全文获取类型
收费全文 | 4933篇 |
免费 | 560篇 |
国内免费 | 796篇 |
专业分类
安全科学 | 978篇 |
废物处理 | 165篇 |
环保管理 | 586篇 |
综合类 | 2770篇 |
基础理论 | 380篇 |
环境理论 | 1篇 |
污染及防治 | 441篇 |
评价与监测 | 508篇 |
社会与环境 | 192篇 |
灾害及防治 | 268篇 |
出版年
2024年 | 17篇 |
2023年 | 102篇 |
2022年 | 192篇 |
2021年 | 231篇 |
2020年 | 179篇 |
2019年 | 145篇 |
2018年 | 157篇 |
2017年 | 216篇 |
2016年 | 256篇 |
2015年 | 254篇 |
2014年 | 271篇 |
2013年 | 308篇 |
2012年 | 439篇 |
2011年 | 429篇 |
2010年 | 292篇 |
2009年 | 291篇 |
2008年 | 212篇 |
2007年 | 338篇 |
2006年 | 304篇 |
2005年 | 269篇 |
2004年 | 203篇 |
2003年 | 201篇 |
2002年 | 146篇 |
2001年 | 136篇 |
2000年 | 117篇 |
1999年 | 105篇 |
1998年 | 95篇 |
1997年 | 111篇 |
1996年 | 62篇 |
1995年 | 44篇 |
1994年 | 38篇 |
1993年 | 35篇 |
1992年 | 22篇 |
1991年 | 17篇 |
1990年 | 11篇 |
1989年 | 11篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1982年 | 1篇 |
1980年 | 4篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 4篇 |
1972年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有6289条查询结果,搜索用时 15 毫秒
341.
采用溶胶凝胶法制备LixNi1-xO和ZnO粉体,利用球磨法制备ZnO/LixNi1-xO复合粉体,以紫外光为光源,通过降解甲基橙,研究了锂掺杂及n-p复合对氧化镍的光催化性能影响。结果表明:当投放量为0.1 g/L,x≤0.075(摩尔分数)的锂掺杂氧化镍均比未掺杂氧化镍的光催化活性高。当锂掺杂摩尔分数为0.025,投放量为0.4 g/L时锂掺杂氧化镍的光催化活性最佳,甲基橙最高降解率达到93.1%。当ZnO/Li0.025Ni0.975O在质量比为1∶1,投放量为0.2 g/L时光催化活性最佳,甲基橙最高降解率达到98.1%。 相似文献
342.
343.
A hybrid method for quasi-three-dimensional slope stability analysis in a municipal solid waste landfill 总被引:1,自引:0,他引:1
Limited space for accommodating the ever increasing mounds of municipal solid waste (MSW) demands the capacity of MSW landfill be maximized by building landfills to greater heights with steeper slopes. This situation has raised concerns regarding the stability of high MSW landfills. A hybrid method for quasi-three-dimensional slope stability analysis based on the finite element stress analysis was applied in a case study at a MSW landfill in north-east Spain. Potential slides can be assumed to be located within the waste mass due to the lack of weak foundation soils and geosynthetic membranes at the landfill base. The only triggering factor of deep-seated slope failure is the higher leachate level and the relatively high and steep slope in the front. The valley-shaped geometry and layered construction procedure at the site make three-dimensional slope stability analyses necessary for this landfill. In the finite element stress analysis, variations of leachate level during construction and continuous settlement of the landfill were taken into account. The "equivalent" three-dimensional factor of safety (FoS) was computed from the individual result of the two-dimensional analysis for a series of evenly spaced cross sections within the potential sliding body. Results indicate that the hybrid method for quasi-three-dimensional slope stability analysis adopted in this paper is capable of locating roughly the spatial position of the potential sliding mass. This easy to manipulate method can serve as an engineering tool in the preliminary estimate of the FoS as well as the approximate position and extent of the potential sliding mass. The result that FoS obtained from three-dimensional analysis increases as much as 50% compared to that from two-dimensional analysis implies the significance of the three-dimensional effect for this study-case. Influences of shear parameters, time elapse after landfill closure, leachate level as well as unit weight of waste on FoS were also investigated in this paper. These sensitivity analyses serve as the guidelines of construction practices and operating procedures for the MSW landfill under study. 相似文献
344.
火电厂CO2减排技术主要包括燃烧前处理、燃烧中减排及燃烧后捕集三类。介绍了IGCC、富氧燃烧、胺吸收法、生物法等CO2捕集与封存技术,分析其存在问题及应用前景。 相似文献
345.
