山东省电力资源空间格局及环境成本分析

基于复杂网络理论,对山东省电力网络空间结构、分布特征进行了分析.结果发现：受资源禀赋的影响,山东省电力输出端主要分布在鲁西南地区,输入端主要集中在中东部重工业城市;电力网络拓扑结构具有较小的聚类系数和较大的平均路径长度,度分布呈现出不完全幂律分布,具有向无标度网络演化的特征;受电源结构的影响,各地市发电环境成本差异较大,尤其与火电发电规模紧密联系.     

朱溪流域植被覆盖的时空变化及地形分异特征

分析2003~2011年朱溪流域植被覆盖的时空分布状况及其变化的地形响应特征,为该地区进一步治理水土流失和生态恢复工程提供决策支持。基于RS和GIS技术,采用像元二分法模型计算植被覆盖度,通过植被重心模型、地形响应指数表征其植被覆盖的时空变化规律。(1)朱溪流域植被覆盖度整体呈上升趋势,Ⅳ、Ⅴ类的植被覆盖面积比率已达到区域的62.28%;格局动态上,Ⅰ、Ⅱ类重心向东北方向移动,Ⅲ、Ⅳ、Ⅴ类重心向西南方向移动,表现为流域植被中、西部改善,东部零散退化的空间格局;(2)在海拔0~300m、坡度小于5°和大于35°区域各等级植被覆盖面积变化最显著,治理措施有效到位,而海拔450~500m处I类植被覆盖面积增加,应引起相关注意。8年间该流域植被覆盖有明显改善,各等级植被覆盖变化在不同地形条件下差异明显。     

Effect of iron ion configurations on Ni2+ removal in electrocoagulation

Electrocoagulation (EC) has been widely used to treat the heavy metal wastewater in industry. A novel process of sinusoidal alternating current electrocoagulation (SACC) is adopted to remove Ni²⁺ in wastewater in this study. The morphology of precipitates and the distribution of the main functional iron configurations were investigated. Ferron timed complex spectroscopy can identify the monomeric iron configurations [Fe(a)], oligomeric iron configurations [Fe(b)] and polymeric iron configurations [Fe(c)]. The optimal operating conditions of SACC process were determined through single-factor experiments. The maximum Ni²⁺ removal efficiency [Re(Ni²⁺)] was achieved under the conditions of pH₀=7, current density (j) = 7 A/m², electrolysis time (t) = 25 min, c₀(Ni²⁺) = 100 mg/L. At pH=7, the proportion of Fe(b) and Fe(c) in the system was 50.4 at.% and 23.1 at.%, respectively. In the SACC process, Fe(b) and Fe(c) are the main iron configurations in solution, while Fe(c) are the vast majority of the iron configurations in the direct current electrocoagulation (DCC) process. Re(Ni²⁺) is 99.56% for SACC and 98.75% for DCC under the same optimum conditions, respectively. The precipitates produced by SACC have a high proportion of Fe(b) configurations with spherical α-FeOOH and γ-FeOOH structures which contain abundant hydroxyl groups. Moreover, it is demonstrated that Fe(b) has better adsorption capacity than Fe(c) through adsorption experiments of methyl orange (MO) dye. Fe(a) configurations in the homogeneous solution had no effect on the removal of nickel.     

Solubility products of six metal‐glyphosate complexes in water and forestry soils,and their influence on glyphosate toxicity to plants

Abstract

The solubility products (K_sp) of 1:1 complexes of glyphosate, [N‐(phosphonomethyl)glycine], with Mg²⁺, Ca²⁺, Mn²⁺, Zn²⁺, Cu²⁺ and Fe³⁺, were determined in buffered (pH 7.0) distilled water, moist Ottawa sand, sandy loam and clay loam soils, each adjusted to 0.02 M with respect to KNO₃. The K_sp values decreased in the order of Mg ? Ca > Mn > Zn > Cu > Fe, regardless of the medium in which they were determined. The constants measured in Ottawa sand were similar to those in water, but those in the forestry soils depended upon the type of metal ion involved. The values for the Mg, Ca, Mn and Zn complexes were about 2 to 3 times lower in sandy loam soil than those in water, but those in clay loam were about 3 to 10 times lower. The K_sp of the Cu and Fe complexes were similar to those in water regardless of the soil type used.

