华中地区种植业生产碳排放驱动因素分析

农业是温室气体排放的第二大人为因素源,探寻农业生产碳排影响因素,对实现农业节能减排有重要意义。以中国粮食主产区华中地区为背景,综合运用IPCC(2006)推荐的方法估算华中地区1994~2013年种植业生产的碳排放量,基于Kaya恒等式、灰色关联模型对华中地区种植业生产的碳排放驱动因素进行识别并探讨主要影响因素的贡献。结果显示:(1)华中地区1994~2013年种植业生产碳排放呈上升趋势,2013年达到了11 257.63万t CO2-eq。其中,河南省、湖北省、湖南省的种植业生产碳排放增幅分别为101.29%、24.88%、21.73%;(2)在过去的20 a中,种植业生产效率、种植业结构、农业劳动力规模对农业生产碳排放具有一定抑制作用,而农业经济发展则促进了种植业生产碳排,具有一定的推动作用;(3)近20 a的农业发展过程中,华中地区种植业生产碳排放最主要的贡献因子是种植业结构,其次是农业从业人口、种植业产值、人均农用物资消耗量。     

Politics of Edibility: Reconceptualizing Ecological Relationality

Taking the Infinity Burial Project (IBP) as its inspiration, this essay theorizes a politics of edibility by way of decomposing the discursive boundaries erected between human bodies and environments. In particular, this essay reads the IBP as a deconstruction of another dualism—eater/eaten—that permeates and informs cultural practices from birth to burial. Mobilizing a rhetoric of carnality, the IBP decomposes the human body's relation to its environments, merging its statuses as eater and eaten. At the same time, this rhetoric of carnality also emphasizes the irreducibly productive nature of consumption as an articulatory practice in its own right. As this essay argues, a politics of edibility not only recognizes the superficiality of the body/environment and eater/eaten dichotomies but it also respects the relations generated in the wake of their deconstruction.     

排水管道中CH4、H2S与N2O的产生机制及其控制策略

排水管道厌氧环境会产生甲烷 (CH₄) 与硫化氢 (H₂S) ,而好氧及缺氧环境又会诱发氧化亚氮 (N₂O) 。污水中所含有机物 (COD) 、氮 (N) 和硫酸盐 (SO₄²⁻) 是产生这些气体的主要根源。系统综述了3种有害气体的产生机理,厘清污水中污染物、管道中微生物及管道环境对有害气体产生的影响。基于此,有针对性地提出了这几类气态污染物的控制策略。其中,对CH₄与H₂S的抑制手段集中在向管道中投加药剂以限制其产生源头,然而投加NO₃⁻或NO₂⁻药剂与通入氧气这两种控制手段可能会导致N₂O这种温室气体的大量产生。因此,应充分了解排水管道中各复杂因素之间的相互作用,以实现对有害污染气体的控制,并实现碳减排的目标。     

工业园区碳排放核算与因素分解实证分析

工业园区贡献了全国过半的工业产值和近31%的碳排放量,是我国应对气候变化实现双碳目标的重要战场,然而当前尚未形成针对工业园区碳排放核算的规范体系。本研究在温室气体清单编制现有方法基础上,构建针对工业园区的碳排放核算体系,并利用此核算体系对重庆市某工业园区2016—2020年碳排放量进行了核算实证研究,且通过LMDI分解模型分析该园区碳排放变动的影响因素。结果表明,该园区在“十三五”期间碳排放呈逐年增长趋势,化石燃料燃烧是园区内最主要的碳排放源,占比达83.5%,化工行业碳排放在该园区所有行业中占比最大 (68.9%) ,园区碳排放的主要驱动因素是能源强度,效应贡献率为64.7%。据此,本研究提出了针对该园区的降碳路径,并通过实证分析后探讨了工业园区碳排放核算方法体系的规范化问题,以期为我国工业园区的碳减排工作提供参考。     

辐射分解处理废水中的苯酚

采用辐射分解法处理废水中的苯酚,分别测定了辐照时间,剂量率,苯酚起始浓度,溶液pH及加入H2O2对苯酚去除率的影响.结果表明,去除率随辐照时间的延长而提高;总剂量一定的条件下,低剂量率下苯酚降解完全;当苯酚浓度较低时,去除效果较好.pH为中性条件下的去除率大于酸性和碱性;加入一定浓度的H2O2可使苯酚的去除率达到100%.     

