全文获取类型
收费全文 | 19386篇 |
免费 | 1374篇 |
国内免费 | 3618篇 |
专业分类
安全科学 | 2392篇 |
废物处理 | 169篇 |
环保管理 | 2923篇 |
综合类 | 11125篇 |
基础理论 | 2082篇 |
环境理论 | 11篇 |
污染及防治 | 1416篇 |
评价与监测 | 1114篇 |
社会与环境 | 2013篇 |
灾害及防治 | 1133篇 |
出版年
2024年 | 90篇 |
2023年 | 335篇 |
2022年 | 588篇 |
2021年 | 664篇 |
2020年 | 637篇 |
2019年 | 600篇 |
2018年 | 512篇 |
2017年 | 688篇 |
2016年 | 829篇 |
2015年 | 906篇 |
2014年 | 848篇 |
2013年 | 1085篇 |
2012年 | 1331篇 |
2011年 | 1482篇 |
2010年 | 1064篇 |
2009年 | 1061篇 |
2008年 | 887篇 |
2007年 | 1301篇 |
2006年 | 1317篇 |
2005年 | 1058篇 |
2004年 | 872篇 |
2003年 | 949篇 |
2002年 | 778篇 |
2001年 | 661篇 |
2000年 | 622篇 |
1999年 | 583篇 |
1998年 | 449篇 |
1997年 | 350篇 |
1996年 | 286篇 |
1995年 | 270篇 |
1994年 | 261篇 |
1993年 | 221篇 |
1992年 | 163篇 |
1991年 | 136篇 |
1990年 | 92篇 |
1989年 | 49篇 |
1988年 | 50篇 |
1987年 | 28篇 |
1986年 | 30篇 |
1985年 | 36篇 |
1984年 | 19篇 |
1983年 | 24篇 |
1982年 | 22篇 |
1981年 | 20篇 |
1980年 | 20篇 |
1979年 | 24篇 |
1978年 | 12篇 |
1977年 | 15篇 |
1973年 | 13篇 |
1971年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
Ge Sun Changqing Zuo Shiyu Liu Mingliang Liu Steven G. McNulty James M. Vose 《Journal of the American Water Resources Association》2008,44(5):1164-1175
Abstract: Natural forests in southern China have been severely logged due to high human demand for timber, food, and fuels during the past century, but are recovering in the past decade. The objective of this study was to investigate how vegetation cover changes in composition and structure affected the water budgets of a 9.6‐km2 Dakeng watershed located in a humid subtropical mountainous region in southern China. We analyzed 27 years (i.e., 1967‐1993) of streamflow and climate data and associated vegetation cover change in the watershed. Land use/land cover census and Normalized Difference of Vegetation Index (NDVI) data derived from remote sensing were used to construct historic land cover change patterns. We found that over the period of record, annual streamflow (Q) and runoff/precipitation ratio did not change significantly, nor did the climatic variables, including air temperature, Hamon’s potential evapotranspiration (ET), pan evaporation, sunshine hours, and radiation. However, annual ET estimated as the differences between P and Q showed a statistically significant increasing trend. Overall, the NDVI of the watershed had a significant increasing trend in the peak spring growing season. This study concluded that watershed ecosystem ET increased as the vegetation cover shifted from low stock forests to shrub and grasslands that had higher ET rates. A conceptual model was developed for the study watershed to describe the vegetation cover‐streamflow relationships during a 50‐year time frame. This paper highlighted the importance of eco‐physiologically based studies in understanding transitory, nonstationary effects of deforestation or forestation on watershed water balances. 相似文献
102.
103.
Impacts on industry of Europe's emerging chemicals policy REACh 总被引:1,自引:0,他引:1
For Europe, a new regime in chemicals regulation is about to start. After the proposal of the European Commission concerning the Registration, Evaluation and Authorization of Chemicals (REACh) passed its readings in the European Parliament and some differences with the European Council of Ministers were resolved, the regulation will come into force in June 2007. This paper is focused on the question how serious the cost burdens for industry induced by REACh will be, and whether the New European Member States (NMS) which joined the European Union in May 2004 will be able to cope with the regulation. This evaluation has been done by assessing the legislative, administrative and economic framework in New Member States and by analysing real business cases in companies. The empirical showcase business impact studies are at the same time of interest for companies of EU-15 states, other European countries who may implement the regulation, and even for exporters of raw materials and chemicals outside Europe, who will also have to comply with REACh if they market in the European Community. The results give no indications that REACh adoption will bring significant drawbacks to companies in the NMS. The emerging regulation will bring challenges for individual companies, especially for small and medium-sized ones, but for the European chemical industry as a whole, there is no question that it will be able to cope with REACh burdens without losing its global competitiveness. 相似文献
104.
Yu FC Chen CY Lin SC Lin YC Wu SY Cheung KW 《Environmental monitoring and assessment》2007,132(1-3):419-428
As the embodiment of human activities, the change of regional industrial structure is an essential driving factor of global
environmental change. Consequently, the research on the change of regional industrial structure and associated effects on
the environment is one of the key issues of researches on sustainable development, human–environment relationship, and regional
response to global environment change. However, compared to the flourish of researches on environmental impact assessment
of industrial departments, few studies have been conducted to assess the environmental impact of regional industrial structure.
In this study, based on a synthetic analysis of environmental disturbances of different industrial departments, the environmental
impact coefficient of industrial department associated with the index of environmental impact of industrial structure was
constructed, so as to make a quantitative assessment of environmental impact of the change of regional industrial structure.
