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81.
82.
灾害史研究中的年代换算及其软件 总被引:1,自引:0,他引:1
“灾害史中的年代换算(TCHD)”软件是进行年代换算的专用软件。本文研究了几种主要历法的年代换算的具体算法.介绍了该软件的结构,流程和功能.TCHD软件使灾害学和历史学等领域的研究人员摆脱了传统的朔闰表式的历法对照和检索方式,并成为灾害史工作计算机化的一部分。 相似文献
83.
氮氧化物生态环境中的转化及危害 总被引:1,自引:0,他引:1
在对氮氧化物污染引起奶牛亚硝酸中毒事件的调查基础上,通过室内模拟实验研究氮氧化物的转化过程及测定方法,探讨氮氧化物的生态环境中的转化规律,分析其危害途径和机理,研究表明氮氧化物中的二氧化氮遇水迅速反应生成硝酸和亚硝酸,而对生态环境和人畜产生危害。 相似文献
84.
85.
绿色贸易转型政策框架及“十二五”重点政策探讨 总被引:4,自引:4,他引:0
绿色贸易转型政策框架,是指一切有利于促进我国对外贸易发展,同时缓解贸易资源环境代价和改善环境质量的贸易手段和措施构成的政策集合体系。本文基于环境保护部环境与贸易专家组(以下称专家组)多年研究探索基础上,依据贸易政策理论,构建促进绿色贸易转型的政策框架,梳理出主要绿色贸易手段的政策矩阵,并顺应"十二五"贸易政策取向和国家"十二五"环保规划目标,提出相应的重点政策建议:一是绿化海关进出口产品目录,进行产品环境分类管理;二是制定实行以征收出口环节的环境关税为主导的绿色贸易政策;三是对生态标志产品实施出口退税差别税率政策;四是推行鼓励进口替代政策,促进节能减排;五是及时修订外商投资产业指导目录,防范外商直接投资西部转移的环境风险;六是制定企业境外投资国别指导目录,把环境影响评价制度延伸至境外投资项目;七是健全进口废物贸易政策,有效防范废物贸易环境风险;八是适度提高人民币汇率,促进绿色贸易转型。 相似文献
86.
Despite the widespread occurrence of phenols in anthropogenic and natural compounds, their fate in reactions with hypochlorous acid (HOCl), one of the most common water treatment disinfectants, remains incompletely understood. To close this knowledge gap, this study investigated the formation of disinfection by-products (DBPs) in the reaction of free chlorine with seven para-substituted phenols. Based on the chemical structures of the DBPs and the reaction mechanisms leading to their formation, the DBPs were categorized into four groups: chlorophenols, coupling products, substituent reaction products, and ring cleavage products. In contrast to previous studies that investigated the formation of early-stage chlorophenols, the primary focus of this study was on the elucidation of novel ring cleavage products, in particular α, β-unsaturated C4-dialdehydes, and C4-dicarboxylic acids, which, for the first time, were identified and quantified in this study. The molar yields of 2-butene-1,4-dial (BDA), one of the identified α, β-unsaturated C4-dialdehydes, varied among the different phenolic compounds, reaching a maximum value of 10.4% for bisphenol S. Molar yields of 2-chloromaleic acid (Cl-MA), one of the identified C4-dicarboxylic acids, reached a maximum value of 30.5% for 4-hydroxy-phenylacetic acid under given conditions. 2,4,6-trichlorophenol (TCP) was shown to be an important intermediate of the parent phenols and the C4-ring cleavage products. Based on the temporal trends of α, β-unsaturated C4-dialdehydes and C4-dicarboxylic acids, their formation is likely attributable to two separate ring cleavage pathways. Based on the obtained results, an overall transformation pathway for the reaction of para-substituted phenols with free chlorine leading to the formation of novel C4 ring cleavage products was proposed. 相似文献
87.
Yanhui Dai Jian Zhao Chunxiao Sun Diying Li Xia Liu Zhenyu Wang Tongtao Yue Baoshan Xing 《Frontiers of Environmental Science & Engineering》2022,16(10):136
88.
Diclofenac (DCF), a widely used non-steroidal anti-inflammatory, reacted readily with birnessite under mild conditions, and the pseudo first order kinetic constants achieved 8.84 × 10?2 hr?1. Five products of DCF including an iminoquinone product (2,5-iminoquinone-diclofenac) and four dimer products were observed and identified by tandem mass spectrometry during the reaction. Meanwhile, 2,5-iminoquinone-diclofenac was identified to be the major product, accounting for 83.09% of the transformed DCF. According to the results of spectroscopic Mn(III) trapping experiments and X-ray Photoelectron Spectroscopy, Mn(IV) contained in birnessite solid was consumed and mainly converted into Mn(III) during reaction process, which proved that the removal of DCF by birnessite was through oxidation. Based on the identified products of DCF and the changes of Mn valence state in birnessite solid, a tentative transformation pathway of DCF was proposed. 相似文献
89.
大气汞在土壤中转化及其与土壤汞富集的相关性 总被引:18,自引:0,他引:18
通过现场调查与模拟试验相结合的方法,研究了大气汞对土壤汞富集的影响及其进入土壤后的形态转化。 相似文献
90.
Zaishan Wei Meiru Tang Zhenshan Huang Huaiyong Jiao 《Frontiers of Environmental Science & Engineering》2022,16(2):20