深圳大气PM2.5中水溶性有机物的来源特征

对2017年9月～2018年8月深圳市北部大气PM_2.5中水溶性有机物(WSOM)的质量浓度、质谱及来源结构进行测量和分析.结果表明:PM_2.5的质量浓度为(32.3±18.4)μg/m³,WSOM的质量浓度为(9.4±5.7)μg/m³,占颗粒物总有机物的(77.6%±14.0%).质谱分析显示,WSOM的氧碳比(O/C)平均值达到(0.57±0.09),属于二次有机物的O/C值范围,且生物质燃烧排放的离子碎片C₂H₄O₂⁺的丰度显著,说明WSOM的来源中有显著的生物质燃烧排放的有机气溶胶.为了明确WSOM的来源结构,利用正矩阵因子分解法(PMF)模型进行来源解析,发现3个合理因子:高氧化态有机气溶胶(MO-OOA),低氧化态有机气溶胶(LO-OOA)和生物质燃烧(BBOA),贡献比例分别为51.7%,31.8%和16.5%.MO-OOA和BBOA贡献浓度均呈现秋冬高、春夏低的季节变化特征,反向轨迹分析显示其与...     

排水造林对小兴安岭湿地土壤溶解性有机碳生物降解和淋溶的影响

以小兴安岭湿地为研究对象,分析了不同年代排水造林的森林沼泽湿地土壤溶解性有机碳(DOC)含量变化及生物降解特征,探讨了排水造林时间对土壤DOC及无机氮(NH+4-N+NO-3-N)淋溶动态变化的影响.结果表明:1排水造林时间对土壤DOC含量变化影响显著(p0.05).2003年(PS03)、1992年(PS92)、1985年(PS85)排水造林后的人工兴安落叶松湿地土壤DOC含量均低于未排水造林的天然兴安落叶松苔草湿地(XATC),且排水造林时间越长,土壤DOC含量越少.2在生物降解过程中,土壤DOC的变化趋势表现为初期降解速率较快,而后逐渐减慢并趋于稳定.其中周转时间为1 d的易降解DOC所占比重表现为:PS92XATCPS03PS85,表明排水时间达到一定阈值后,易降解DOC部分可能会转化为难降解部分.3在淋溶过程中,随着淋溶次数的增加,淋出液中DOC含量呈现为先增加后减小的趋势,淋溶1 d后,不同年代排水造林的森林沼泽湿地土壤DOC的淋失率表现为:PS85PS92PS03XATC,表明排水造林时间越长,土壤DOC淋失率越大,因此长时间的排水造林改造可能进一步影响土壤养分的贮量及其有效性.     

两种工艺对污水再生水中微量有机物的去除效果

以20种微量有机污染物为目标物,针对北京市2个再生水厂的不同工艺,系统地考察了污水再生水中目标化合物的去除效果,并采用重组酵母雌激素活性筛检法(YES法)对再生水中雌激素活性进行评价.结果表明,超滤(UF)+臭氧(O3)氧化处理工艺可有效地去除微量有机污染物,出水中雌二醇当量浓度(EEQ)低于YES法检出范围.A2/O+膜生物反应器(MBR)+反渗透(RO)处理工艺对微量有机污染物有很高的去除能力,出水中可检测出的目标化合物较少.2种工艺均可降低再生水的环境风险,保障其使用安全.     

Seasonal variation and size distribution of biogenic secondary organic aerosols at urban and continental background sites of China

Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas.     

Effects of organic matter on Leymus chinensis germination,growth, and urease activity and available nitrogen in coastal saline soil

ABSTRACT

The present study was carried out to investigate the effect of three organic matters (stalk powder, microbial fertilizer, and manure) on Leymus chinensis germination, growth, and urease activity and available nitrogen (N) in coastal saline soil. The study was conducted in a completely randomized design with eight treatments: J₀V₀Y₀, J₁V₀Y₀, J₀V₁Y₀, J₀V₀Y₁, J₁V₁Y₀, J₁V₀Y₁, J₀V₁Y₁, J₁V₁Y₁. The notations were based on the quantities of each agent added to 1 kg of coastal saline soil: J₀ – no straw powder, J₁ – 0.2 kg straw powder, Y₀ – no manure, Y₁ – 0.3 kg manure, V₀ – no microbial fertilizer, V₁ – 0.2 L microbial fertilizer, each in quantic repeat. L. chinensis was sown as 50 seeds per pot. Results indicated that addition of organic agents exerted a significantly enhanced germination, increase in fresh weight and elevated soil urease activity. Soil available N levels were significantly positively correlated with soil urease activity and fresh weight, but not with germination rate. It is noteworthy that the halophyte L. chinensis showed improved characteristics when grown in coastal saline soil with addition of organic amendments.     