NiFe2O4直接分解二氧化碳成碳循环反应过程结构演变研究

用XRD Rietveld分析法,对共沉淀法制备的NiFe2O4在H2／CO2循环反应中的结构演变进行研究,发现随着循环反应次数的增加,NiFe2O4物相的含量逐渐降低,Fe2Ni1-x物相的含量及其(200)衍射的平均晶粒逐渐增大,并出现Fe3C物相,其含量增长较快．纯NiEe2O4经15次循环反应后,体系中NiFe2O4物相的含量只剩下5％左右,样品基本失去分解CO2的活性．NiFe2O4掺杂4％铬后,明显提高了NiFe2O4骨架结构的稳定性,虽经50次H2／CO2循环反应,体系中NiFe2O4物相含量仍然有20％,分解CO2的活性仍达到初始活性的40％．     

双(对羧苯基)苯基氧化膦阻燃改性聚酯的热解和燃烧特性实验研究

本文以双(对羧苯基)苯基氧化膦为阻燃单体,合成了阻燃共聚酯(COPET)。通过热失重分析和锥形量热分析,研究了阻燃共聚酯的热降解行为和燃烧特性,并对阻燃剂的阻燃机理进行了简单的讨论。实验结果表明,阻燃剂双(对羧苯基)苯基氧化膦是适于聚酯的较好阻燃剂,但其发烟量有待抑制。     

Lignin and its effects on litter decomposition in forest ecosystems

Lignin is a major component of plant litter. In this review, we found lignin comprises a complex class of organic compounds whose concentration differs greatly both between and within plant species. There are many analytical methods for detecting the composition and structure of lignins. As lignins are enormously complex compounds, chemical assay is difficult and different methods vary with the results. Lignin plays a significant role in the carbon cycle, sequestering atmospheric carbon into the living tissues of woody perennial vegetation. It has also great effects on nitrogen dynamics of forest ecosystems as well as other ecological processes. Lignin is one of the most slowly decomposing components of dead vegetation, contributing a major fraction of the material that becomes humus as it decomposes. Lignin is highly correlated with decomposition of litter. Thus, there is evidence that the lignin concentration is a more influential factor than the other chemical concentrations, in determining the rate of leaf litter decomposition of different forest ecosystems. Although a great number of researchers have addressed lignin's role in litter decomposition, still there are many aspects of lignin biogeochemistry that are not known. This lack of information hinders complete amalgam of lignin effects on litter decomposition processes and dynamics of nutrient cycling.     

湿地挺水植物凋落物立枯分解研究进展

在许多湿地生态系统中,挺水植物立枯常组成凋落物总量的主要部分,其分解过程研究对于正确评价湿地生态系统的碳收支状况具有重要意义。对立枯分解过程与传统研究中凋落物分解过程的差异,分解过程中的 CO2排放,立枯分解的研究方法,以及分解过程的影响因素进行了综述。一般认为,湿地挺水植物立枯与传统研究中凋落物所处环境的差异造成了分解过程的差异,其分解过程中产生 CO2是湿地温室气体排放的重要途径;凋落袋和红外气体分析仪是湿地挺水植物立枯分解研究的主要方法;真菌组成了立枯体上微生物的大部分,对于立枯分解具有重要作用;环境因子（温度、水分等）和“基质质量”是影响挺水植物立枯分解过程的重要因素。在全球变化背景下,气候变化因子会直接或间接影响凋落物立枯分解过程,引起对气候变化的反馈,因此,在全球范围内开展气候变化对于湿地生态系统挺水植物立枯分解影响的研究具有重要的意义,必将成为凋落物研究的一个重要方向。     

Thermal behaviors, combustion mechanisms, evolved gasses, and ash analysis of spent potlining for a hazardous waste management

An unavoidable but reusable waste so as to enhance a more circular waste utilization has been spent potlining (SPL) generated by the aluminum industry. The combustion mechanisms, evolved gasses, and ash properties of SPL were characterized dynamically in response to the elevated temperature and heating rates. Differential scanning calorimetric (DSC) results indicated an exothermic reaction behavior probably able to meet the energy needs of various industrial applications. The reaction mechanisms for the SPL combustion were best described using the 1.5-, 3- and 2.5-order reaction models. Fluoride volatilization rate of the flue gas was estimated at 2.24%. The SPL combustion emitted CO₂, HNCO, NO, and NO₂ but SO_x. The joint optimization of remaining mass, derivative thermogravimetry, and derivative DSC was achieved with the optimal temperature and heating rate combination of 783.5°C, and 5 °C/min, respectively. Interaction between temperature and heating rate exerted the strongest and weakest impact on DSC and remaining mass, respectively. The fluorine mainly as the formation of substantial NaF and CaF₂ in the residual ash. Besides, the composition and effect of environment of residual solid were evaluated. The ash slagging tendency and its mineral deposition mechanisms were elucidated in terms of turning SPL waste into a benign input to a circular waste utilization.