Fluoride removal by a continuous flow electrocoagulation reactor

Long-term consumption of water containing excessive fluoride can lead to fluorosis of the teeth and bones. Electrocoagulation (EC) is an electrochemical technique, in which a variety of unwanted dissolved particles and suspended matter can be effectively removed from an aqueous solution by electrolysis. Continuous flow experiments with monopolar aluminium electrodes for fluoride removal were undertaken to investigate the effects of the different parameters such as: current density (12.5-50A/m(2)), flow rate (150-400 mL/min), initial pH (4-8), and initial fluoride concentration (5-25mg/L). The highest treatment efficiency was obtained for the largest current and the removal efficiency was found to be dependent on the current density, the flow rate and the initial fluoride concentration when the final pH ranged between 6 and 8. The composition of the sludge produced was analysed using the X-ray diffraction (XRD) spectrum. The strong presence of the aluminium hydroxide [Al(OH)(3)] in the above pH range, which maximizes the formation of aluminium fluoride hydroxide complex [Al(n)F(m)(OH)(3n-m)], is the main reason for defluoridation by electrocoagulation. The results obtained showed that the continuous flow electrocoagulation technology is an effective process for defluoridation of potable water supplies and could also be utilized for the defluoridation of industrial wastewater.     

Analysis of pollution status of River Illo,Ota, Nigeria

An assessment of the pollution status of River Illo, located within River Owo catchments area in Ota, Ogun State, Nigeria, was carried out. The River’s response to deoxygenation due to BOD loading from an abattoir and its dissolved oxygen (DO) level was predicted using the modified Streeter-Phelps model. The average concentrations of measured parameters at the sampling stations include: 2.24 mg/l of DO, 312.85 mg/l of BOD, 782.86 mg/l of chemical oxygen demand, and 620.76 g/l of total solids. The DO model for River Illo showed a positive correlation between measured and calculated DO, while the dissolved oxygen curve gave a double spoon shape of two major segments with distinct zones of degradation, decomposition, and recovery. The self-purification factor (f) for both segments ranged between 0.8 and 1.1 depicting River Illo as a slow moving or sluggish river. The above results revealed slow reaeration of the water body while full recovery from pollution was difficult. The treatment of River Illo before usage is very essential to ensure public health safety of users from waterborne diseases.     

A Cost-Effectiveness Analysis of Seminatural Wetlands and Activated Sludge Wastewater-Treatment Systems

A cost-effectiveness analysis was performed to evaluate the competitiveness of seminatural Free Water Surface (FWS) wetlands compared to traditional wastewater-treatment plants. Six scenarios of the service costs of three FWS wetlands and three different wastewater-treatment plants based on active sludge processes were compared. The six scenarios were all equally effective in their wastewater-treatment capacity. The service costs were estimated using real accounting data from an experimental wetland and by means of a market survey. Some assumptions had to be made to perform the analysis. A reference wastewater situation was established to solve the problem of the different levels of dilution that characterize the inflow water of the different systems; the land purchase cost was excluded from the analysis, considering the use of public land as shared social services, and an equal life span for both seminatural and traditional wastewater-treatment plants was set. The results suggest that seminatural systems are competitive with traditional biotechnological systems, with an average service cost improvement of 2.1-fold to 8-fold, according to the specific solution and discount rate. The main improvement factor was the lower maintenance cost of the seminatural systems, due to the self-regulating, low artificial energy inputs and the absence of waste to be disposed. In this work, only the waste-treatment capacity of wetlands was considered as a parameter for the economic competitiveness analysis. Other goods/services and environmental benefits provided by FWS wetlands were not considered.

Current and Future Strategies for Water and Wastewater Management of Istanbul City

Istanbul has experienced rapid increases in population to more than 12 million people, which has created infrastructure problems of water supply and wastewater treatment and disposal. In this article, the achievements and approaches of the Istanbul Water and Sewerage Administration (ISKI) to solve the water shortage problem and to improve services are summarized. Istanbul had a very severe water shortage problem in 1994 because of ignorance of the implementation of the needed projects. After reviewing the reasons and causes of the problem, new priority criteria adopted after 1994 are given. Following the implementation of the projects determined according to the aforementioned criteria, water supplied has exceeded the water demand. The added capacity is equal to one to three times of the capacity built up to 1994 for water treatment, service reservoirs, pumping stations, transmission lines, and the water distribution network; water quality has been improved the meet local and international potable water standards. Unaccounted for water has been reduced from 60% to 27%. The percentage of treated wastewater has been increased from 10% to 90% in 8 years, resulting in drastic improvements and rehabilitation of the Golden Horn and coastal water quality. Through improved customer services, complaints were reduced from 33% in 1994 to 0.3%. Some of the main criteria and the approaches behind this success are summarized. Published online     

