The concentrations, profiles, sources and spatial distribution of polycyclic aromatic hydrocarbons (PAHs) were determined in 40 surface soil samples collected from Beijing, Tianjin and surrounding areas, North China in 2007, and all sampling sites were far from industrial areas, roadsides and other pollution sources, and across a range of soil types in remote, rural villages and urban areas. The total concentrations of 16 PAHs ranged from 31.6 to 1475.0 ng/g, with an arithmetic average of 336.4 ng/g. The highest PAH concentrations were measured in urban soils, followed by rural village soils and soils from remote locations. The remote-rural village-urban PAH concentration gradient was related to population density, gross domestic product (GDP), long-range atmospheric transport and different types of land use. In addition, the PAH concentration was well correlated with the total organic carbon (TOC) concentration of the soil. The PAH profile suggested that coal combustion and biomass burning were primary PAH sources. 相似文献
With increased environmental awareness, recycling/utilization of industrial byproducts is gaining ground. One such by-product is silica fume (SF), which is byproduct of the smelting process in the silicon and ferrosilicon industry. By-products of the production of silicon metal and the ferrosilicon alloys having silicon contents of 75% or more contain 85-95% non crystalline silica. Silica fume is very useful in the design and development of high quality cement paste/mortar and concrete.This paper presents comprehensive details of the physical, chemical, properties, and its reaction mechanism. It also covers the hydration characteristics, consistency, setting times, workability and compressive strength of cement paste and mortar. 相似文献
We present estimated emission source strengths of seven polychlorinated biphenyl (PCB) congeners for Banja Luka, a city that was affected by the civil war in Bosnia and Hercegovina (former Yugoslavia) in the 1990s. These emission estimates are compared to PCB emission rates estimated for the cities of Zurich, Switzerland, and Chicago, USA using an approach that combines multimedia mass balance modeling and measurement data. Our modeled per-capita emission estimates for Banja Luka are lower by a factor of ten than those for Zurich and Chicago, which are similar. This indicates that the sources of PCB emissions in Banja Luka are likely to be weaker than in the Western European and North American cities which show relatively high PCB emissions. Our emission rates from the three cities agree within a factor of ten with emission estimates from a global PCB emission inventory derived from production and usage estimates and emission factors. 相似文献
The source apportionment of the annual nutrient load carried by the Po river to the Adriatic sea has been studied.
An integrated modelling approach was applied to the Lombardy plain area, which covers about 34% of the Po river watershed area and accounts for about 50% of the point sources’ loads carried by the river. To extract all the information available from direct instream measurements, two different modelling tools were alternatively used. The source apportionment was investigated considering both dry and wet weather scenarios. In order to quantify the apportionment in dry-weather conditions, the Lombardy portion of the Po river basin was modelled by using the US-EPA QUAL2E model. Such a simulation allowed to assess a significant contribution (about 50% of the total dry-weather load) of a not rain-driven diffuse pollution component (i.e. groundwater, springs, lake emissaries). Moreover, to estimate the rain-driven surface runoff contribution to the instream total load, the Lombardy plain area was also modelled by means of the US-DA SWAT model. SWAT results indicate a runoff contribution to the Po river instream total load of about 10 000 t N yr−1 and 1300 t P yr−1 (i.e. approximately the 10–20% of the total annual Lombardy nutrient load). At the event scale (i.e. the single rainstorm event) the runoff contribution may rise up to 30–80% of the total instream load. Finally, the total annual nitrogen load at the Po basin closure was estimated for the period 1985–2001. Out of a total annual load of 140 000 t N yr−1, Lombardy accounts for 43% (point plus diffuse sources). The rain-driven diffuse sources constitute the 20% of the overall total load, the point sources account for 40%, whereas the remaining 40% is mainly constituted by “dry-weather diffuse sources” (i.e. groundwater, springs, lake emissaries). 相似文献
Multivariate statistical techniques are applied to particulate matter (PM) and meteorological data to identify the sources responsible for evening PM spikes at Sunland Park, NM (USA). The statistical techniques applied are principal components analysis (PCA), redundancy analysis (RDA), and absolute principal components scores analysis (APCSA), and the data evaluated are 3-h average (6–9 p.m.) PM2.5 mass and chemical composition and 1-h average PM2.5 and PM10 mass and environmental data collected in the winter of 2002. Although the interpretation of the data was complicated by the presence of sources which are likely changing in time (e.g. brick kilns), the multivariate analyses indicate that the evening high PM2.5 is associated with burning-activities occurring to the south of Sunland Park, and these emissions are characterized by elevated Sb, Cl−, and elemental carbon; 68% of the PM2.5 mass can be attributed to this source. The PM10 evening peaks, on the other hand, are mainly caused by resuspended dust generated by vehicular movements south of the site and transported by the local terrain-induced drainage flow. 相似文献