And the results of the case study in Lijiang City, a rural region of China, have showed that there are two obvious changes
of industrial structure in the study area from 1992 to 2003, associated with a continuous decreasing of the index of environmental
impact of industrial structure, which indicated a positive environmental effects of the change of regional industrial structure. 相似文献
105.
106.
107.
It is established that the activity of marmots (the genusMarmota) on the surface is timed to the daylight period. In the Arctic, under conditions of continuous illumination (the polar day),
the diurnal rhythm of black-capped marmotsMarmota camtschatica bungei on the surface has a “daylight” pattern. The main external regulator of the diurnal rhythm is the altitude of the sun above
the horizon. In the cold period, however, the effect of air temperature on animal activity becomes stronger. 相似文献
108.
底泥中重金属毒性的室内孔隙水分析技术 总被引:1,自引:0,他引:1
根据孔隙水中重金属的浓度可以判定底泥中重金属的毒性但获得真正的底泥孔隙水十分困难。本文提供了一套简便易行的室内原状孔隙水取样技术,将碳化硅砂芯埋入底泥,添加表层水并静置90d,通过渗滤获得孔隙水,测定孔隙水中重的浓度,所得结果与微生态系统暴露试验中生物指示的重金属的毒性大小相吻合,与生物积累重金属的浓度显著正相关。 相似文献
109.
聚苯乙烯基硫代磺酸钾树脂的合成及其与卤代烃的反应 总被引:2,自引:2,他引:0
由聚苯乙烯基磺酰氯树脂与硫化氢钾反应制备聚苯乙烯基硫代磺酸钾树脂(I),树脂I与亲电的卤代烃反应,生成聚苯乙烯基硫代磺酸酯树脂(Ⅱ),树脂Ⅱ经过乙硫醇处理,使卤代烃结构部分以不对称二硫醚的形式游离下来,用GC/MS对其结构进行鉴定。从不对称二硫醚的结构可推导出原卤代烃的结构,所制备的聚苯乙烯基硫代磺酸钾树脂的转化效率为1.11mmol·g^-1。 相似文献
110.
Samaratunga SS Nishimoto J Tabata M 《Environmental science and pollution research international》2008,15(1):27-30
BACKGROUND, AIMS AND SCOPE: Chromium enters into the aquatic environment as a result of effluent discharge from steel works, electroplating, leather tanning industries and chemical industries. As the Cr(VI) is very harmful to living organisms, it should be quickly removed from the environment when it happens to be contaminated. Therefore, the aim of this laboratory research was to develop a rapid, simple and adaptable solvent extraction system to quantitatively remove Cr(VI) from polluted waters. METHODS: Aqueous salt-solutions containing Cr(VI) as CrO4(2-) at ppm level (4-6 ppm) were prepared. Equal volumes (5 ml) of aqueous and organic (2-PrOH) phases were mixed in a 10 ml centrifuge tube for 15 min, centrifuged and separated. Concentrations of Cr(VI), in both the aqueous and organic phases, were determined by atomic absorption spectrometry. The effects of salt and acid concentrations, and phase-contact time on the extraction of Cr(VI) were investigated. In addition, the extraction of Cr(VI) was assessed in the presence of tetramethylammonium chloride (TMAC) in 2-PrOH phase. Effects of some other metals, (Cd(II), Co(II), Cu(II), Ni(II) and Zn(II)), on the extraction of Cr(VI) were also investigated. RESULTS AND DISCUSSION: The Cr(VI) at ppm level was extracted quantitatively by salting-out the homogeneous system of water and 2-propanol(2-PrOH) using chloride salts, namely CaCl2 or NaCl, under acidic chloride media. The extracted chemical species of Cr(VI) was confirmed to be the CrO3Cl-. The ion-pair complex extracted into the organic phase was rationalized as the solvated ion-pair complex of [2-PrOH2+, CrO3Cl-]. The complex was no longer stable. It implied the reaction between extracted species. Studies revealed that salts and acid directly participated in the formation of the above complex. Use of extracting agents (TMAC) didn't show any significant effect on the extraction of Cr(VI) under high salting-out conditions. There is no significant interference effect on the extraction of Cr(VI) by the presence of other metals. The Cr(VI) in the organic phase was back-extracted using an aqueous ammonia solution (1.6 mol dm(-3)) containing 3 mol dm(-3) NaCl. The extraction mechanism of Cr(VI) is also discussed. CONCLUSIONS: Salting-out of homogeneous mixed solvent of 2-propanol can be employed to extract Cr(VI) quantitatively, as an ion-pair of [2-PrOH2+ * CrO3Cl-] solvated by 2-PrOH molecules. Then, the complex becomes 'solvent-like' and is readily separated into the organic phase. The increase of Cl- ion concentration in the aqueous phase favors the extraction. The 2-PrOH, salts and acid play important roles in the extraction process. There is no need to use an extracting agent at a high salting-out condition. RECOMMENDATIONS AND PERSPECTIVES: Chromium(VI) must be quickly removed before it enters into the natural cycle. As the 2-PrOH is water-miscible in any proportion, ion-pairing between 2-PrOH2+ and CrO3Cl- becomes very fast. As a result, Cr(VI) can easily be extracted. Therefore, the method is recommended as a simple, rapid and adaptable method to quickly separate Cr(VI) from aqueous samples. 相似文献