杂质对硝酸铵水溶液临界爆炸温度的影响

利用自制装置对含杂质的硝酸铵水溶液临界爆炸温度进行测试研究.结果表明,Cl-单独作用在一定程度上抑制硝酸铵溶液的热分解,提高了其临界爆炸温度;pH值一定时,随着Cl-浓度的增大,硝酸铵水溶液的临界爆炸温度呈指数形式降低;Cl-浓度一定时,pH值越小,硝酸铵水溶液的临界爆炸温度越低;油脂会降低硝酸铵溶液的热稳定性.该结果...     

基于红色旅游的国土空间规划层级传导与冲突协调研究

以跨行政区域线状分布且多与自然资源相伴而生的红色旅游资源为切入点,针对区域红色旅游与国土空间规划拟合错位、红色旅游与三条控制线相互交织等问题,围绕国土空间规划层级传导和冲突协调展开探讨：以纵横传导双向引擎的方式构建分层次有传导的红色旅游空间体系,从而打破红色旅游区域协调和用地管制的问题;科学合理地协调红色旅游与三条控制线的冲突,当红色旅游与生态保护红线和永久基本农田红线冲突时应强调在保护中发展,在城镇开发边界内的红色文化资源应强调在发展中保护。本文旨在为红色旅游在国土空间规划体系下探索一条高质量发展路径,同时提高国土空间规划编制和三条控制线划定的科学性和可操作性。     

USING REFERENCE SITES AND SIMPLE LINEAR REGRESSION TO ESTIMATE LONG‐TERM WATER LEVELS IN COASTAL PLAIN FORESTS1

ABSTRACT: The ability of regulators, resource managers, and consultants to assess accurately wetland hydrology is crucial when identifying and delineating wetlands. In this study, simple linear regression and long‐term (ten year) New Jersey Pinelands stream gaging and pitch pine lowland water‐level data sets were used to estimate long‐term hydroperiods at lowland test sites with short‐term (two year) records. Separate regression equations were developed for each test site using reference site data and stream gaging data, and two sets of equations for selected test sites were produced using two different short‐term periods of record. Test sites had long‐term records ranging from four to ten years, allowing validation of the regression models. Measured and predicted test site growing season water levels were similar regardless of which short‐term period of record was used. The results based on the stream gaging site data were similar, although the difference between measured and estimated growing season water levels was greater when this approach was used. Excellent agreement was found between measured and estimated frequencies of near‐surface saturation at test sites for each growing season month, and these relationships improved when cumulative, seasonal frequencies were considered. The reference wetland approach used in this study may have its greatest value in regions with both high development pressures and problem wetlands and may provide an effective way of resolving costly wetland delineation disputes.     

4种重金属污染对稻田土反硝化细菌的影响

在实验室条件下,研究Cd²⁺、As⁵⁺、Cu²⁺和Pb²⁺处理黄松稻田土、紫色稻田土和红壤稻田土后,4周内重金属污染对反硝化细菌种群数量及其反硝化活性的影响.结果表明,在1kg干土中加入0.5mg Cd²⁺、30mg As⁵⁺、50mg Cu²⁺和200mg Pb²⁺时,对稻田土反硝化细菌种群数量及其活性有促进作用,加入Cd²⁺、As⁵⁺、Cu²⁺和Pb²⁺分别超过1.0,60,500,400mg/kg干土时,对稻田土反硝化细菌种群数量及其活性有明显抑制作用.但反硝化细菌种群数量及其活性能逐渐恢复并接近对照水平,重金属污染越重,恢复所需的时间也越长.同一种重金属元素对不同水稻田土的反硝化细菌种群数量及其活性的影响也有差异.     

Uncertainties in Large Scale Assessments of Critical Load Exceedances

In the 1999 Gothenburg protocol to the UN/ECE LRTAP Convention andin the negotiations for an EU acidification strategy the area withexceedances of critical loads has been the preferred measure forenvironmental impacts. The aim of this study has been to assessthe influence of the uncertainty and spatial variation of both thecritical loads and deposition values on the calculated area withexceedances of critical loads. This has been done on a nationalscale for Denmark and on the European scale based on the dataincluded in the RAINS model. It is demonstrated that includinguncertainty and spatial variation in exceedance calculations, ingeneral gives larger exceeded area for the critical load ofacidity, CL(A). The picture for the critical load of nutrientnitrogen, CL_nut(N), is more mixed because of the higherproportion of exceeded areas. A further point of interest is thepossibility of validating relationships between critical loadexceedances and observable damage based on large scale monitoringand model data. It is demonstrated that it will probably not bepossible to use exceedance calculations on European scale as basisfor validation exercises, linking exceedances to observable damage.     

