新型污染物风险防范国际实践及其对中国的启示

随着重化工业的快速发展和各类化学品的大量使用,一些新型污染物对中国居民和生态环境的危害正逐步显现并日趋严重。如何进一步完善中国新型污染物的风险防范体系,是中国生态环境治理面临的重要问题。发达国家新型污染物的风险防范工作启动较早,对中国完善新型污染物风险防范体系具有重要的借鉴意义。本文从制度建设、体制机制、评估监测、科学研究等方面比较国内外新型污染物风险防范实践的异同,立足我国国情,发现国内实践还需加强之处。在此基础上,提出国际新型污染物风险防范实践对中国的启示。     

An LC-MS/MS method for creatine and creatinine analysis in paraquat-intoxicated patients

Abstract

A sudden increase in serum creatinine after paraquat intoxication has been reported in several clinical studies. However, this dramatic change of creatinine may be possibly due to an interconversion of creatine-creatinine in relation to paraquat toxicity. In order to investigate the creatine-creatinine relationship, a liquid chromatography tandem mass spectrometry in combination with electrospray ionization was developed and validated for simultaneous determination of creatine and creatinine in the serum. The chromatographic separation was achieved on a Gemini® C₆-Phenyl column with a gradient elution consisting of 0.1% formic acid in ultrapure water and methanol as the mobile phase. The method yielded suitable levels of specificity and selectivity, and calibration curves of creatine and creatinine in serum were linear over the concentration range of 0.5–200?µg mL^?1. The limit of quantification of both compounds was 0.5?µg mL^?1, and the method was accurate within the recovery range of 96.23–102.75%, indicating the robustness of the method. The method was successfully applied to toxicological samples from paraquat-intoxicated patients, and the concentrations of creatine and creatinine were quantified. High creatine concentrations in serum samples were observed which may lead to high serum creatinine despite normal kidney function as creatine is converted to creatinine in proportion to its concentration.     

基于稳健统计方法对实验室比对中土壤汞的质量控制指标研究

利用稳健四分位间距法和迭代法2种稳健统计方法,通过对全国31个省、自治区、直辖市范围内共334家环境监测单位开展土壤中汞的实验室间比对,对比对测定结果和质控数据进行统计分析,系统性地研究了土壤中汞的质量控制指标。建议实际监测工作中土壤汞的实验室间相对标准偏差范围为7%～19%,相对误差控制指标为±8%,低浓度水平下可适当放宽至±10%,加标回收率控制范围为81%～109%,为日常监测开展土壤汞的质量控制工作提供了评价依据,具有广泛的应用价值和较好的指导作用。     

机械冲击振打扁袋和脉冲圆袋除尘器性能对比

对脉冲对反吹圆袋除尘器和机械冲击振打扁袋除尘器进行了数字计算和分析对比,显示前者落后,后者先进,并对空气净化除尘及可预计的节能降耗目标进行了粗估。     

中国低碳发展的国际比较研究——基于历史和经济发展阶段的审视

随着近年来我国碳排放总量的增加,一些西方国家开始把碳减排责任的矛头指向中国。为了明确中国碳排放的国际地位,运用历史唯物主义观点,从经济发展阶段视角进行了国际比较研究。首先运用IEA2011年公布的碳排放数据分析了我国2009年面临的碳排放形势,继而研究了工业革命以来中国碳排放的总体贡献情况,最后从经济发展阶段视角进行了国际比较研究。认为:①尽管我国当前的碳排放总量巨大,但人均碳排放量低于世界前10名的主要碳排放国家,碳排放强度与世界主要碳排放国家相比还存在一定差距;②我国的历史累计碳排放贡献及人均碳排放均较低,发达国家和地区的累计碳排放量达到世界累计碳排放量的近3/4;③与发达国家相同经济发展阶段相比,我国的人均碳排放和碳排放强度远低于主要发达国家和地区;④世界主要发达国家和地区在快速推进工业化的经济发展阶段普遍伴随着高碳排放。鉴于此,我们认为应该辩证地看待中国的碳排放,一方面中国当前的确产生了较大的碳排放,另一方面中国的经济发展阶段决定了这种碳排放规模和水平。发达国家的经济发展轨迹和碳足迹也表明,在工业化快速推进的过程中,一定程度的高碳排放是世界经济发展的客观规律。     

中国低碳发展的国际比较:世界贸易格局

近年来随着我国经济的持续平稳快速发展,与之相伴随的碳排放总量持续攀升,中国也因此被推上世界碳减排的风口浪尖.为了明确中国碳排放的国际地位,本文从世界贸易格局视角对中国的碳排放现状进行了国际比较研究.首先分析研究了我国2007年面临的碳排放国际形势,继而对我国的出口贸易形势进行了国际比较,最后采用GDP比例法和类推法对我国商品出口隐含的碳排放进行了初步测算,并分析了剔除出口贸易影响后的我国碳排放情况.通过研究认为:①出口贸易对我国的碳排放总量影响巨大,我国的商品出口占GDP比例长期维持在20%以上,近几年高峰值超过36%;②在当前的世界贸易格局、国际分工体系下,采用“生产者责任体系”碳排放测算模式大大高估了中国的碳排放水平,中国的碳排放总量中有34-60%是为他国服务而产生;③中国在当前世界贸易格局和国际分工体系中的地位使得中国在目前的碳排放测算模式下必然“产生较高的碳排放”;④世界各国应该重新审视和正确认识中国的“高”碳排放形势,中国为世界各国提供商品服务而产生的碳排放不应该受到指责.     

