柱色谱法批量分离N-甲基-2-(3-硝基苯基)吡咯烷[3’,4’:1,2][60]富勒烯研究

经C60、N-甲基甘氨酸和间硝基苯甲醛反应得到N-甲基-2-(3-硝基苯基)吡咯烷[3′,4′∶1,2][60]富勒烯(MNPF)反应液,旋转蒸发干燥得质量分数为23%的MNPF粗品,采用柱色谱法批量分离其中的MNPF。确定了柱色谱法批量分离MNPF的最佳工艺条件:二硫化碳为流动相,柱层析用硅胶(37~48μm)为固定相,色谱柱直径5cm,高径比为6∶1,最大上样量为23 g。此时分离所得MNPF纯度达99%,回收率为92.3%。     

水果蔬菜中有机磷农药残留量的气相色谱测定方法研究

建立了水果、蔬菜食品中有机磷农药的提取、净化及其毛细管柱气相色谱测定法.用水和丙酮溶剂提取,填有无水Na2SO4和Al2O3的层析柱净化,浓缩后采用火焰离子化检测器(FID)检测到样品中甲胺磷、对硫磷、马拉硫磷、甲基对硫磷的添加回收率分别为81%～90%,82%～90%,84%～102%,80%～90%,变异系数均小于8.0%.实验表明,该方法在一定条件下具有灵敏度高,净化效果好,适用性广等特点,可以作为一种常规测定方法.     

长江下游地区新近沉积土动剪切模量比和阻尼比的试验研究

通过对长江下游地区南京、苏州、常州、徐州、泰州、盐城、扬州、无锡、镇江、张家港、连云港、启东、常熟、江阴、宿迁等15个城市的淤泥质粉质粘土、粘土、粉质粘土、粉质粘土与粉砂互层土、粉土、粉细砂和粗砂等七类新近沉积土共计275个原装土样历时3年的自振柱试验研究,给出了长江下游地区七类新近沉积土的动剪切模量比 G/Gmax和阻尼比λ与剪应变幅值γ变化的平均曲线的拟合曲线、包络线及其参数的推荐值。由于未见报道其他研究者对长江下游地区新近沉积土动力参数的系统研究,该研究成果有利于加深对该长江下游地区各类新近沉积土动力特性的认识,并对该地区各类工程建设的工程场地地震安全性评价工作具有一定的借鉴和参考价值,且有利于推动长江下游地区工程场地地震安全性评价工作的开展。     

矿化垃圾柱吸附能力预测模型

建立数学模型对矿化垃圾柱的吸附能力进行理论预测。通过改变模型参数得到矿化垃圾柱的不同吸附穿透曲线，分析穿透曲线的变化规律，判定参数的优劣，确定垃圾柱吸附运行最优工况。为矿化垃圾柱的设计提供一定的理论依据。     

钢筋混凝土柱的耐火极限研究

编制了钢筋混凝土柱高温反应的全过程分析程序,程序的有效性得到了其他学者试验结果的验证。针对不同轴压比、截面尺寸、配筋率和荷载偏心率共480种工况进行了钢筋混凝土柱的高温反应分析,揭示了各主要参数对钢筋混凝土柱耐火极限的影响规律。在计算结果的基础上,定量给出了钢筋混凝土柱耐火极限的简化确定方法。研究结果表明:配筋率对轴压柱的耐火极限影响不大;严格控制轴压比和荷载偏心率是提高轴压柱和偏压柱耐火极限的有效措施。     

采用内支撑的深基坑支护施工技术及安全

论述了用工程桩加支承桁架来代替内支撑支承桩的施工技术、安全及经济价值。     

中空夹层钢管再生混凝土柱火灾后力学性能分析

基于ABAQUS建立中空夹层钢管再生混凝土短柱理论模型,进行受火后加载模拟,受火过程采用ISO-834标准升、降温曲线。进而探究柱构件在受火全过程中的温度分布规律和受火后的力学性能。并分析了受火时间、空心率、取代率、名义含钢率、钢管强度和混凝土强度等参数对柱构件剩余承载力的影响。结果表明:受火时间、含钢率、混凝土强度和钢材强度对构件剩余承载力影响较明显,空心率和取代率对构件剩余承载力影响较小;受火45 min和90 min后,空心率取33.90%能较大限度减轻构件自重,且具备良好的抗火性能。     

Steam cavity and explosion intensity of molten copper column interaction with water

The steam explosion is one of the most serious accidents in the metallurgical industry. In this paper, an experimental study on the interaction of molten copper column with cooling water was carried out using high-speed camera and transient pressure measurement system. The effects of temperature, falling height, diameter and mass of molten copper column on the interaction were investigated. The steam cavity phenomenon was observed in the interaction and the percentage of steam cavity volume affects the probability of fragmentation of molten copper column. The maximum percentage of steam cavity volume increases firstly and then decreases with the increase of temperature and falling height. It increases with the increase of diameter of molten copper column, but the mass has a weak effect. The pressure wave generated by the interaction of molten copper column with cooling water gradually increases with an increase in the temperature of molten copper column. The energy conversion rate in the interaction of molten copper column with cooling water was calculated. The rate of energy conversion from the thermal energy of molten copper column to the energy of pressure wave is low because most of the thermal energy is dissipated into the cooling water by heat transfer.     

A laboratory scale study on arsenic（Ⅴ） removal from aqueous medium using calcined bauxite ore

The present work deals with the As（Ⅴ） removal from an aqueous medium by calcined refractory grade bauxite （CRB） as a function of solution pH, time, As（Ⅴ） concentration and temperature. The residual As（Ⅴ） was lowered from 2 mg/L to below 0.01 mg/L in the optimum pH range 4.0-7.0 using a 5 g/L CRB within 3 h contact time. The adsorption data fits well with Langmuir isotherm and yielded Langmuir monolayer capacity of 1.78 mg As（Ⅴ）/g of CRB at pH 7.0. Presence of anions such as silicate and phosphate decreased As（Ⅴ） adsorption efficiency. An increase temperature resulted a decrease in the amount of As（Ⅴ） adsorbed by 6%. The continuous fixed bed column study showed that at the adsorbent bed depth of 30 cm and residence time of 168 min, the CRB was capable of treating 340 bed volumes of As（V） spiked water （C0 = 2 mg/L） before breakthrough （Ce = 0.01 mg/L）. This solid adsorbent, although not reusable, can be considered for design of adsorption columns as an efficiency arsenic adsorption media.