Use of the Dynamic Model `MAGIC' to Predict Recovery Following Implementation of the Gothenburg Protocol

Reduction of sulphur deposition causesrecovery of acidified surface waters. Processes in thecatchment delay recovery. The acidification model MAGICwas applied to the Vikedal and Tovdal rivers in southernNorway. Response in water chemsitry is delayed by 10–20 yr. The delay is due to release of old sulphate atVikedal and cation exchange at Tovdal. Assuming that theGothenburg protocol is fully implemented by the year2010, much of the predicted increase of ANC will occur inthe next 10 yr with a levelling off by about 2040. Ifnitrogen leaching increases in the future, however,recovery of ANC will not be as rapid, nor as complete.Critical load for acidity calculated by steady-statemodels is confirmed by the MAGIC predictions. Futurerequirement for mitigation measures such as liming willdecrease in the future as acid deposition decreases. Bythe year 2046 the liming requirement will be reduced byabout 45% at Vikedal and 65% at Tovdal. One of the mainpurposes of the Norwegian national monitoring programmeis to provide documentation of changes in environmentalquality due to long-range transported air pollutants.Modelling applications such as this clearly show that thedata fill this purpose.     

Fluxes of NO3-, NH4+, NO,NO2, and N2O in an Old Danish Beech Forest

The fluxes of the major nitrogen compounds havebeen investigated in many ecosystem studies over the world.However, only in few studies has attention been drawn to theimportance of the fluxes of minor gaseous nitrogen compoundsto complete the nitrogen cycle. In Denmark a detailed study onthe nitrogen cycle in an old beech forest has been implementedin 1997 at Gyrstinge near Sorø, Zealand. The study includesthe fluxes of the gases NO, N₂O and water mediatedtransport of NO₃ ^- and NH₄ ⁺. Measurementsof the fluxes of the gaseous compounds are performed withmicro-meteorological methods (eddy-correlation and gradient)and with chambers. Water mediated fluxes encompass rain,throughfall, stem-flow and leaching from the root zone. Thehydrological model is verified by TDR measurements. The findings show that the total water mediated N input tothe forest floor with throughfall and stemflow was 25.6 kg Nha^-1 yr ^-1, and open field wet deposition withprecipitation was 19.0 kg N ha^-1 yr ^-1. The internalcycling of N in the ecosystem measured as turnover oflitterfall and plant uptake was 100 kg N ha^-1 yr ^-1and 14 kg N ha^-1 yr ^-1, respectively. The fluxes ofthe gaseous N compounds NO and N₂O were of minorimportance for the total N turnover in the forest, NO_xemission being <1 kg N ha^-1 yr ^-1 and N₂Oemission from the soil being 0.5 kg N ha^-1 yr ^-1 withno significant difference between wet and dry soils.Concentrations of NO₃ ^- and NH₄ ⁺ in thesoil solution beneath the rooting zone are very small andconsequently the N leaching is almost negligible. It isconcluded that the nitrogen mass balance of this old beechforest ecosystem mainly is controlled by the input by dry andwet deposition and a large internal N cycle with a fast litterturnover. The nitrogen input tothe forest ecosystem which currently exceeds the critical loadby 5 kg N ha^-1 yr ^-1is mainly accumulated in the soil and no significant nitrateleaching is occurring.     

Incorporation of Seasonal Nitrogen Dynamics within a Long-Term Acidification Model

This paper describes an application of the long termdynamic model, MAGIC, on a monthly timestep, enablingincorporation of the seasonal dynamics associated with abroad understanding of the ecosystem N cycle. The modelhas been applied to the Dargall Lane catchment in theGalloway region of Scotland where marked seasonal Ndynamics are apparent. Mean monthly proportions ofrainfall, runoff, deposition fluxes and net retention ofN are utilised to drive the model on a monthly timestep.Calibration of the model has successfully reproduced thepresent day observed seasonal variation in streamNO₃ and ANC. Prediction of recovery at the siteunder the second sulphur protocol indicates that,although mean annual ANC increases, mean monthly ANC doesnot rise above zero for all months of the year until2010.     

新型膜-生物反应器在不同通量下的膜污染特性研究

选择适当的膜通量是膜-生物反应器控制膜污染的有效手段之一.本文根据膜通量与临界通量的关系选取了5个不同的膜通量,考察在这些通量条件下新型膜-生物反应器膜污染发展特性的变化.试验结果表明,膜通量的变化会影响膜污染的发展特性.当膜通量小于临界通量区时,膜污染发展具有"2阶段"趋势,并且膜通量越小"第1阶段"和"第2阶段"的膜污染发展速率对比越显著.当膜通量在临界通量区通量内时,首先出现短暂的膜污染快速增长期,随后膜污染发展仍呈现"2阶段"现象.当膜通量大于临界通量区通量时,膜操作压力(TMP)从开始运行即迅速上涨直至试验结束.     

Sensitivity analysis of a parameterization of the stomatal component of the DO3SE model for Quercus ilex to estimate ozone fluxes

A sensitivity analysis of a proposed parameterization of the stomatal conductance (g(s)) module of the European ozone deposition model (DO(3)SE) for Quercus ilex was performed. The performance of the model was tested against measured g(s) in the field at three sites in Spain. The best fit of the model was found for those sites, or during those periods, facing no or mild stress conditions, but a worse performance was found under severe drought or temperature stress, mostly occurring at continental sites. The best performance was obtained when both f(phen) and f(SWP) were included. A local parameterization accounting for the lower temperatures recorded in winter and the higher water shortage at the continental sites resulted in a better performance of the model. The overall results indicate that two different parameterizations of the model are needed, one for marine-influenced sites and another one for continental sites.