Assessment of Wet Sulfate Concentration Changes at CAPMoN Sites, Canada

This paper describes a statistical analysis of wet sulfate deposition data sampled by the Canadian Air and Precipitation Monitoring Network (CAPMoN) since 1988 till 1997. The goal of the investigation is to detect presence of prevailing significant changes in the probability distribution of annual samples collected by the network at each site. The considerations are based on a first order autoregression model with second order polynomial trend and methods used for analysis of variance and multiple comparison. Unlike studies suggesting existence of long term trends in the data, methods applied here indicate absence of any systematic changes in the observed annual concentration patterns at most of the sites.     

Uncertainty Assessment of Voc Emissions from Paint in the Netherlands Using the Nusap System

We demonstrate an innovative approach to uncertainty assessment known as the NUSAP system, to assess qualitative and quantitative uncertainty for the case of emissions of volatile organic compounds (VOC) from paint in The Netherlands. Using expert elicitation, we identified key sources of error, critical assumptions, and bias in the monitoring process. We assessed pedigree and probabilistic uncertainty of all input quantities. We used four pedigree criteria to assess the strength of the knowledge base: proxy representation, empirical basis, methodological rigour and degree of validation. Using Monte Carlo analysis, we assessed sensitivity and propagation of uncertainty. Results for sensitivity and pedigree were combined in a NUSAP Diagnostic Diagram, which effectively highlighted the assumption for VOC percentage of imported paint as the weakest spot in the monitoring of VOC emissions. We conclude that NUSAP facilitates systematic scrutinization of method and underlying assumptions and structures creative thinking on sources of error and bias. It provides a means to prioritise uncertainties and focus research efforts on the potentially most problematic parameters and assumptions, at the same time identifying specific weaknesses in the knowledge base. With NUSAP, nuances of meaning about quantities can be conveyed concisely and clearly, to a degree that is not possible with statistic methods only.     

Development of an Overall Index of Pollution for Surface Water Based on a General Classification Scheme in Indian Context

Various National and International Agencies involved in water quality assessment and pollution control have defined water quality criteria for different uses of water considering different indicator parameters. Classification schemes for water quality criteria/standards developed by these agencies differ inaddition to terminologies used such as Action level, Guide level etc. in defining the concentration values in these classes. In the present article a general classification scheme viz. Excellent,Acceptable, Slightly Polluted, Polluted and Heavily Polluted water is proposed for surface water quality assessment. The concentration ranges in these classes are defined in Indianscenario considering Indian Standards and CPCB criteria. Standardsby the European Community (EC), WHO etc. and the reported factsabout the pollution effects of important water quality indicatorparameters on the surrounding were also taken into account. Themathematical equations to transform the actual concentrationvalues into pollution indices are formulated and correspondingvalue function curves are plotted. Based on the individual indexvalues, an `Overall Index of Pollution' (OIP) is estimated. Theapplication of OIP is demonstrated at a few sampling stations onriver Yamuna based on observed water quality data. The general classification scheme along with concentrationranges defined in these classes will be of immense use fordetermining the surface water quality status with reference tospecific individual parameter, and the OIP for assessing theoverall water quality status in Indian context.     

A method to combine non-probability sample data with probability sample data in estimating spatial means of environmental variables

In estimating spatial means of environmental variables of a region from datacollected by convenience or purposive sampling, validity of the results canbe ensured by collecting additional data through probability sampling. Theprecision of the estimator that uses the probability sample can beincreased by interpolating the values at the nonprobability sample points tothe probability sample points, and using these interpolated values as anauxiliary variable in the difference or regression estimator. Theseestimators are (approximately) unbiased, even when the nonprobability sampleis severely biased such as in preferential samples. The gain in precisioncompared to the estimator in combination with Simple Random Samplingis controlled by the correlation between the target variable andinterpolated variable. This correlation is determined by the size (density)and spatial coverage of the nonprobability sample, and the spatialcontinuity of the target variable. In a case study the average ratio of thevariances of the simple regression estimator and estimator was 0.68for preferential samples of size 150 with moderate spatial clustering, and0.80 for preferential samples of similar size with strong spatialclustering. In the latter case the simple regression estimator wassubstantially more precise than the simple difference estimator.     

A Parallel Computation Tool to Enable Dynamic Sensitivity and Model Performance Analysis of APEX: Evapotranspiration Modeling

Global sensitivity analysis can be used for assessing the relative importance of model parameters on model outputs. The sensitivity of parameters usually indicates a temporal variation due to variation in the environmental conditions (e.g., variation in weather or plant growth). In addition, the size of averaging window by which the outputs of a model are aggregated or averaged may impact parameter sensitivities. In this study, temporal variation of parameters sensitives, model performance, as well as the impact of the size of time‐averaging window on evapotranspiration (ET) prediction using the Agricultural Policy/Environmental eXtender (APEX) model are investigated. To achieve these goals, an open‐source package named PARAPEX was developed in R and used to perform dynamic sensitivity and model performance analysis of APEX using parallel computation. PARAPEX reduced the computation time from 5,939 to 379 s (using 20 and 1 computation nodes, respectively). The sensitivity analysis results indicated the parameters accounting for the reducing effect of plant cover on evaporation from the soil surface, the effect of soil on the plant root growth, and the effect of cycling and transformation dynamics of organic matter at the top soil layer as the top sensitive parameters based on the mean daily simulated ET and the Nash–Sutcliffe model performance measure. The dynamic performance analysis indicated poor ET predictions by APEX during the growing seasons. Editor's note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

Comparison of epidemiology and injury profile between vulnerable road users and motor vehicle occupants in road traffic fatalities

Objective: Road traffic injuries (RTIs) are a major global health issue causing a global burden of mortality and morbidity. Half of all fatalities on the world’s roads are vulnerable road users (VRUs). The targeted intervention strategies based on fatality analysis focusing on VRUs can effectively contribute to reducing RTIs. This study aimed to compare VRUs and motor vehicle occupants (MVOs) in terms of epidemiology and injury profile.

