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141.
Synthesis of poly(hydroxyalkanoate) from hydrolyzed linseed oil 总被引:3,自引:0,他引:3
Elena Casini Theo C. de Rijk Pieter de Waard Gerrit Eggink 《Journal of Polymers and the Environment》1997,5(3):153-158
Pseudomonas putida was grown on a mixture of long-chain fatty acids obtained by hydrolysis of linseed oil. A poly(3-hydroxyalkanoate) containing
51.2% of unsaturated monomers was obtained. A considerable percentage (13.6%) was constituted by C14 and C16 monomers containing three double-bonds in the side chains. The polymer showed a high tendency to crosslink when it was kept
in presence of air. In the crosslinked polymer no polyunsaturated monomers could be detected. 相似文献
142.
Tohru Kamo Kanji Takaoka Junichiro Otomo Hiroshi Takahashi 《Journal of Material Cycles and Waste Management》2006,8(2):109-115
Steam gasification of dehydrochlorinated poly(vinyl chloride) (PVC) or activated carbon was carried out in the presence of
various alkali compounds at 3.0 MPa and 560°C–660°C in a batch reactor or in a semi-batch reactor with a flow of nitrogen
and steam. Hydrogen and sodium carbonate were the main products, and methane and carbon dioxide were the minor products. Yields
of hydrogen were high in the presence of sodium hydroxide and potassium hydroxide. The acceleration effect of the alkali compounds
on the gasification reaction was as follows: KOH > NaOH > Ca(OH)2 > Na2CO3. The rate of gasification increased with increasing partial steam pressure and NaOH/C molar ratio. However, the rate became
saturated at a molar ratio of NaOH/C greater than 2.0. 相似文献
143.
针对仪化热电厂将循环水用作冲灰水,导致浓缩倍率只有1.6,以及凝汽器铜管腐蚀结垢严重等问题,提出了隔断循环水与冲灰水的直接联系,实现闲路循环,对凝汽器铜管进行酸洗,并对循环水实施加缓蚀阻垢荆、杀菌剂和旁流过滤等办法,全部实施后产生了很好的效益,值得借鉴。 相似文献
144.
玉米芯为碳源实现酸性矿山废水生物处理 总被引:9,自引:0,他引:9
引入了一种新的碳源——玉米芯,对SRB法处理酸性矿山废水进行了更加深入的探索,分析了各种参数条件对s暖一还原效果的影响,确定了常温下这种碳源所需要的最适宜工况条件,探讨了硫酸盐矿山废水的水质资源化问题,并对山西矿山废水的生物治理进行了可行性实验验证。实验证明,玉米芯为碳源时,矿山废水中SO^2-4的出水值可达221.1mg/L,金属离子的浓度也都达到了生活饮用水的质量标准,所以玉米芯可作为酸性矿山废水资源化生物处理的合适有效碳源。 相似文献
145.
楼静 《中国环境管理干部学院学报》2004,14(3):38-39
利用由O2和Fenton试剂组成的类Fenton系统处理对氨基苯磺酸废水,取得了很好的降解效果.当FeSO4(10g/L)投加量为1.2mL、H2O2(3%)投加量为3mL时,COD去除率可达到70%. 相似文献
146.
Nugraha E. Suyatma Alain Copinet Lan Tighzert Veronique Coma 《Journal of Polymers and the Environment》2004,12(1):1-6
Biodegradable film blends of chitosan with poly(lactic acid) (PLA) were prepared by solution mixing and film casting. The main goal of these blends is to improve the water vapor barrier of chitosan by blending it with a hydrophobic biodegradable polymer from renewable resources. Mechanical properties of obtained films were assessed by tensile test. Thermal properties, water barrier properties, and water sensitivity were studied by differential scanning calorimeter analysis, water vapor permeability measurements, and surface-angle contact tests, respectively. The incorporation of PLA to chitosan improved the water barrier properties and decreased the water sensitivity of chitosan film. However, the tensile strength and elastic modulus of chitosan decreased with the addition of PLA. Mechanical and thermal properties revealed that chitosan and PLA blends are incompatible, consistent with the results of Fourier transform infrared (FTIR) analysis that showed the absence of specific interaction between chitosan and PLA. 相似文献
147.
本文分析了金沙江对硫酸的缓冲特征,建立了江水的缓冲曲线方程,并且验证了此方程的有效性,证明用此方程预测硫酸进入金沙江后江水pH值的变化情况,其预测准确度在0.2个pH单位内。 相似文献
148.
Effects of planned expansion of waste incineration in the Swedish district heating systems 总被引:1,自引:0,他引:1
Recent targets for reduced amounts of waste to landfills in Sweden will result in a large increase in waste incineration with recovery of energy, used primarily for district heating. The aim of this study is to investigate what changes in the usage of other fuels and technologies for district heat production would be caused by this increase. A questionnaire was sent out to the largest district heating companies, and simulations in an energy systems model were carried out. The analysis shows that increased waste incineration reduces the demand for other fuels, especially biomass, for district heat production. The effects include reductions in operating hours as well as the avoidance or postponement of investments in new plants for district heat production. Increased waste incineration will also lead to a greater use of district heating in Sweden. 相似文献
149.
150.
E.V. Antonakou K.G. Kalogiannis S.D. Stephanidis K.S. Triantafyllidis A.A. Lappas D.S. Achilias 《Waste management (New York, N.Y.)》2014,34(12):2487-2493
Pyrolysis appears to be a promising recycling process since it could convert the disposed polymers to hydrocarbon based fuels or various useful chemicals. In the current study, two model polymers found in WEEEs, namely polycarbonate (PC) and high impact polystyrene (HIPS) and their counterparts found in waste commercial Compact Discs (CDs) were pyrolysed in a bench scale reactor. Both, thermal pyrolysis and pyrolysis in the presence of two catalytic materials (basic MgO and acidic ZSM-5 zeolite) was performed for all four types of polymers. Results have shown significant recovery of the monomers and valuable chemicals (phenols in the case of PC and aromatic hydrocarbons in the case of HIPS), while catalysts seem to decrease the selectivity towards the monomers and enhance the selectivity towards other desirable compounds. 相似文献