Karimoun M. Illyassou Rabani Adamou Bruno Schiffers 《Journal of environmental science and health. Part. B》2019,54(3):176-186
The use of pesticides in horticultural sector in Niger has become an integral part of modern agriculture. Nevertheless, their inappropriate use can generate negative health effects to operators. A study was carried out among Kongou farmers in order to assess their potential dermal exposure (PDE). The UK-POEM model was used to quantify the PDE during mixing/loading and application according to the local practices. In order to determine which parts of the operator body are subject to most contamination during spraying and to validate the theoretical model used, a patch method was used with a tartrazine dye. The deposits of the tartrazine on patches were measured by colorimetry thanks to the absorbance value determined after their extraction in water and a calibration curve. A total of ten spraying trials (five trials with the hand-held sprayer and five others with the backpack sprayer) were performed by different producers at 0.5 and 1 m height for each trial. The survey shows that 92% of the farmers are illiterate and the most common active substances identified are organophosphate or pyrethroids insecticides. Seventy percent of operators do not use any personal protective equipment (PPE) during mixing/loading or spraying. The predictive systemic exposure levels vary from 0.0027?mg kg?1 bw per day to 0.7692?mg kg?1 bw per day for backpack sprayer and from 0.0261?mg kg?1 bw per day to 0.9788?mg kg?1 bw per day for hand-held sprayer, several times higher the Acceptable Operator Exposure Level (AOEL) for some actives substances. Theoretical modeling indicates more exposure of operator by a hand-held sprayer than a backpack sprayer. The patch method results show that the deposits of dye increase when the position of sprayer nozzle increases from 0.5 to 1 m for the two sprayers. All parts of the operator body are contaminated but lower body parts and chest are the most exposed. The patch method results also show that hand spraying contaminates operator more than backpack spraying, confirming the results of the theoretical model. 相似文献
346.
采用钙基吸收剂及复合氧化剂半干法脱除模拟球团烟气中的SO_2及Hg~0,考察了多因素条件对吸收效果的影响。实验结果表明,在以NaClO和NaClO_2为复合氧化剂、 NaClO与NaClO_2体积比1∶0.5、复合氧化剂质量分数3%、反应温度110℃、钙基吸收剂质量3.0 g、模拟烟气进气流量1.2 L/min的条件下,SO_2和Hg~0的脱除率分别为98%和93%,证明钙基吸收剂与复合氧化剂对污染物球团烟气中的SO_2和Hg~0有良好的脱除作用。 相似文献
347.
用溶胶-凝胶法并通过控制煅烧温度合成不同晶相比的混合晶型纳米TiO_2,在紫外光光照下降解气相苯。考察了苯初始质量浓度、紫外灯光照强度和催化剂加入量对苯去除率的影响;探究了光催化降解气相苯的动力学特征。结果表明:450℃煅烧制备的催化剂降解苯效率最高,此催化剂金红石相质量分数为6.30%;在苯初始质量浓度为74.39 mg/m~3、催化剂加入量为7 g、光照强度为2.18 klux的最佳条件下反应84 min,苯去除率达99.73%;光催化降解率与光照强度之间符合0.5级动力学特征;当催化剂加入量为3 g时,单位时间单位质量催化剂降解苯的质量最多;苯的光催化降解反应均符合一级动力学方程。 相似文献
348.
349.
Taslim Akhtar Muhammad Ilyas Tariq Nargis Sultana Chan Kim Wei 《International Journal of Green Energy》2017,14(6):569-574
Biodiesel is now-a-days recognized as a real potential alternative to petroleum-derived diesel fuel due to its number of desirable characteristics. However, its higher production cost resulting mainly due to use of costly food-grade vegetable oils as raw materials is the major barrier to its economic viability. Present work is an attempt to explore the potential of Eriobotrya japonica seed oil for the synthesis of biodiesel using alkali-catalyzed transesterification. Optimization of production parameters, namely molar ratio of alcohol to oil, amount of catalyst, reaction time and temperature, was carried out using Taguchi method. Fatty acid composition of both oil and biodiesel was determined using GC and H1 NMR. Alcohol to oil molar ratio of 6:1, catalyst amount of 1% wt/wt, 2 h reaction time and 50 °C reaction temperature were found to be the optimum conditions for obtaining 94.52% biodiesel. Highest % contribution was shown by the ‘amount of catalyst’ (67.32%) followed by molar ratio of alcohol to oil (25.51%). Major fuel properties of E. japonica methyl esters produced under optimum conditions were found within the specified limits of ASTM D6751 for biodiesel, hence it may be considered a prospective substitute of petro-diesel. 相似文献
350.
建立了金属冶炼进口物料的固体废物鉴别方法,并利用该方法对海关查扣的3种金属冶炼进口物料进行了固体废物鉴别。鉴别结果显示:物料1、2和3的自然属性分别为砷含量超标铜精矿、锰阳极泥、回转窑氧化锌,产生来源分别为有害物质超标的产品、污染控制设施产生的物质、有意识加工的目标产物;物料1和2属于我国禁止进口的固体废物,物料3不属于固体废物。本文建立的固体废物鉴别方法可行,可为金属冶炼进口物料的固体废物鉴别和监管提供参考。 相似文献