱的抗火性能。通过对高强钢和普通钢的抗火性能分析发现,轴向约束明显降低钢柱的临界温度,长细比、荷载比越大,临界温度越低;高强钢的抗火性能要优于普通钢。     

TiO2薄膜光催化效果的强化

采用溶胶-凝胶法制备TiO2溶胶,将其涂覆在普通钠钙玻璃上,以TiO2对甲基橙的光分解率探讨TiO2薄膜最佳光催化性能.结果表明,当PEG400的加入量为7%时,TiO2薄膜的光催化性能最强;用锐钛型TiO2粉末二次引发的溶胶提拉制成的薄膜对甲基橙的光催化分解效果有很大的提高;经滴加操作后薄膜的光催化性能有明显改善;各个影响因素最好的组合效果为滴加操作 锐钛型粉体引发 H2SO4超强酸化 La3 掺杂.     

Stabilization of heavy metals in MSWI fly ash using silica fume

The objective of this work was to investigate the feasibility and effectiveness of silica fume on stabilizing heavy metals in municipal solid waste incineration (MSWI) fly ash. In addition to compressive strength measurements, hydrated pastes were characterized by X-ray diffraction (XRD), thermal-analyses (DTA/TG), and MAS NMR (²⁷Al and ²⁹Si) techniques. It was found that silica fume additions could effectively reduce the leaching of toxic heavy metals. At the addition of 20% silica fume, leaching concentrations for Cu, Pb and Zn of the hydrated paste cured for 7 days decreased from 0.32 mg/L to 0.05 mg/L, 40.99 mg/L to 4.40 mg/L, and 6.96 mg/L to 0.21 mg/L compared with the MSWI fly ash. After curing for 135 days, Cd and Pb in the leachates were not detected, while Cu and Zn concentrations decreased to 0.02 mg/L and 0.03 mg/L. The speciation of Pb and Cd by the modified version of the European Community Bureau of Reference (BCR) extractions showed that these metals converted into more stable state in hydrated pastes of MSWI fly ash in the presence of silica fume. Although exchangeable and weak-acid soluble fractions of Cu and Zn increased with hydration time, silica fume addition of 10% can satisfy the requirement of detoxification for heavy metals investigated in terms of the identification standard of hazardous waste of China.     

Leaching,mobility and persistence of tebufenozide in columns packed with forest litter and soil

Abstract

Leaching, downward mobility and persistence of tebufenozide was investigated under laboratory conditions in columns packed with forest litter and soil, after fortification with the analytical grade material (purity > 99.6%) and with two commercial formulations, RH‐5992 2F (aqueous flowable) and RH‐5992 ES (emulsion suspension). Two types of litter and soil were used: one type with relatively high amounts of sand and the other with high amounts of clay.

The concentrations eluted in the leachates were lower when the analytical material (dissolved in acetone) was used for fortification, than when the two formulations (diluted with water) were used. The amount leached was higher for RH‐5992 2F than for RH‐5992 ES. The type of substrate, i.e., sandy or clay type, had only marginal influence on the amounts eluted in the leachates. Downward movement of tebufenozide from the top 2‐cm layer to the untreated middle and bottom layers (3‐cm segments) was consistently lower when the analytical material was used for fortification, than when the two formulations were used. Downward movement was higher for RH‐5992 2F than for RH‐5992 ES. Persistence of tebufenozide in substrates, maintained under submerged conditions for 70 days after leaching, indicated an initial 2‐week lag period prior to the onset of degradation. Formulation‐related differences were observed in the half‐life (DT₅₀) values. When the analytical material was used for fortification, the DT₅₀ ranged from ca 54 to 59 d. However, when the formulations were used for fortification, the DT₅₀ showed a higher range, i.e., from ca 62 to 67 d for RH‐5992 2F and ca 70 to 80 d for RH‐5992 ES. Formulation ingredients appear to have caused enhanced adsorption of tebufenozide onto the substrates, thus delaying degradation.     

