铜及其与四环素的联合暴露对斑马鱼胚胎的毒性效应

近年来工业和养殖业中铜和四环素的滥用,导致了一定的水环境污染问题。为探究铜与四环素对水生生物的毒害作用,选择斑马鱼作为受试生物,研究了铜及其与四环素的联合暴露对斑马鱼胚胎的毒性效应,并进一步探索了其可能的致毒机制。结果表明：铜在低浓度下（10%致死浓度LC10=2.5 μg?L-1,10%效应浓度EC10=0.1 μg?L-1）明显延迟了斑马鱼胚胎的孵化、卵黄囊吸收、头部、鱼鳔和体长等生长指标的发育,同时在心脏区域引起明显细胞凋亡效应。幼鱼体内总铜含量检测结果显示低浓度下铜的生物利用度相对更高。基因表达结果显示环境浓度的铜可能通过影响神经和心脏相关基因的表达引起斑马鱼胚胎的神经发育和心脏发育异常。铜和四环素的联合暴露实验结果表明二者的复合污染类型为拮抗作用,且两者相互作用可以形成络合物。综合以上结论,说明环境浓度的铜可能通过细胞凋亡、分子水平的变化等方式对水生生物的早期生长发育产生危害,如延迟生长发育、神经及心脏发育异常,另外铜可通过和四环素等环境中其他污染物的结合改变铜的生物有效性和毒性。     

富里酸-膨润土复合体对氟的吸附特性

采用共沉淀法制备了富里酸-膨润土复合体(FA-BENT),研究了FA-BENT的基本性质及其在不同环境条件下对氟的吸附特性.XRD分析显示,FA-BENT中蒙脱石的(001)面衍射峰强度有所减弱,但其层间距没有明显变化,表明FA-BENT中富里酸主要包被在膨润土外表面.FTIR结果表明,FA-BENT膨润土的矿物组分主要与富里酸表面C=O、—OH等官能团结合,配位体交换、表面络合作用是其主要作用机制.低p H范围内,升高反应体系的初始p H有利于FA-BENT对氟的吸附;当初始p H上升至4.50以后,吸附量随p H升高而降低;FA-BENT对氟的吸附也受离子强度的影响,其主要原因可能是"极性"效应;FA-BENT对氟的动力学吸附过程遵循拟二级动力学机制,受化学过程控制(R~2=0.999 2);与Freundlich模型相比,Langmuir模型对氟在FA-BENT上的吸附数据具有较高的拟合优度(R~20.994 9).热力学参数表明,FA-BENT对氟的吸附属于熵驱动的自发吸热反应过程[ΔH为32.57 k J·mol~(-1),ΔS为112.31 J·(mol·K)~(-1),ΔG为-0.65~-1.76 k J·mol~(-1)].     

糠醛生产废渣直接转化为复合肥:添加剂(Ⅱ)配方与蒸馏条件的研究

采用复合添加剂 (Ⅱ ) ,主要成分为 :重钙、磷酸、亚硫酸氢钠和碳酸钙等 ,以稻草 (或麦杆 )为原料 ,用硫酸酸化水解制取糠醛 ,硫酸浓度为 6 % (摩尔 % ) ,液固比为 1∶1～ 2∶1 (wt /wt) ,复合添加剂 (Ⅱ )与原料的比为 0 .0 5∶1 (wt/wt) ,出醛率 :稻草为 1 0 % ;麦杆 1 1 % ,废渣全部转化为中性复合肥。     

长江上游及雅砻江徒步考察概况

本文对长江上游雅砻江一带的藏、汉、彝和纳西等民族混合居住地区的文化、社会、生产、生活习俗,地形、地质、地貌演变,以及森林砍伐,乱开矿山,随意捕杀动物等人为活动,造成了水土流失、滑坡、泥石流和地震等自然灾害。破坏了自然生态环境,给当地开发丰富的水资源和矿产资源带来了极大的影响。     

Construction of evolving models for the environmental evaluation of innovative sub-systems based on a hierarchical agglomerative clustering

This paper deals with simplifying the environmental evaluation of an innovative sub-system related to the future complex system that will include it, by using evolving generic models built on a limited number of characteristics. For a complex system range, the evolving approach of the environmental modelling aims to generate a learning dynamics, to avoid the paralysing complexity induced in design by the valuation of many components according to many impact categories. Applied to the automotive sector, dendrograms are made with results of life cycle assessments (LCA) of 17 vehicles for 4 environmental indicators and on 3 life cycle steps. In an iterative process, a limit condition threshold on the resulting relative errors aims to cluster the vehicles. First, several calculation methods of dendrograms are tested. Second, the influence of the limit condition on the models is observed. Lastly, by simulating the vehicle population increase, the modelling capacity to evolve is tested. Five vehicle characteristics are sufficient to identify a model to be equivalent to the future vehicle. While the number of clusters is increased to simplify their identification with the system characteristics, the relative error variability increases too. The generic models are stable when adding LCA's results.     

基于复杂网络理论的原油贸易空间格局差异分析

本文采用复杂网络分析方法,结合区域分析与相似性分析,比较了十大进口国(地区)原油贸易空间结构差异.复杂网络分析旨在以入度、权重及结构熵勾勒出十大原油进口国(地区)石油贸易的拓扑结构差异,并在拓扑结构分析中结合区域分析以揭示十大贸易国(地区)原油进口贸易空间格局构成之不同;相似性分析则是在拓扑结构和空间结构研究基础上,进一步量化了十大进口国(地区)的空间结构差异程度及区位在进口国(地区)原油贸易空间格局形成中的作用.研究表明,主要进口国与地区的原油进口贸易空间结构存在显著差异.而地理区位差异越大的国家与地区间,贸易空间结构差异越大.除中国外,各原油进口大国与地区更倾向于选择较经济的进口地域;显著的多元化与均质化则导致了中国贸易空间格局的不经济.研究结果提示我们,多元化不应以过多牺牲经济性为前提,中国应权衡所面临的客观环境选择适合区域合作伙伴,才能更好的落实多元化进口策略,切实解决可能面临的石油安全问题.     