Assessing inter-laboratory comparability and limits of determination for the analysis of cyclic volatile methyl siloxanes in whole Rainbow Trout (Oncorhynchus mykiss)

Cyclic volatile methyl siloxanes (cVMS) are high volume production chemicals used in a wide range of industrial and consumer products. Three cVMS compounds (D4, D5, and D6) have and are undergoing environmental risk evaluations in several countries and have been proposed for legal regulation in Canada. As interest in monitoring concentrations of these chemicals in the environment increase, there is a need to evaluate the analytical procedures for cVMS in biological matrices in order to assess the quality of data produced. The purpose of this study was to determine laboratory testing performance for measuring residues of D4, D5, and D6 in a standard set of fish homogenate samples and to estimate limits of determination for each substance. The samples sent to each laboratory consisted of homogenized whole body tissues of hatchery raised rainbow trout which were fed food fortified with D4, D5, and D6 (dosed) and trout that were fed standard food rations (control). The participants analyzed each sample using their analytical method of choice using their own standards and procedures for quantification and quality control. With a few exceptions, participating laboratories generated comparable results for D4, D5, and D6 in both the dosed and control samples having z-scores between 2 and −2. Method detection limits for the whole fish matrix were on average 2.4 ng g⁻¹ ww for D4, 2.3 ng g⁻¹ ww for D5, and 1.8 ng g⁻¹ ww for D6.     

中美职业安全健康法对比

通过对中美职业安全健康立法目的和背景的考察,对比分析职业安全健康法涉及的6项具体内容,即体例结构、适用范围、监管方式、监管体制、教育与培训、法律责任,并指出国情不同是造成中美职业安全健康法立法巨大差异的原因之一。经对比分析,可得出几点结论:从中国国情出发,走逐步完善的职业安全健康立法路径,建立独立的职业安全健康法律体系,是我国安全生产的治本之策;对从业人员的职业安全健康保护具有首要性,须明晰保护劳动者的上层法律要求,《安全生产法》并不能代替《职业安全健康法》;完善中国职业安全健康法律制度须走一体化整合的道路。     

Evidence of new particle formation during post monsoon season over a high-altitude site of the Western Ghats,India

The formation of ultrafine particles, their growth, and associated characteristic features has been studied during new particle formation events over a high-altitude station of the Western Ghats during the 2014 post-monsoon season. Most of the events were observed during noon time where particle bursts in the nucleation-mode size range from 5 to 25 nm followed by sustained growth in size. This phenomenon persists for ～4–8 h with a growth rate of 1–2 nm h^–1. Peak concentrations of nucleation-mode particles during the event generally vary from 2300 to 5000 cm^–3. The mean growth rate is 1.4 ± 0.42 nm h^–1, particle formation rate is 1.14 ± 0.22 cm^–3 s^–1, coagulation sink is 0.35 ± 0.22 cm^–3 s^–1, and condensational sink is 15.4 ± 2.6?×?10^–3 s^–1. All these values are comparable with earlier results from Indian region. Comparison of size-segregated particle number concentration during days of new particle formation events and those without new particle formation were carried out showing a distinct variation in nucleation and Aitken mode with least variability associated with the accumulation mode.     

城市污水污泥发酵制园林营养土中微生物的变化分析

通过桶装发酵装置,进行城市污水污泥发酵制园林营养土过程中微生物的变化研究,测试不同好氧-厌氧交替组的发酵温度以及细菌、真菌、放线菌数量等的变化,探讨发酵温度与微生物变化的规律.结果表明,夏季不同发酵方式的发酵温度在50℃以上的持续时间均长于冬季,且夏季好氧-厌氧交替发酵的发酵温度在55℃以上的持续时间长于好氧发酵;冬季与夏季的好氧、好氧-厌氧交替发酵后,堆料中的粪大肠菌群数量均达到了《城镇污水处理厂污泥处置园林绿化用泥质》(CJ 248-2007)的卫生学指标要求;夏季好氧-厌氧交替发酵过程中,厌氧后发酵温度有所下降,好氧后发酵温度又有所回升;无论好氧还是好氧～厌氧交替发酵中,细菌均为优势种群,真菌、放线菌数量比细菌数量低2～6个数量级.