The effect of oil sands process-affected water and naphthenic acids on the germination and development of Arabidopsis

Oil sands mining in the Athabasca region of northern Alberta results in the production of large volumes of oil sands process-affected water (OSPW). We have evaluated the effects of OSPW, the acid extractable organic (AEO) fraction of OSPW, and individual naphthenic acids (NAs) on the germination and development of the model plant, Arabidopsis thaliana (Arabidopsis). The surrogate NAs that were selected for this study were petroleum NAs that have been used in previous toxicology studies and may not represent OSPW NAs. A tricyclic diamondoid NA that was recently identified as a component of OSPW served as a model NA in this study. Germination of Arabidopsis seeds was not inhibited when grown on medium containing up to 75% OSPW or by 50 mg L⁻¹ AEO. However, simultaneous exposure to three simple, single-ringed surrogate NAs or a double-ringed surrogate NA had an inhibitory effect on germination at a concentration of 10 mg L⁻¹, whereas inhibition of germination by the diamondoid model NA was observed only at 50 mg L⁻¹. Seedling root growth was impaired by treatment with low concentrations of OSPW, and exposure to higher concentrations of OSPW resulted in increased growth inhibition of roots and primary leaves, and caused bleaching of cotyledons. Treatment with single- or double-ringed surrogate NAs at 10 mg L⁻¹ severely impaired seedling growth. AEO or diamondoid NA treatment was less toxic, but resulted in severely impaired growth at 50 mg L⁻¹. At low NA concentrations there was occasionally a stimulatory effect on root and shoot growth, possibly owing to the broad structural similarity of some NAs to known plant growth regulators such as auxins. This report provides a foundation for future studies aimed at using Arabidopsis as a biosensor for toxicity and to identify genes with possible roles in NA phytoremediation.     

Quantifying Metal Contributions from Multiple Sources to the Clark Fork River,Montana, U.S.A.

Identifying and quantifying the contributions of multiple sources of trace elements to stream sediments in a basin containing several possible inputs presents a unique problem related to the investigation of rivers impacted by industrial activity. A multi-source dilution-mixing model was developed and applied to determine the relative contributions to As, Cu and Pb burdens in the Clark Fork River, Montana, a recipient of historical mine wastes as a result of over a century of mining and milling operations. The results identified the Flint Creek drainage as a major source of anthropogenic As (47%) and Pb (35%) to sediments of the Clark Fork River and the Milltown Reservoir, in addition to the major sources associated with mining operations in Butte, MT. The Little Blackfoot River also contributes anthropogenic As (3%) and Pb (4%) to the Clark Fork River, while minor inputs of Cu (1%) and Pb (2%) emanate from the Blackfoot River. The model allows source quantification, and an understanding of the fate and transport of mine wastes in a basin, allowing identification and eventual prioritization of sites destined for remediation.     

Gold mining in Australia: linking historical trends and environmental and resource sustainability

The mining of gold has been and continues to be an important aspect of Australian industry. Gold mining moved quickly from fossicking and alluvial sources in the 1850's to hard rock mining. This paper presents, arguably for the first time, a detailed historical compilation of Australian gold mining production data. This data is then analysed in the context of sustainability, focussing particularly on mineral resource sustainability and the broader aspects of environmental impacts now commonly reported by some mining companies in annual sustainability performance reports. The key trends which are demonstrated by the data include a long-term decline in ore grade, increased open cut mining, substantive increases in tailings and waste rock production, as well as showing the impact of new technologies and economics on available gold resources. The available environmental data on material and energy inputs to and pollutant emissions from gold production is also presented, showing a clear sensitivity to ore grade. In terms of sustainability, these relationships raise significant issues such as increasing greenhouse footprint per unit gold produced, potential impacts on energy and water consumption, as well as overall gold resource sustainability. The paper presents a unique case study of the resource and environmental sustainability of the Australian gold mining sector with major implications for sustainability policy and reporting.     

Long-term effects of submergence and wetland vegetation on metals in a 90-year old abandoned Pb-Zn mine tailings pond

A Pb-Zn tailings pond, abandoned for approximately 90 years, has been naturally colonized by Glyceria fluitans and is an excellent example of long-term metal retention in tailings ponds under various water cover and vegetation conditions. Shallow/intermittently flooded areas (dry zone) were unvegetated and low in organic matter (OM) content. Permanently flooded areas were either unvegetated with low OM, contained dead vegetation and high OM, or living plants and high OM. It was expected that either water cover or high OM would result in enhanced reducing conditions and lower metal mobility, but live plants would increase metal mobility due to root radial oxygen loss. The flooded low OM tailings showed higher As and Fe mobility compared with dry low OM tailings. In the permanently flooded areas without live vegetation, the high OM content decreased Zn mobility and caused extremely high concentrations of acid-volatile sulfides (AVS). In areas with high OM, living plants significantly increased Zn mobility and decreased concentrations of AVS, indicating root induced sediment oxidation or decreased sulfate-reduction. This is the first study reporting the ability of wetland plants to affect the metal mobility and AVS in long-term (decades), unmanaged tailings ponds.     

Discriminating between Copper and Silver Mill Tailings in Silver Bow Creek Overbank Deposits,Butte, Montana,U.S.A.

Mining of the Butte deposit evolved over 100 years from placer mining starting in 1864 through silver mining to copper mining in the 1900s. Tailings resulting from milling during the period 1876-1924 were typically sluiced into the adjacent Silver Bow Creek (SBC) where they were washed downstream. The most significant flood event in 1908, among others, resulted in emplacement of approximately 2.9 m tons of sediment intermixed with tailings as overbank deposits along SBC between Butte and the Warm Springs Ponds. Apportioning the associated costs was contingent in part on discriminating between ownership of liability for the silver and copper tailings, which together formed the most significant portion of the overbank deposits. Samples were collected of tailings end-members and SBC deposits and their characteristic mineralogy (e.g. galena for silver tailings, and enargite for copper tailings) used to ascertain mixing of the tailings along SBC. This analysis identified Pb as a signature element for silver tailings and Cu for copper tailings. Two-hundred and twenty-four Cu and Pb chemical analyses representing 43 transects through the overbank deposits along SBC allowed calculation of the proportional contribution of the end members for each integrated transect. Accumulating the volumes from each transect resulted in an apportionment of 53% copper and 47% silver tailings in the overbank deposits.     

德兴铜矿2号尾矿库安全管理经验

从4个部分介绍了德兴铜矿2号尾矿库生产运行情况,安全管理的一些具体做法。并针对生产中存在的问题进行了剖析、总结,取得了一些经验,对后期堆坝的设计、管理工作也具有一定的指导意义。