Influence of organic loading on an anaerobic sequencing biofilm batch reactor (ASBBR) as a function of cycle period and wastewater concentration

The effect of organic loading on the performance of a mechanically stirred anaerobic sequencing biofilm batch reactor (ASBBR) has been investigated, by varying influent concentration and cycle period. For microbial immobilization 1-cm polyurethane foam cubes were used. An agitation rate of 500 rpm and temperature of 30+/-2 degrees C were employed. Organic loading rates (OLR) of 1.5-6.0gCODl(-1)d(-1) were applied to the 6.3-l reactor treating 2.0 l synthetic wastewater in 8 and 12-h batches and at concentrations of 500-2000mgCODl(-1), making it possible to analyze the effect of these two operation variables for the same organic loading range. Microbial immobilization on inert support maintained approximately 60 gTVS in the reactor. Filtered sample organic COD removal efficiencies ranged from 73 to 88% for organic loading up to 5.4gCODl(-1)d(-1). For higher organic loading (influent concentration of 2000mgCODl(-1) and 8-h cycle) the system presented total volatile acids accumulation, which reduced organics removal efficiency down to 55%. In this way, ASBBR with immobilized biomass was shown to be efficient for organic removal at organic loading rates of up to 5.4gCODl(-1)d(-1) and to be more stable to organic loading variations for 12-h cycles. This reactor might be an alternative to intermittent systems as it possesses greater operational flexibility. It might also be an alternative to batch systems suspended with microorganisms since it eliminates both the uncertainties regarding granulation and the time necessary for biomass sedimentation, hence reducing the total cycle period.     

污水处理磷回收的研究进展

磷矿数量减少与含磷污水造成的水体富营养化问题对磷资源的可持续利用提出了迫切要求。从污水处理的不同环节回收磷并重新利用,是实现磷资源循环利用的有效途径。本文讨论了国内外磷回收技术的研究进展和应用实例,包括从含磷污泥和富磷污水中回收磷的工艺,并对磷回收的技术经济性进行了分析。     

Degradation of polycyclic aromatic hydrocarbons by combined chemical pre-oxidation and bioremediation in creosote contaminated soil

The ability of pre-oxidation to overcome polycyclic aromatic hydrocarbons (PAH) recalcitrance to biodegradation was investigated in creosote contaminated soil. Sand and peat artificially spiked with creosote (quality WEI C) were used as model systems. Ozonation and Fenton-like treatment were proved to be feasible technologies for PAH degradation in soil. The efficiency of ozonation was strongly dependent on the water content of treated soil samples. The removal of PAH by Fenton-like treatment depended on the applied H2O2/soil weight ratio and ferrous ions addition. It was determined that the application of chemical oxidation in sand resulted in a higher PAH removal and required lower oxidant (ozone, hydrogen peroxide) doses. The enhancement of PAH biodegradability by different pre-treatment technologies also depended on the soil matrix. It was ascertained that combined chemical and biological treatment was more efficient in PAH elimination in creosote contaminated soil than either one alone. Thus, the combination of Fenton-like and the subsequent biological treatment resulted in the highest removal of PAH in creosote contaminated sand, and biodegradation with pre-ozonation was found to be the most effective technology for PAH elimination in peat.     

Chemical fluxes in time through forest ecosystems in the UK - Soil response to pollution recovery

Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored.     

Stock market responses to chemical accidents in Japan: An event study

Despite recent major chemical process accidents in Japan, the top management teams of firms still avoid taking costly risk reduction measures because of their low perceived impact on firm performance. The disclosure of information on accident risks might motivate managers to enhance workplace safety because of the subsequent evaluation of firms by investors in stock markets. If the disclosed risk information is newly available for investors, firms with a high risk of accidents would receive a poor evaluation by stock markets and thus managers would take risk reduction measures to prevent stock prices from declining. In this study, we conduct an event study analysis to examine whether accident risk information is already reflected in stock prices, using data on the Japanese chemical industry. The results of our event study show that the estimated cumulative average abnormal returns of firms' stocks are significantly negative after severe accidents actually occurred. This finding implies that risk information is not already reflected in the stock prices of Japanese chemical firms and that the disclosure of accident risk information has the potential to motivate the top management teams of firms to reduce their firms’ accident risk.     

改性脲醛树脂絮凝浮选剂在污水处理中的应用

用尿素和甲醛作为主要原料合成脲醛树脂季胺盐和脲醛树脂叔胺盐。采用ＷＥＭＣＯ浮选模型机和自行设计的模拟现场充气浮选的气浮设备及现场污水对絮凝浮选剂除油、除悬浮物的性能进行了评价。另外，用核磁共振和红外光谱测定了脲醛树脂叔胺盐的结构，并用凝胶色谱法测定了其分子量。