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141.
Evaluating non-equilibrium solute transport in small soil columns 总被引:11,自引:0,他引:11
Kamra SK Lennartz B Van Genuchten MT Widmoser P 《Journal of contaminant hydrology》2001,48(3-4):189-212
Displacement studies on leaching of bromide and two pesticides (atrazine and isoproturon) were conducted under unsaturated steady state flow conditions in 24 small undisturbed soil columns (5.7 cm in diameter and 10 cm long) each collected from two sites differing in soil structure and organic carbon content in North Germany. There were large and irregular variabilities in the characteristics of both soils, as well as in the shapes of breakthrough curves (BTCs) of different columns, including some with early breakthrough and increased tailing, qualitatively indicating the presence of preferential flow. It was estimated that one preferential flow column (PFC) at site A, and four at site B, contributed, respectively to 11% and 58% of the accumulated leached fraction and to more than 80% of the maximum observed standard deviation (SD) in the field-scale concentration and mass flux of pesticides at two sites. The bromide BTCs of two sites were analyzed with the equilibrium convection-dispersion equation (CDE) and a non-equilibrium two-region/mobile-immobile model. Transport parameters of these models for individual BTCs were determined using a curve fitting program, CXTFIT, and by the time moment method. For the CDE based equilibrium model, the mean values of retardation factor, R, considered separately for all columns, PFCs or non-preferential flow columns (NPFCs) were comparable for the two methods; significant differences were observed in the values of dispersion coefficients of two sites using the two estimation methods. It was inferred from the estimated parameters of non-equilibrium model that 5-12% of water at site A, and 12% at site B, was immobile during displacement in NPFCs. The corresponding values for PFCs of two sites were much larger, ranging from 25% to 51% by CXTFIT and from 24% to 72% by the moment method, suggesting the role of certain mechanisms other than immobile water in higher degrees of non-equilibrium in these columns. Peclet numbers in PFCs of both sites were consistently smaller than five, indicating the inadequacy of the non-equilibrium model to incorporate the effect of all forms of non-equilibrium in PFCs. Overall, the BTCs of individual NPFCs, PFCs and of field average concentration at the two sites were better reproduced with parameters obtained from CXTFIT than by the moment method. The moment method failed to capture the peak concentrations in PFCs, but tended to describe the desorption and tail branches of BTCs better than the curve fitting approach. 相似文献
142.
SBR工艺设计经验探讨 总被引:2,自引:0,他引:2
提出了SBR工艺中,反应池容积、反应时间以及需氧量的计算方法和设计经验。同时,在研读和对比国内外相关资料的基础上,探讨了SBR工艺发生污泥膨胀的可能性和原因,介绍了控制方法与措施。 相似文献
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145.
用主成分分析的方法,找出影响废黄河2007年水质的主成分,计算各样本的主成分得分,用聚类分析的方法将样本水质分类,结合分类结果及水质综合评分对各样本水质进行评价。 相似文献
146.
大气连续采样在乌鲁木齐应用分析 总被引:3,自引:0,他引:3
对乌鲁木齐市大气连续采样方法试运行实验进行总结,比较了以往的定时采样方法后认为,连续采样方法更准确反映本地大气污染物的状况。 相似文献
147.
水体中重要污染元素化学形态分析研究方法及其进展 总被引:3,自引:0,他引:3
概述了元素化学形态分析的意义、概念和范围,元素化学形态分析与模拟计算方法,并分别对某些重要元素的化学形态分析方法的进展作了综述,介绍了115篇文献。 相似文献
148.
Ghoramara Island is located ca. 150 km south of Kolkata, Bay of Bengal, India, in the Sundarban Delta complex. This sparsely
populated island is suffering from severe coastal erosion and areal reduction for the last three decades, which results in
the loss of major areas on the northwest coast. Both numerous households and a significant area of agricultural land and coastal
stretches for fish drying have been lost. This has rendered thousands of people homeless as ‘environmental refugess’. In the
present paper an attempt is made to study the erosion and accretion process through time series analysis using a GIS technique.
Also, a study of remedial measures to protect the island using a ‘bio-engineering’ technique is reported in this paper. It
has been shown that, in the absence of protection measures, the eastern shore will merge with the Indian mainland during the
next 25 years, while the western part will be completely washed off. 相似文献
149.
1949—1994年中国洪水灾害成灾面积的时序分形特征 总被引:24,自引:3,他引:24
作者应用1949~1994年中国洪水灾情资料,重构了其嵌入相空间序列,探讨了其时序的分形特征,计算得到了分维数。研究表明:洪水灾害成灾面积的时序分布具有分形特征。研究结果为建立洪水灾害成灾面积的时序预测预报模型提供依据。 相似文献
150.
为在一定程度上减轻流域干旱损失,国家防汛抗旱总指挥部提出旱限水位的概念,并开展水库抗旱调度,降低干旱影响程度。旱限水位是水库低水位运行的控制性水位,其合理设置对提高区域水资源利用率意义重大,而水文气象特征在年内的阶段性变化要求基于旱限水位的水库管理应适应其变化特征。此次研究提出水库抗旱调度分期的确定方法,采用核主成分分析法提取指标的非线性特征,结合熵权法赋予指标权重后利用Fisher最优分割法对干旱的年内阶段性变化进行划分。以黄河流域刘家峡和小浪底水库为例,分期结果刘家峡水库分3期为:7月至9月,10月至3月,4月至6月;小浪底水库分3期为:7月至10月,11月至3月,4月至6月。 相似文献