红壤稻田系统有机物循环再利用潜力及增产作用

10年田间试验结果表明：红墩妥田系统有机养分循环再利用潜力大，水稻收获，年均从稻田系统中输出NPK的总量最大可达到224.7,53.0和271.4kg/hm^2，有机物循环再利用，年均可归N，P，K量最大分别为115.1,35.8和231.5kg/hm^2，占系统输总量的51.2%,67.5%g和85.3%，保持稻田系统内有机物循环再利用可提高系统生产力，在不施化肥的情况下，增产3056kg/hm^2，增施N肥，增产2753kg/hm^2，增施N，P肥，增产1543kg/hm^2；NPK配合，增产984kg/hm^2；有机物循环再利用还可增强稻田系统的稳产性能，降低稻谷产量的年际变异系数；有机物循环再利用对水稻的增产有着明显的残效叠加作用，在施用N，P，K化肥基础上圾机物养分循环再利用水稻增产率在试验期间的前5年为7．2％，后5年平均为9．4％。     

Cr(Ⅵ)污染土壤的热解还原无害化处理

提出了用热解还原法对含铬土壤进行无害化处理的新技术,研究了热解温度、热解时间及土壤有机质对铬无害化处理的影响,分析了热解前后土壤中铬的元素形态的变化.同时还探讨了热解还原过程中Cr(Ⅵ)的无害化机制.结果表明,土壤中的有机质在热解还原过程中产生的挥发分对Cr(Ⅵ)的无害化起核心作用;在200～600℃范围内,Cr(Ⅵ)的还原量随着热解温度升高而增大,500.0℃最适合于经济有效地实现Cr(Ⅵ)的热解还原处理;Cr(Ⅵ)的热解还原过程较快.铬的形态分析结果表明,热解后可交换态和碳酸盐结合态铬量大大降低,大部分铬转化成了活性低的残渣态,极大地降低了铬的危害.     

铁炭微电解预处理电路板废水

采用铁炭微电解法预处理电路板废水.结果表明,在进水pH为2.00、铁炭质量比为4:1、振荡时间为20 min的铁炭微电解静态实验最佳条件下,絮凝出水COD去除率为30%;在进水pH为2.00、铁炭质量比为4:1、水力停留时间为50 min的铁炭微电解柱动态实验最佳条件下,连续曝气.絮凝出水COD为11021 mg/L,COD去除率约为34%,BOD5/COD从0.12上升到0.32,可生化性提高,Cu2+质量浓度从9.11 mg/L下降至0.76 mg/L,降低了废水的生物毒性,为生化处理创造了条件.     

电袋复合除尘器的应用研究

针对我国燃煤电厂的除尘现状,指出电袋复合除尘器的技术经济优势.电袋复合除尘器在新建及改扩建电厂的成功应用取得了良好的经济、环境效益,并有广阔的发展前景.其研究重点是静电除尘单元和布袋除尘单元之间的结合.     

固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物

用固相微苹取(ＳＰＭＥ)－气相色谱/质谱联用法测定饮用水中苯类化合物,以１００μｍ ＰＤＭＳ(聚二甲基硅氧烷)萃取针提取、浓缩、分离与测定九种目标化合物．萃取时间经优化选定为８ｍｉｎ,而热解析时间设定为２ｍｉｎ． 本方法的相对标准偏差小于５%,线性范围宽(２０ｎｇ·ｍｌ－１－１００００ｎｇ·ｍｌ－１),多数化合物的检测限低于５μｇ·ｌ－１．饮用水样品检测显示,样品加标回收率范围在８４%至１１０%内．