全文获取类型
收费全文 | 394篇 |
免费 | 40篇 |
国内免费 | 94篇 |
专业分类
安全科学 | 83篇 |
废物处理 | 11篇 |
环保管理 | 42篇 |
综合类 | 233篇 |
基础理论 | 38篇 |
污染及防治 | 50篇 |
评价与监测 | 44篇 |
社会与环境 | 10篇 |
灾害及防治 | 17篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 13篇 |
2021年 | 13篇 |
2020年 | 14篇 |
2019年 | 11篇 |
2018年 | 9篇 |
2017年 | 16篇 |
2016年 | 20篇 |
2015年 | 15篇 |
2014年 | 20篇 |
2013年 | 33篇 |
2012年 | 33篇 |
2011年 | 35篇 |
2010年 | 27篇 |
2009年 | 21篇 |
2008年 | 25篇 |
2007年 | 37篇 |
2006年 | 21篇 |
2005年 | 27篇 |
2004年 | 14篇 |
2003年 | 12篇 |
2002年 | 14篇 |
2001年 | 9篇 |
2000年 | 8篇 |
1999年 | 10篇 |
1998年 | 15篇 |
1997年 | 12篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有528条查询结果,搜索用时 31 毫秒
101.
Decolorization and biodegradation of dye wastewaters by a facultative-aerobic process 总被引:1,自引:0,他引:1
BACKGROUND: Dye wastewater is one of the main pollution sources of water bodies in China. Conventional biological processes are relatively ineffective for color removal, the development of alternative treatment methods will become important. Our subjective was that of introducing a new biotreatment technology which combined a facultative biofilm reactor (FBR) with an aerobic reactor (AR) to treat a dye wastewater. The efficiencies of color and chemical oxygen demand (COD) removal and the mechanism of dye degradation were investigated. METHODS: The anthraquinone acid dye (acid blue BRLL) concentration, organic loading rate (OLR) and hydraulic retention time (HRT) were varied in the experiments to evaluate the treatment efficiency and process stability. The biodegradation products were detected by infrared (IR) and high performance liquid chromatography and mass spectrometry (HPLC-MS). RESULTS AND DISCUSSION: The results demonstrated that the facultative biofilm process was more effective for decolorization than the anaerobic stage of an anaerobic-aerobic process. Most color removal occurred in the facultative reaction (maximum to 88.5%) and the BOD (biochemical oxygen demand): COD of the FBR effluent increased by 82.2%, thus improving the biodegradability of dyes for further aerobic treatment. The dye concentration, OLR and HRT will be the factors affecting decolorization. Color removal efficiency falls as the influent dye concentration increases, but rises with increased HRT. The infrared and HPLC-MS analyses of the effluents of FBR and AR reveal that the dye parent compound was degraded in each reactor during the process. CONCLUSION: The Facultative-aerobic (F-A) system can effectively remove both color and COD from the dye wastewater. The FBR played an essential role in the process. The average overall color and COD in the system were removed by more than 93.9% and 97.1%, respectively, at an OLR of 1.1 kg COD m(-3) d(-1) and at the HRT of 18-20 hours in the FBR and 4-5 hours in the AR. The color removal mechanism in each reactor was not only a sort of biosorption on the floc materials, but even more an effect of biodegradation, especially in the facultative process. Recommendation and Outlook. In applying the F-A system to treat a dye wastewater, the control of facultative processes and the set up of appropriate operation conditions appear to be critical factors. Also, it is suggested a moderate COD loading rate and about a 24-hour HRT will favor the F-A system. 相似文献
102.
焦化厂生化出水电解脱色工艺及其机理的初步研究 总被引:4,自引:0,他引:4
针对焦化废水经萃取(蒸氨)脱酚和生化处理后的出水水质的特点,研究用铝板作为电极电解该废水的脱色效果,研究了废水pH、电解槽电压、时间等因素对其色度去除率的影响。结果表明,最佳工艺参数为:pH=4、电解槽电压=10V、时间=30min,此时色度去除率可达93.6%,COD的去除率也可以达到61.78%。采用GC—MS分析了电解前后废水中的有机物成分,探讨了形成高色度水质的原因、有机物的去除及脱色机理。 相似文献
103.
104.
