Quantitative characterization of Cu binding potential of dissolved organic matter （DOM） in sediment from Taihu Lake using multiple techniques

Dissolved organic matter （DOM） plays an important role in heavy metal speciation and distribution in the aquatic environment especially for eutrophic lakes which have higher DOM concentration. Taihu Lake is the third largest freshwater and a high eutrophic lake in the downstream of the Yangtze River, China. In the lake, frequent breakout of algae blooms greatly increased the concentration of different organic matters in the lake sediment. In this study, sediment samples were collected from various part of Taihu Lake to explore the spatial difference in the binding potential of DOM with Cu. The titration experiment was adopted to quantitatively characterize the interaction between Cu（II） and DOM extracted from Taihu Lake sediments using ion selective electrode （ISE） and fluorescence quenching technology. The ISE results showed that the exogenous DOM had higher binding ability than endogenous DOM, and DOM derived from aquatic macrophytes had a higher binding ability than that derived from algae. The fluorescence quenching results indicated that humic substances played a key role in the complexation between DOM and Cu（II） in the lake. However, because of the frequent breakout of algae blooms, protein-like matters are also main component like hnmic matters in Taihu Lake. Therefore, the metals bound by protein-like substances should be caused concern as protein-like substances in DOM were unstable and they will release bound metal when decomposed.     

步行街在城市地下综合体中防火分隔的应用

城市地下综合体在大型城市中迅猛发展,而现行防火规范中对其商业部分防火分隔的要求难以满足设计需求。结合城市地下综合体的建筑特点,提出将采取加强消防设计的步行街作为防火分隔的措施,以某城市地下综合体为例,通过理论分析与数值模拟的方法,证明了该防火分隔方案能够达到现行防火规范要求的分隔效果。     

柠檬酸-施氏矿物复合体对Cd和Pb的吸附研究

施氏矿物(Schwertmannite)是酸性矿区废水污染环境中典型的铁硫酸盐次生矿物,由于其较好的吸附能力成为矿区多种重金属的沉积库.环境中同时广泛存在着各种有机质,易与矿物结合形成有机质矿物复合体,从而影响矿物对重金属的吸附行为.目前关于有机质与施氏矿物形成的复合体对重金属的吸附研究相对较少.因此,本研究选取柠檬酸作为天然有机质的代表,研究不同环境条件下柠檬酸施氏矿物复合体对重金属Cd、Pb的吸附.结果表明,复合体保持着施氏矿物基本的矿物学特征,对重金属Cd和Pb的吸附行为表现出不同的趋势:复合体对Cd的吸附量整体上随着Cd浓度和pH值的升高而上升;相反,复合体对Pb的吸附量均比纯施氏矿物要低,并且随着柠檬酸含量的升高吸附量下降越明显;体系中共存的硫酸根离子(SO₄^2-)抑制了复合体对Cd的吸附,而对Pb的吸附则起到促进作用.XRD分析表明柠檬酸抑制了高pH下Pb在矿物表面形成PbSO₄沉淀.FTIR红外谱图进一步证明结合在复合体上的柠檬酸参与了对Cd和Pb的吸附过程.本研究结果有助于更好地预测Cd和Pb在矿区的迁移和归宿.     

商业综合体人员密度调查与分析

人员密度是建筑疏散设计的基础,而商业综合体人员密度具有一定的特点。运用黑箱理论模型及统计学相关知识,建立了商业综合体人员密度计算模型。结合两个典型商业综合体实例的调查数据,获得了商业综合体人员密度、每天不同时段的人员密度分布规律以及工作日、休息日和节假日的平均人员密度比值;提出了相应的消防管理措施。结果表明:商业综合体的人员密度小于现行规范推荐值,可为商业综合体安全疏散设计提供参考。     

海底管道泄漏风险演化复杂网络分析

为了控制海底管道泄漏连锁风险,基于复杂网络,提出针对管道系统泄漏演化的半定量风险演化评价方法,将复杂的事故风险发展过程转化为简洁的网络分析计算。首先,构建包含30个风险节点与54条连接边的海底管道泄漏演化复杂网络模型;其次,采用无权有向网络中的节点出入度和聚类系数进行风险分析,确定影响管道泄漏的关键节点,提出断链控制方案;最后,将演化模型转化为带权的有向网络,采用Dijkstra算法计算各初始事件导致泄漏事故的最短路径。结果表明:海底管道系统泄漏网络的聚类系数为0.13,网络聚集程度偏低而演化性较强;各初始事件的最短路径均不超过10,表现出明显的小世界网络特征,初始事件的风险经少数几步传递即可导致泄漏事故的发生。海底管道泄漏风险演化规律的研究可为抑制初始事件、控制传递事件和减轻后果事件提供理论依据,对预防海底管道泄漏事故发生、保障管道持续安全运行具有现实意义。     