Ionic dye adsorption by zinc oxide nanoparticles

The adsorption behaviour of Basic Red 12, Acid Orange 7 and Acid Blue 1 on zinc oxide nanoparticles (ZNP) has been investigated to understand the physicochemical process involved and to explore the possible use of nanoparticles in the treatment and management of textile waste matter. The dye removal capacity of ZNP towards Basic Red 12, Acid Orange 7 and Acid Blue 1 was found to be 15.64, 6.78 and 6.38 mg g^?1, respectively. The adsorption process was pH dependent and optimum pH values of 9.0, 2.0 and 4.0 were obtained for Basic Red 12, Acid Orange 7 and Acid Blue 1, respectively. Equilibrium was established after 1.0 h for all dyes. Langmuir, Freundlich and Temkin isotherm models were applied to the system. The adsorbent ZNP was characterised using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR) techniques. SEM analysis revealed the noticeable nanoporous morphology of the material. The results of FTIR spectroscopy showed that the process is driven by an electrostatic complexation mechanism. XRD studies revealed the nanocrystalline structure of ZNP. BET surface area measurement suggested a high pore volume and large surface area for the adsorbent. The kinetic measurements suggested pseudo-second-order kinetic processes with high regression coefficients and smaller standard error of estimate values and lower residual sum of squares. The thermodynamic measurements suggested that all processes were exothermic and accompanied by negative values for Δ G⁰, Δ S⁰ and Δ H⁰.     

低周荷载下型钢混凝土柱抗剪性能智能分析

为了研究型钢混凝土短柱的抗震性能，通过21根SRC柱在低周反复荷载作用下的剪切黏结破坏试验结果，在利用灰色关联理论进行模型输入变量选择的基础上，建立了其基于改进神经网络模型的受剪承载力分析模型，进而研究了混凝土抗压强度、腹板宽度、轴压比及箍筋间距等因素对SRC柱抗剪能力的影响规律，并对SRC柱的受剪承载力进行了预测。结果表明，所提方法能够反映受剪承载力与影响因素间的非线性变化规律，可供SRC柱在低周往复荷载作用下的受剪承载力分析参考。     

轴心受压钢筋混凝土柱等效火灾荷载的计算

迄今为止，国内外有关计算构件耐火极限的方法，是钢筋混凝土构件与防火研究的主要内容。而在结构设计中，由于直接考虑的是荷载作用，为此提出了一个新概念——等效火灾荷载，将火灾对结构的影响直接考虑成荷载作用。在确定了混凝土柱的截面温度场后，利用一种简化计算方法计算出钢筋混凝土柱的等效火灾荷载，进而计算出钢筋混凝土柱的耐火极限。在火灾中，作为结构最基本的构件柱可能受到单面或多面的火作用，这里仅介绍轴心受压钢筋混凝土柱等效火灾荷载的计算。     

带压开采陷落柱突水影响因素数值模拟

为研究承压水压与煤层陷落柱位置这两种因素对陷落柱突水的影响,在分析固流耦合数学模型的基础上,利用数值模拟软件FLAC3D,以双柳矿地质条件为背景,分别对3 MPa和5 MPa承压水压下开采上、下两组煤4种情况进行模拟,分析陷落柱及其周边围岩的渗流-塑性破坏耦合场、应力场和位移场的变化.结果表明:随着工作面推进至接近陷落柱,工作面前方集中应力场与柱体周边应力场发生耦合,并出现应力集中,当水压为5 MPa开采上组煤时应力集中系数最大,最容易形成突水危险区域;当上组煤工作面距离陷落柱为30 m时,陷落柱渗流场与集中应力场开始连通,在开采下组煤时这一距离比上组煤扩大15 ～ 20 m;煤层底板随工作面推进发生压缩-膨胀周期变化,引起拉伸、剪切破坏.