新型聚铝硅复合絮凝剂的制备及性能研究 总被引:33,自引:0,他引:33
本文初步制备了两种新型聚铝硅复合絮凝剂:聚铝硅(含活化硅酸聚合铝,PACSi)和聚硅铝(聚硅酸硫酸铝,PSiAS),研究对比了PACSi,PSiAS与PAC的絮凝性能。考察了硅酸聚合程度,硅、铝含量对其絮凝性能的影响,结果表明,提高硅酸聚合程度或硅、铝含量的增加均有利于增强絮凝性能,且随(Si)/(Al)比值的提高,其絮凝性能也明显增加,在铝含量相同情况下,聚铝硅和聚硅铝的絮凝性能均优于聚合氯化铝 相似文献
105.
Reactive Red 195, which is an azoic anionic dye characterized by the presence of five sulfonic groups and one azoic group, is efficiently removed using chitosan. The increasing chitosan dose had a dramatic positive impact on the achieved color removal, there was approximately a linear relationship between chitosan dose and color removal of dye before color removal reach maximum. Also, the increase of dye concentration led to the increase of chitosan dosage in order to get the same color remova l.92 mg/L of chitosan dosage was sufficient to achieve complete remove of dye at initial concentration of dye at 200 mg/L. For the higher concentrations of dye, high dosages were necessary to reach complete color removal. On the other hand, the use of adsorption interferents(Fe^2+ , Na^+ , HCO3^- and others) can be interesting, addition of ions had effect on the color removal of Reactive Red 195. Comparing with blank, addition of chemical species approximately decreased the color removal except Na^+ and combination of Fe^2+ + HCO3^- . However, comparing with Fe^2+ alone and HCO3^- alone, combination of Fe^2+ + HCO3^- increased the color removal. 相似文献
106.
祁连山区水资源及其对河西走廊生态环境的影响 总被引:10,自引:2,他引:10
根据甘肃省河西地区石羊河、黑河和疏勒河三大内陆水系的祁连山区流域水资源和出山径流量,详细地计算了河西走廊各县市绿洲的实际年水资源。从生态平衡角度出发,确定了各县市绿洲和农田的生态需水量。据此,计算出基本能保持各县市自然生态平衡的绿洲和农田的适宜面积。 相似文献
107.
强化A2/O工艺反硝化除磷性能的运行控制策略 总被引:10,自引:2,他引:10
以啤酒废水为研究对象,重点考察了如何强化A2/O工艺反硝化除磷性能,从而提高营养物去除效果、并实现节能的目的.试验中建立了3种运行控制策略:(1)根据缺氧区末端出水硝酸盐的浓度控制内循环回流量;(2)调节厌氧/缺氧/好氧区体积比以减少厌氧区出水剩余COD对缺氧磷吸收的影响;(3)向缺氧区引入旁流并调节旁流比.试验结果表明,当缺氧区末端出水硝酸盐浓度控制在1~3 mg·L-1时,不仅可强化反硝化除磷效果,而且可以节省内循环所需能耗;厌氧/缺氧/好氧区最佳体积比为1/1/2;旁流的引入可以提高低C/N比条件下TN的去除,最优旁流比为0.32. 相似文献
108.
根据非稳定热传导基本方程式积分得到离散化方程式,编写出计算程序,利用计算机求出复合板在热处理过程中各结点随时间而变化的温度,绘出等温线,以研究复合板经升温固化处理后的理想冷却方法. 相似文献
109.
110.
营养源对活性艳红脱色降解体系的影响研究 总被引:2,自引:1,他引:2
选择活性艳红X-3B为脱色和降解对象,将白腐真菌固定在生化填料上构建白腐真菌生物膜反应器,并以接种活性污泥的生物膜反应器为对照,考察了营养源对活性艳红脱色降解的影响。实验表明,对白腐真菌Shu-13采用查氏培养基预培养和在反应器中投加适量蔗糖及酱油废水,均能明显提高活性艳红X-3B的脱色率。城市污水中的营养源,不足以满足白腐真菌对活性艳红X-3B的脱色降解需要,白腐真菌Shu-13对富氮条件存在依赖性。在富营养条件下,白腐真菌Shu-13生物膜反应器对活性艳红X-3B的脱色效果明显优于活性污泥。营养源及其浓度、菌种是影响pH变化的重要因素,活性污泥和酱油曲霉生物膜反应器的出水pH变化规律,与Shu-13存在明显不同,Shu-13对活性艳红X-3B的脱色过程中发生了明显的降解作用,而这种作用对生物膜恢复其污染物净化功能是至关重要。另外,酱油废水中存在的酱油曲霉属于半知菌纲的白腐真菌,其对活性艳红X-3B也有较显著的脱色降解效果。 相似文献