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151.
Enhanced removal of ethylbenzene from gas streams in biotrickling filters by Tween-20 and Zn(II) 总被引:4,自引:0,他引:4
Lu Wang Chunping Yang Yan Cheng Jian Huang Haining Yang Guangming Zeng Li Lu Shanying He 《环境科学学报(英文版)》2014,26(12):2500-2507
The effects of Tween-20 and Zn(II) on ethylbenzene removal were evaluated using two biotrickling filters(BTFs), BTF1 and BTF2. Only BTF1 was fed with Tween-20 and Zn(II).Results show that ethylbenzene removal decreased from 94% to 69% for BTF1 and from 74%to 54% for BTF2 with increased organic loading from 64.8 to 189.0 g ethylbenzene/(m3·hr) at EBRT of 40 sec. The effect of EBRT(60–15 sec) at a constant ethylbenzene inlet concentration was more significant than that of EBRT(30–10 sec) at a constant organic loading. Biomass accumulation rate within packing media was reduced significantly. 相似文献
152.
正A wetland with attractive plants hosting birds and other wildlife is an esthetically pleasing prospect that is gaining popularity as a way of stabilizing or remediating metalcontaminated soils and sediment(Weber and Gagnon,2014; 相似文献
153.
154.
Totally dry cleaning has become a common technology for top gas cleaning in blast furnaces in recent years. A significant advantage of totally dry gas cleaning is that the dust collected is obtained as dry powder, thus simplifying the recycling of the dust in the sinter plant and avoiding aqueous emissions. The concentration of some heavy metals, especially zinc, in the collected dust is usually higher than the maximum tolerable concentration for recycling to the sinter process. Therefore, a process for separation of dust with a low level of contamination from the rest is necessary to make partial recycling possible. This is possible because the limited components are more volatile and accumulate in the finer dust fraction. In wet blast furnace top gas cleaning, hydrocyclones are well established for this separation. For the separation of dry powder from the dry dedusting process air classification can be used. Dust from the top gas of a blast furnace with a fabric filter for dry top gas cleaning was split into several size fractions using a laboratory air classifier. The concentration of Ca, Cd, Cl, Cu, Fe, K, Na, Pb and Zn was analysed for each particle class and the loss on ignition was determined. A strong dependence of the concentration on the particle size was found for the more volatile metals, whereas the Fe and Ca concentration and the loss on ignition were quite evenly distributed. With the calculated recovery–removal-functions the possible recycling rate can be estimated for a given removal rate for the limited components. 相似文献
155.
Sequential extractions of metals can be useful to study metal distributions in various soil fractions. Although several sequential extraction procedures have been suggested in the literature, most were developed for temperate soils and may not be suitable for tropical soils with high contents of Mn and Fe oxides. The objective of this study was to develop a sequential fractionation procedure for Cu and Zn in tropical soils. Extractions were performed on surface (0–20 cm) samples of ten representative soils of Sao Paulo State, Brazil. Chemically reactive Mn forms were satisfactorily assessed by the new modified procedure. Amorphous and crystalline Fe oxides were more selectively extracted in a new two-step extraction. Soil-born Zn and Cu were primarily associated with recalcitrant soil fractions. The proposed procedure provided more detailed information on metal distribution in tropical soils and better characterization of the various components of the soil matrix. The new procedure is expected to be an important tool for predicting the potential effects of environmental changes and land application of metals on the redistribution of chemical forms of metals in tropical soils. 相似文献
156.
Xiangyang Bi Xinbin Feng Yuangen Yang Grace P.Y. Shin Guangle Qiu Taoze Liu 《Environmental pollution (Barking, Essex : 1987)》2009,157(3):834-839
Plants grown in contaminated areas may accumulate trace metals to a toxic level via their roots and/or leaves. In the present study, we investigated the distribution and sources of Pb and Cd in maize plants (Zea mays L.) grown in a typical zinc smelting impacted area of southwestern China. Results showed that the smelting activities caused significantly elevated concentrations of Pb and Cd in the surrounding soils and maize plants. Pb isotope data revealed that the foliar uptake of atmospheric Pb was the dominant pathway for Pb to the leaf and grain tissues of maize, while Pb in the stalk and root tissues was mainly derived from root uptake. The ratio of Pb to Cd concentrations in the plants indicated that Cd had a different behavior from Pb, with most Cd in the maize plants coming from the soil via root uptake. 相似文献
157.
David Eugene Kimbrough 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1310-1316
A natural experiment indicated that a link between the presence and concentration of four elements, copper, lead, nickel, and zinc in the influent to two wastewater reclamation plants to the presence and concentrations of the same four elements in the tap water of residential properties. There were 36 populations of results that were assessed for the normality of their distribution, the difference in their median concentrations, the similarity in the ratios of their median concentrations, and the correlations of the concentrations. The results of this study suggest that brass corrosion is the major source of these four elements in the water reclamation plants influent and that there are two distinct populations of brass sources, those in the early stages of dezincification where the release of the non-copper elements is dominant and those in the later stages where the release of copper dominates and the type of brass that is corroding. 相似文献
158.
The transfer of Cd and Zn from soils amended with sewage sludge was followed through a food chain consisting of wheat, aphids and the predator Coccinella septempunctata. Multiple regression models were generated to predict the concentrations of Cd and Zn in C. septempunctata. No significant model could be generated for Cd, indicting that the concentration of this metal was maintained within relatively narrow limits. A model predicting 64% of the variability in the Zn concentration of C. septempunctata was generated from of the concentration of Zn in the diet, time and rate of Zn consumption. The results suggest that decreasing the rate of food consumption is an effective mechanism to prevent the accumulation of Zn and that the availability of Zn in the aphid prey increased with the concentration in the aphids. The results emphasise the importance of using ecologically relevant food chains and exposure pathways during ecotoxicological studies. 相似文献
159.
Maxted AP Black CR West HM Crout NM McGrath SP Young SD 《Environmental pollution (Barking, Essex : 1987)》2007,150(3):363-372
The objectives of this study were to assess the potential for using Thlaspi caerulescens as a phytoextraction plant and develop a user-advice model, which can predict the frequency of phytoextraction operation required under prescribed conditions. Pot and field trials were conducted using soil collected from a dedicated sewage sludge disposal facility. Soil amendments (sulphuric acid, potassium chloride and EDTA) intended to increase Cd solubility were also tested. Predictive models of Cd and Zn uptake were developed which were able to reproduce the observed pH-dependence of Cd uptake with an apparent maximum around pH 6. Chemical treatments did not significantly increase the uptake of Cd. The periodic use of phytoextraction with T. caerulescens to maintain soils below statutory metal concentration limits, when modern sewage sludges are repeatedly applied, seems very attractive given the non-intrusive and cost-effective nature of the process. The major limitations lie with the large-scale husbandry of T. caerulescens. 相似文献
160.
试验了溴代十六烷基吡啶、正丁醇、正庚烷、水自制微乳溶液体系中,锌与二溴邻硝基偶氮胂的显色反应,建立了分光光度法测定水中锌的方法。在pH值为3.0的乙酸-乙酸钠缓冲溶液中,锌与试剂形成淡红色配合物,其最大吸收峰位于532nm波长处,表观摩尔吸光系数F为1.87×10^5L/(mol·cm)。在显色液中锌的质量浓度在0.003mg/L-0.350mg/L范围内符合比尔定律,检出限为0.001mg/L,水样中锌测定的RSD为1.3%-2.9%,加标回收率为95.7%-102%。 相似文献