In a bioassay experiment using tomato plants, immersed in the saturated solutions of the complexes or planted in the sand and soils containing saturated solutions of the complexes, no mortality occurred although slight inhibition in growth was observed in all cases. The most soluble complexes of Mg and Ca caused the most reduction in plant height, while the least soluble complex of Fe caused little growth inhibition. The Zn, Cu and Mn complexes caused some growth inhibition depending on their K_sp values. The larger the solubility product, the greater the concentration of glyphosate ion in solution, and the greater the growth inhibition. In a similar experiment using white spruce seedlings, growth inhibition was insignificant over the 12‐d bioassay period.     

灾后承接非政府组织援助系统工程的综合集成模式——以汶川8.0级地震为例

分析了承接非政府组织(NGO)援助复杂巨系统的框架结构、时空结构、运行结构及整体特性;提出了地震灾后承接援助系统工程的综合集成模式;分别就承接援建集成工程的运作模式和具体实施框架进行了讨论;就援建系统工程、迎建系统工程、应急组织系统工程和保障系统工程等具体实施工程做了细致的阐述。     

土壤-植物系统中模拟酸雨与Cd复合污染的短期环境效应--黄豆盆栽试验

通过盆栽实验,研究了在黄豆(Glycne max)的一个生长周期内,模拟酸雨与Cd复合污染对土壤基本性质的影响,模拟酸雨作用下土壤-植物系统中Cd的迁移转化规律以及模拟酸雨与Cd复合污染对黄豆生长与生理特性的影响,探讨了土壤-植物系统中这种复合污染的短期环境效应.结果表明,短期内模拟酸雨和Cd污染对土壤-植物系统都有致害作用,但Cd污染的效应大于模拟酸雨的效应,模拟酸雨与Cd复合污染环境效应大于这2种污染物的单因素效应,且表现出明显的协同作用.在本试验条件下,pH值为3.5的模拟酸雨和20 mg·kg-1Cd的处理组合对土壤-植物系统的危害最严重.尽管在短期内,协同作用仅在土壤交换态Cd含量、黄豆茎和根中的Cd含量这3项指标上得到一定程度的体现,但这种复合污染的化学机制和环境效应值得关注,这2种污染物长时期共同作用对土壤-植物系统的影响也值得深入研究.     

FE型电袋复合除尘器在大型燃煤机组上的应用

介绍了FE型电袋复合除尘器的特点,以及其在大型燃煤机组上的应用情况,运行结果显示,该新型除尘器不仅可以满足更高的排放要求,而且可以长期稳定运行,并对细微粉尘有更好的捕集效果;可从根本上解决大型燃煤机组粉尘排放的难题。     

平原地区复合土地利用系统中氮磷流失敏感区界定

为正确识别平原地区复合土地利用系统中氮磷流失敏感区，利用美国农业部水土保持局设计的水文模型中的〖WTBX〗CN〖WTBZ〗值描述地表状况，反映不同土地利用条件下下垫面对土壤氮、磷流失的影响；运用等标污染负荷计算方法评估不同类型污染源强度；建立了复合土地利用系统中土壤氮、磷流失敏感区的综合指数评价体系。构建的氮、磷流失评价方法在浙江大学华家池校区的应用评价结果表明，氮磷流失敏感性高的区块主要为研究区内的居民区、畜牧场和一些施肥量大的种植区，而敏感性最低的区块集中在具有良好植被覆盖的绿化区。高的污染源和高的迁移因子叠加区构成了高的流失敏感区.