Methods: We utilized a nationwide, prospective database of RTI-related mortality cases for patients who visited 23 emergency departments between January 2011 and December 2015. All fatalities due to RTIs in the prehospital phase or in-hospital were eligible, excluding patients with unknown mode of transport and those admitted to general wards. The primary and secondary outcomes were fracture injuries and visceral injuries diagnosed using the International Classification of Diseases, Tenth Revision (ICD-10). We compared fracture injuries between VRUs and MVOs using Abbreviated Injury Scale (AIS) 2? and 2+ classification.

Results: Among a total 3,694 road traffic fatalities (RTFs), 43.3% were pedestrians, followed by MVOs (27.0%), motorcyclists (18.9), bicyclists (6.6%), and agricultural vehicle users (4.2%). The elderly (>60 years old) accounted for 54.9% of VRU fatalities. RTFs occurred most frequently in the autumn and the VRU group and the MVO group showed significant differences in weekly and diurnal variation in RTFs. The injury severities (AIS 2+) of the head, neck, and thorax were significantly different between the 2 groups (P?Conclusions: Elderly pedestrians should be targeted for decreases in RTFs, and road traffic safety interventions for VRUs should be made based on the analysis of temporal epidemiology and injury profiles of RTFs.     

基于电力历史应急大数据的应急情景规则分析与发现方法研究

为了解决电力突发事件演化过程难于预测,进而导致事件应急缺少针对性,较为被动的问题,提出在现有应急预案指导、事故模拟仿真、事故案例经验总结等方法基础上,引入基于电力历史大数据分析与预测的应急情景规则分析与发现方法,将电力应急突发事件情景构建的结果与相关大数据预测模型（汇总统计、分类与预测）相结合,提出科学、合理且具有良好操作性的情景演化规则的获取方法与技术路线,为进一步提高复杂电力突发事件的应急处置与指挥能力提供技术支撑。     

全国非煤矿山总量情况统计分析及监管建议

为研究全国非煤矿山基本情况并为非煤矿山安全监管部门提供决策支撑,采用统计、对比分析等方法,以各地上报的2017年统计数据及历年安全生产年鉴为依据,对我国“十三五”期间非煤矿山总量、类型、分布以及“头顶库”、高边坡露天矿山等重点监管对象进行分析,并在此基础上提出强化重点对象精准监管、严格安全生产条件、严控建设项目准入、规范尾矿库闭库注销制度4点监管建议。分析汇总了截至2017年底我国非煤矿山总量情况的统计数据,可为非煤矿山行业的深入分析研究提供重要支撑。     

贵州省闪电定位资料中小幅值地闪范围研究

采用2006—2015年贵州省ADTD闪电定位资料,应用Matlab软件中的曲线拟合工具箱对数据进行对数正态分布拟合,利用非参数正态分布检验中的Kolmogorov—Smirnov检验方法(简称K-S检验方法)分析各区间拟合效果,最终确定贵州省闪电定位系统资料的"小幅值地闪"干扰区间为-10~2k A,该结论为贵州省闪电资料修正提供理论依据,在使用ADTD闪电定位资料时可先将此区间误差数据剔除。该研究为利用闪电定位资料确定雷电灾害风险区划提供重要参考。     

Methylated and thiolated arsenic species for environmental and health research——A review on synthesis and characterization

Hundreds of millions of people around the world are exposed to elevated concentrations of inorganic and organic arsenic compounds, increasing the risk of a wide range of health effects. Studies of the environmental fate and human health effects of arsenic require authentic arsenic compounds. We summarize here the synthesis and characterization of more than a dozen methylated and thiolated arsenic compounds that are not commercially available. We discuss the methods of synthesis for the following14 trivalent(Ⅲ) and pentavalent() arsenic compounds: monomethylarsonous acid(MMA~Ⅲ), dicysteinylmethyldithioarsenite(MMA~Ⅲ(Cys)_2), monomethylarsonic acid(MMA~Ⅴ),monomethylmonothioarsonic acid(MMMTAⅤ) or monothio-MMA~Ⅴ, monomethyldithioarsonic acid(MMDTA~Ⅴ) or dithio-MMA~Ⅴ, monomethyltrithioarsonate(MMTTA~Ⅴ) or trithio-MMA~Ⅴ,dimethylarsinous acid(DMA~Ⅲ), dimethylarsino-glutathione(DMA~Ⅲ(SG)), dimethylarsinic acid(DMA~Ⅴ), dimethylmonothioarsinic acid(DMMTA~Ⅴ) or monothio-DMAⅤ, dimethyldithioarsinic acid(DMDTA~Ⅴ) or dithio-DMA~Ⅴ, trimethylarsine oxide(TMAO~Ⅴ), arsenobetaine(AsB), and an arsenicin-A model compound. We have reviewed and compared the available methods,synthesized the arsenic compounds in our laboratories, and provided characterization information. On the basis of reaction yield, ease of synthesis and purification of product, safety considerations, and our experience, we recommend a method for the synthesis of each of these arsenic compounds.