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221.
研究了硝酸-双氧水体系消解、石墨炉原子吸收法测定环境空气中锡的方法.采用抗坏血酸和磷酸二氢铵作混合基体改进剂,热解涂层石墨管,塞曼扣背景.方法的检测限为3.56 μg/L,实际样品回收率为90.6%~102%. 相似文献
222.
目的 对氟醚橡胶FM-2D在空气与飞马Ⅱ号润滑油中的热老化行为与机理进行研究。方法 开展氟醚橡胶高温贮存试验,在热氧、热油的介质环境下,研究氟醚橡胶的力学性能退化规律。试验后对样品的拉伸性能、压缩性能以及硬度进行检测,并且利用傅里叶红外光谱仪、扫描电子显微镜以及X射线电子能谱对试验后样品进行检测。结果 通过热老化试验,发现氟醚橡胶在200℃以下能够长期维持较好的力学性能。试验温度在200℃以上,氟醚橡胶的力学性能出现明显退化趋势,并且在热空气与热油中的老化趋势不同。在220℃的热空气老化31 d后,氟醚橡胶的拉伸强度下降27.0%,断裂伸长率增大89.8%,压缩应力松弛率为34.6%,硬度下降8.7%。在220℃的热油老化31 d后,氟醚橡胶的拉伸强度下降85.9%,断裂伸长率下降83.9%,压缩应力松弛率为-17.5%,硬度上升4.2%。结论 在热空气老化过程中,橡胶分子链受热氧影响发生断裂,使其强度下降;在热油老化过程中,油介质和高温的耦合作用使橡胶的交联网络失效,橡胶发硬变脆。 相似文献
223.
Lazar M. Kaluđerović Zorica P. Tomić Darko P. Ašanin Rada D. Đurović-Pejčev Branka J. Kresović 《Journal of environmental science and health. Part. B》2018,53(8):503-509
The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86 mmol 100 g?1 of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43 mmol 100 g?1 of clay (0.5 CEC), 86 mmol 100 g?1 of clay (1 CEC) and 129 mmol 100 g?1 of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide. 相似文献
224.
Cohen MJ Dabral S Graham WD Prenger JP Debusk WF 《Environmental monitoring and assessment》2006,116(1-3):427-457
Rapid, repeatable assessment of ecological condition is critical for quantitative ecosystem monitoring. Soils provide a sensitive,
integrative indicator for which sampling and analysis techniques are well defined. We evaluated soil properties as indicators
of ecological condition (subjectively classified into minimally/moderately/severely degraded based on vegetative, hydrologic
and edaphic cues) at 526 sites within Ft. Benning military installation (Georgia, USA). For each sample, we measured 17 biogeochemical
parameters, and collected high-resolution diffuse reflectance spectra using visible/near infrared reflectance spectroscopy
(VNIRS). VNIR spectra have been related to numerous soil attributes — we examine them here for diagnosing integrated response
(i.e., ecological condition). We used ordinal logistic regression (OLR) and classification trees (CT) to discriminate between
condition categories using both sets of predictors (biogeochemistry and spectra). Sixteen biogeochemical parameters were significantly
different across condition categories; however, multivariate models greatly improved discrimination ([calibration, validation]
accuracy of [69%, 66%] and [96%, 73%] for OLT and CT models, respectively). Important predictors included total C, total P,
and Mehlich K/Ca/Mg. VNIR spectra further improved discrimination ([calibration, validation] accuracy of [74%, 70%] and [96%,
75%] for OLR and CT models, respectively). While spectra were comparably effective at discriminating minimally degraded sites,
they were significantly more effective at discriminating severely degraded sites. Error rates across confounding factors suggest
that watershed of origin and landscape position were the only important confounders, likely due to imbalanced sampling. We
conclude that multivariate diagnosis improves accuracy, and that VNIR spectroscopy, which yields substantial cost and logistical
improvements over conventional analyses, provides an effective tool for rapid condition diagnosis. 相似文献
225.
Monitoring and assessment of toxic metals in Gulf War oil spill contaminated soil using laser-induced breakdown spectroscopy 总被引:1,自引:0,他引:1
Laser-induced breakdown spectroscopy (LIBS) was applied for the detection of toxic metals in oil spill contaminated soil (OSCS).
The OSCS samples were collected from Khursania Saudi Arabia along the coast of Persian Gulf exposed to oil spills in 1991
Gulf war. Environmentally important elements like Aluminum Magnesium, Calcium, Chromium, Titanium, Strontium, Iron, Barium,
Sodium, potassium, Zirconium and Vanadium from the contaminated soil have been detected. Optimal experimental conditions for
analysis were investigated. The LIBS system was calibrated using standard samples containing these trace elements. The results
obtained using Laser-Induced Breakdown Spectroscopy (LIBS) were compared with the results obtained using Inductively Coupled
Plasma Emission Spectroscopy (ICP). The concentrations of some elements (Ba and Cr) were found higher than permissible safe
limits. Health risks associated with exposure to such toxic elements are also discussed. 相似文献
226.