水生植物复合系统处理富营养化水体的初步研究

根据水生植物不同的生活型,设计建造了由漂浮、浮叶植物组成的水生植物复合生态系统,并在洋河水库进行了动态模拟试验,从群落水平研究了多种水生植物镶嵌组合的复合系统对富营养化水体的净化效果.结果表明:富营养化水体在流经该系统之后水中的TN、TP、NH4 -N、NO3--N、PO43--P被有效地去除,对藻类也有很好抑制、截留作用,使水质和水体透明度得到改善.通过实践,水力停留时间3d时对水体有较好的净化效果.     

地质灾害控灾因素的遥感地质分析--以藏南拉轨岗日地区为例

以实地调研数据为基础,在综合分析TM影像所提供的空间及光谱信息之后认为:(1)拉轨岗日变质核杂岩带通过其接触带中的断裂体系直接控制相应的地质灾害,通过所形成的构造地貌和特征水系对地质灾害的孕育、规模和强度产生间接影响;(2)拉轨岗日变质核杂岩带各个组成变质核杂岩的接触带及其外延的盖层区域因受构造变动的影响而成为崩塌、滑坡和泥石流等地质灾害的易发区域;(3)研究拉轨岗日变质核杂岩带的结构形式及成因模式可对地质灾害易发区域的圈绘起到指导作用.     

A 'Principled' Approach to Complex Emergencies: Testing a New Aid Delivery Model in the Nuba Mountains

This paper provides an analysis of the Nuba Mountains Programme Advancing Conflict Trans-formation (NMPACT) as an example of an operational response in a complex emergency that innovatively addressed an incipient food security crisis. NMPACT is notable for having brought together an array of actors around a common principled agenda and for being the only operational programme in the Sudan to which both warring parties subscribed during the conflict. The key features of the programme are presented and the main innovative elements are reviewed, including the role of the principles of engagement and the 'political humanitarianism' of NMPACT. The paper looks at how NMPACT broke from traditional externally driven responses to food insecurity, and, drawing on lessons from Operation Lifeline Sudan, adopted an approach that focuses on capacity building, sustainable agriculture and market revitalisation, alongside conflict transformation and peace-building. The limitations of the model are also assessed, and preliminary lessons regarding its replication in other complex emergency contexts are presented.     

Ferron逐时络合比色法研究聚硅硫酸铁中铁的形态

通过实验制备了一种新型无机高分子絮凝剂聚硅硫酸铁（PFSS），用Ferron逐时络合比色法测定了PFSS中铁的形态，考察了熟化时间、Fe3+／SiO2摩尔比对铁的形态分布及转化规律的影响。不同Fe3+／SiO2摩尔比的PFSS中Fe（a）的量最多、占50％以上，Fe（c）在35％～50％之间，Fe（b）在0～5％之间。研究表明：铁的形态分布及其转化规律与溶液的高酸度及聚硅酸的存在有关。     

A COLORIMETRIC METHOD FOR THE DETERMINATION OF TRACE COPPER CONCENTRATIONS IN WATER1

Trace quantities of copper (II) ion can be found in natural water as waste products from industrial, mining, and agricultural operations. Because low concentrations of copper can be toxic to plant life, many workers have devised methods of analysis for this metal in water. These methods require expensive equipment and skilled technicians. The described study illustrates a simple method in which copper (II) ion is concentrated by a batch ion exchange technique and estimated colorimetrically after formation of the blue triethylenetetramine complex. Using the visible absorption peak of the complex at 600 nm it was possible to obtain accurate estimations of original copper concentrations in the range 0.5-3 ppm. Using the complex absorption peak at 260 nm in the ultra-violet region of the spectrum increased the sensitivity by a factor of twenty. Because of the dependence of the complex formation reaction on solution acidity it is possible to optimize conditions for the detection of copper (II) in the presence of other metal ions. This type of method, which could be extended to the analysis of other metal ions, could be performed by a relatively unskilled technician under field conditions.