Microbial remediation of nitro-aromatic compounds: an overview

Nitro-aromatic compounds are produced by incomplete combustion of fossil fuel or nitration reactions and are used as chemical feedstock for synthesis of explosives, pesticides, herbicides, dyes, pharmaceuticals, etc. The indiscriminate use of nitro-aromatics in the past due to wide applications has resulted in inexorable environmental pollution. Hence, nitro-aromatics are recognized as recalcitrant and given Hazardous Rating-3. Although several conventional pump and treat clean up methods are currently in use for the removal of nitro-aromatics, none has proved to be sustainable. Recently, remediation by biological systems has attracted worldwide attention to decontaminate nitro-aromatics polluted sources. The incredible versatility inherited in microbes has rendered these compounds as a part of the biogeochemical cycle. Several microbes catalyze mineralization and/or non-specific transformation of nitro-aromatics either by aerobic or anaerobic processes. Aerobic degradation of nitro-aromatics applies mainly to mono-, dinitro-derivatives and to some extent to poly-nitro-aromatics through oxygenation by: (i) monooxygenase, (ii) dioxygenase catalyzed reactions, (iii) Meisenheimer complex formation, and (iv) partial reduction of aromatic ring. Under anaerobic conditions, nitro-aromatics are reduced to amino-aromatics to facilitate complete mineralization. The nitro-aromatic explosives from contaminated sediments are effectively degraded at field scale using in situ bioremediation strategies, while ex situ techniques using whole cell/enzyme(s) immobilized on a suitable matrix/support are gaining acceptance for decontamination of nitrophenolic pesticides from soils at high chemical loading rates. Presently, the qualitative and quantitative performance of biological approaches of remediation is undergoing improvement due to: (i) knowledge of catabolic pathways of degradation, (ii) optimization of various parameters for accelerated degradation, and (iii) design of microbe(s) through molecular biology tools, capable of detoxifying nitro-aromatic pollutants. Among them, degradative plasmids have provided a major handle in construction of recombinant strains. Although recombinants designed for high performance seem to provide a ray of hope, their true assessment under field conditions is required to address ecological considerations for sustainable bioremediation.     

开放空间复杂地形人员疏散模拟研究

为研究开放空间复杂地形条件下人员疏散,开发出能够模拟行人疏散的三维可视化软件系统。将复杂多变的地形分解为一系列连续变化的坡面,分析斜坡上行人受力,考虑重力影响,在经典社会力模型的基础上,提出一个改进模型。选择某气井周边居民疏散案例,运用VC++和OpenGL图形库技术初步完成整合数字高程模型(DEM)、道路网络和行人特征的三维社会力人员疏散模拟程序。最后通过实例模拟,可以明显地观察到人群的动态疏散过程以及在灾难中的拥堵行为、转向躲避行为和超越行为。应用该模型,能够实现复杂地形人员疏散三维动态模拟,并快速预测疏散时间。     

城市地铁网络系统运行脆弱性分析

为提高城市地铁网络系统(UMNS)运行的抗风险能力,降低事故造成的经济、社会损失,对UMNS运行脆弱性进行研究。通过对UMNS的特点和事故案例统计分析,将UMNS的运行脆弱性分解为物理、结构和社会功能3类脆弱性,解析UMNS运行脆弱性在事故发生过程中的作用,定义UMNS的运行脆弱性为UMNS在运行阶段抵御来自系统故障、人为失误、社会干扰的能力中的缺陷。通过案例分析,解释运行脆弱性的发生机理,提出降低UMNS运行脆弱性的相关建议。研究表明:UMNS运行脆弱性对地铁事故的发生、蔓延和最终损失有关键性影响;物理和社会功能脆弱性在事故发生的初期影响较大,结构脆弱性对事故在网络中的蔓延有较大影响,社会功能脆弱性则影响着最终事故的损失大小。因此,降低UMNS运行脆弱性应从结构、网络和社会功能3个方面综合展开。     

内蒙古典型草原土壤及其水文过程对灌丛化的响应

基于野外观测和室内试验相结合的方法,研究了内蒙古典型草原小叶锦鸡儿灌丛化过程对土壤和土壤水文过程的影响,旨在为干旱半干旱区环境保护和恢复提供理论基础。结果表明,斑块尺度上,灌丛斑块土壤有机质和全氮含量分别是草地斑块的1.54倍和1.16倍;灌丛斑块平均沙粒、粉粒和粘粒含量是草地斑块的0.87倍、1.34倍和1.35倍;灌丛斑块土壤容重是草地斑块的0.97倍;灌丛斑块钙积层上表面出现深度是草地斑块的1.27倍。地形等自然条件也是形成土壤异质性的重要因子,坡面尺度上,灌丛和草地斑块土壤有机质、全氮、土壤容重、土壤钙积层上表面出现深度呈自坡顶向坡下方向增加的趋势。染色示踪实验表明,灌丛斑块土壤剖面湿润锋和土壤水分入渗速率分别是草地斑块的1.36倍和5.16倍,草地斑块0~10cm土层对水分的响应较敏感,而灌丛斑块25 cm以下土层对水分的响应较敏感。研究认为,灌丛化过程增强了土壤空间异质性,灌丛斑块能将土壤水分快速输送并存储于深层土壤中,灌丛斑块是土壤养分和水分富集区,灌木植物的定居和发展过程与土壤形态之间形成了正反馈。