采用微波消解-原子荧光光谱法测定大气细颗粒物中的砷,确定了最佳样品处理方法与测定条件。方法在0μg/L~40.0μg/L范围内线性良好,标准曲线相关系数达0.999以上,检出限为0.01μg/L。土壤标准品的测定值在标准值范围内,大气PM2.5滤膜样品加标回收率为96.0%~102%,5次平行测定的RSD为1.5%~3.6%。 相似文献
227.
228.
Fluorescence excitation-emission spectroscopy with regional integration analysis for assessment of compost maturity 总被引:3,自引:0,他引:3
Composting of animal manures is believed as an alternative way for directly recycling them in farms, and therefore assessment of compost maturity is crucial for achieving high quality compost. Fluorescence excitation-emission matrices (EEMs) combined with regional integration analysis is presented to assess compost maturity. The results showed that the EEM contours of water-extract organic matter (WEOM) from immature composts exhibited four peaks at excitation/emission (Ex/Em) of 220/340 nm, 280/340 nm, 220/410 nm, and 330/410 nm, whereas EEM contour of WEOM from mature composts had only two peaks at Ex/Em of 230/420 nm and 330/420 nm. Pearson correlation demonstrated that peaks intensity rather than their ratios had a significantly correlation with the common indices assessing compost maturity, whereas the normalized excitation-emission area volumes (Φi,ns) from regional integration analysis had a stronger correlation with the common indices assessing compost maturity than peaks intensity. It is concluded that the Φi,ns from regional integration analysis are more suitable to assess the maturity of compost than the intensities of peaks. Therefore, the fluorescence spectroscopy combined with regional integration analysis can be used as a valuable industrial and research tool for assessing compost maturity, given its high sensitivity and selectivity. 相似文献
229.
Benn TM Westerhoff P Herckes P 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1334-1342
Detection methods are necessary to quantify fullerenes in commercial applications to provide potential exposure levels for future risk assessments of fullerene technologies. The fullerene concentrations of five cosmetic products were evaluated using liquid chromatography with mass spectrometry to separate and specifically detect C60 and C70 from interfering cosmetic substances (e.g., castor oil). A cosmetic formulation was characterized with transmission electron microscopy, which confirmed that polyvinylpyrrolidone encapsulated C60. Liquid-liquid extraction of fullerenes from control samples approached 100% while solid-phase and sonication in toluene extractions yielded recoveries of 27-42%. C60 was detected in four commercial cosmetics ranging from 0.04 to 1.1 μg/g, and C70 was qualitatively detected in two samples. A single-use quantity of cosmetic (0.5 g) may contain up to 0.6 μg of C60, demonstrating a pathway for human exposure. Steady-state modeling of fullerene adsorption to biosolids is used to discuss potential environmental releases from wastewater treatment systems. 相似文献
230.
As a result of the changes that occur during their use, used engine oils tend to differ in chemical and physical composition from a virgin oil. In general recycled oils have: much higher water and sediment levels than virgin oil; relatively higher concentrations of organic compounds (oxidation products); and relatively higher levels of metals such as Fe, Cd, Cr, Pb, etc. Therefore, the aim of this work was to investigate, assess and to observe, by means of the physical and the chemical properties of the oils, atomic absorption (AA), inductive couple plasma (ICP) and Fourier transform infrared (FTIR) analyses the extent of the differences occurring between the virgin and recycled oil. In important part of this work was also the development of analytical techniques based on the use of FTIR spectroscopy; in relation to the rapid analysis of lubricants; in particular for the differentiation of virgin and recycled oil. The results obtained were expected to be useful for differentiation purposes, providing information on whether the metal concentrations and oxidation products could be an appropriate feature for differentiating a particular oil sample from the others. This work is categorized into a two-step procedure. Firstly, an evaluation of a typical FTIR spectrum of an engine oil sample (mono- and multigrade) is presented. The broad feature centered at 1716 cm(-1) is due to the presence of carbonyl containing degradation products of oil. A band observed at 1732, 1169, 1154 and 1270 cm(-1) assigned to the polymethacrylate stretching vibrations, allows the determination of viscosity modifier and pour point depressant additives. The observed differences in the specific spectral bands (1732, 1169, 1154 and 1270 and 1716 cm(-1)) are investigated and discussed. Secondly, an analytical technique for the measurement of the levels of the wear metals is also applied. 相似文献