首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   411篇
  免费   66篇
  国内免费   138篇
安全科学   90篇
废物处理   17篇
环保管理   37篇
综合类   262篇
基础理论   83篇
污染及防治   40篇
评价与监测   13篇
社会与环境   64篇
灾害及防治   9篇
  2024年   4篇
  2023年   13篇
  2022年   22篇
  2021年   19篇
  2020年   24篇
  2019年   22篇
  2018年   15篇
  2017年   20篇
  2016年   20篇
  2015年   31篇
  2014年   21篇
  2013年   56篇
  2012年   43篇
  2011年   57篇
  2010年   27篇
  2009年   25篇
  2008年   24篇
  2007年   26篇
  2006年   25篇
  2005年   12篇
  2004年   10篇
  2003年   16篇
  2002年   12篇
  2001年   9篇
  2000年   13篇
  1999年   13篇
  1998年   8篇
  1997年   10篇
  1996年   3篇
  1995年   3篇
  1994年   2篇
  1993年   3篇
  1991年   1篇
  1988年   1篇
  1987年   1篇
  1975年   1篇
  1971年   2篇
  1970年   1篇
排序方式: 共有615条查询结果,搜索用时 375 毫秒
271.
Abstract

Objective: Particular testing by functional decomposition of the automated driving function can potentially contribute to reducing the effort of validating highly automated driving functions. In this study, the required size of test suites for scenario-based testing and the potential to reduce it by functional decomposition are quantified for the first time.

Methods: The required size of test suites for scenario-based approval of a so-called Autobahn-Chauffeur (SAE Level 3) is analyzed for an exemplary set of scenarios. Based on studies of data from failure analyses in other domains, the possible range for the required test coverage is narrowed down and suitable discretization steps, as well as ranges for the influence parameters, are assumed. Based on those assumptions, the size of the test suites for testing the complete system is quantified. The effects that lead to a reduction in the parameter space for particular testing of the decomposed driving function are analyzed and the potential to reduce the validation effort is estimated by comparing the resulting test suite sizes for both methods.

Results: The combination of all effects leads to a reduction in the test suites’ size by a factor between 20 and 130, depending on the required test coverage. This means that the size of the required test suite can be reduced by 95–99% by particular testing compared to scenario-based testing of the complete system.

Conclusions: The reduction potential is a valuable contribution to overcome the parameter space explosion during the validation of highly automated driving. However, this study is based on assumptions and only a small set of exemplary scenarios. Thus, the findings have to be validated in further studies.  相似文献   
272.
Ionic liquid, an organic molten salt, has efficient flame-retardant performance. Few researchers have attempted to study its flame-retardant mechanism. Moreover, thermal stability and pyrolysis products have a great impact on the flame retardancy. Therefore, this paper focused on the phosphate ionic liquid of 1-butyl-3-methylimidazolium dibutyl phosphate ([Bmim][DBP]) and analyzed its thermal decomposition products and characteristics. The major bond energies of [Bmim][DBP] were calculated using B3LYP/6–311++G(d,p)//M06–2X/6–311++G(d,p) level. The experimental results show that the pyrolysis products were as followed: alkane or alkene with a carbon chain length of 1–4; imidazole and its derivatives; esters. Furthermore, Gas chromatography-mass spectrometer and Fourier transform infrared spectrometer were utilized to measure the gaseous products and solid phase products of [Bmim][DBP], which were obtained during thermogravimetric analysis. The results of theoretical and experimental analysis were highly consistent. Finally, the possible flame-retardant mechanism of [Bmim][DBP] was proposed.  相似文献   
273.
A number of runaway scenarios of the excess of hydrogen peroxide used during the N-oxidation of alkylpyridines, under closed and open conditions, were examined. It was found that, in most cases, if the volume of the liquid hydrogen peroxide solution occupies more than 10% of the total volume of a closed system (e.g. reactor and vent line between reactor and blockage), the production of gases raises the pressure so quickly that evaporation is completely suppressed. Higher than 70% filling levels result in complete expansion of the liquid. The MTSR(t) of the system falls rapidly if the normal process temperature is high, but if a runaway occurs exactly at the end of dosing, MTST will be very high and secondary decompositions will rapidly develop. The results of this study are currently being used to critically assess the current approaches and further the study of inherently safer designs.  相似文献   
274.
采用分解袋法,研究了川西亚高山云杉纯林与混交林叶凋落物的质量损失过程及土壤动物与微生物的作用。结果如下:(1)云杉叶凋落物分解过程中,土壤动物数量总体呈下降趋势,即土壤动物主要在分解前期发挥作用,其中,大型土壤动物早期以植食性的蛴螬为主,中期以捕食性的石蜈蚣为主,后期以腐食性的马陆为主;中小型土壤动物始终以螨类、跳虫和线虫为优势类群;相关分析表明线虫数量与云杉叶凋落物分解速率相关性最大,大型土壤动物次之。(2)云杉叶凋落物分解过程中,微生物数量总体呈上升趋势,即土壤微生物主要在分解后期发挥作用,进一步相关分析表明真菌数量与云杉叶凋落物分解速率相关性大于细菌和放线菌。(3)云杉纯林叶凋落物分解速率低于混交林,其中分解3、15、21、24个月时,纯林小孔径分解袋失重率分别为混交林的65.51%、95.73%、98.91%、94.8%,大孔径分解袋失重率分别为混交林的89.83%、92.95%、98.13%、97.13%,即,两类林分小孔径分解袋及凋落物分解前期失重率差异更为明显,表明凋落物分解速率既受底物质量的影响,也和参与分解的土壤生物有关,其中与线虫、大型土壤动物及真菌的数量相关性最大。  相似文献   
275.
杭州湾潮滩湿地植物不同分解过程及其磷素动态   总被引:3,自引:2,他引:1  
湿地植物枯死物分解影响湿地营养物质循环.为分析杭州湾潮滩植物枯死物分解过程和磷素动态,开展了3种优势植物芦苇(Phragmites australis)、互花米草(Spartina alterniflora)和海三棱藨草(Scirpus mariqueter)立枯阶段的观测和分解袋法模拟实验.结果表明,观测期间立枯干物质量逐渐降低,180 d后逐步凋落至地面;立枯磷含量则波动下降.植物分解具有明显的阶段性,初期(0~15 d)损失最快,然后降低.地下根系分解速率表现为:海三棱藨草>芦苇>互花米草,地上部分则相反.分解95%所需时间在1.2~8.3 a之间.植物磷含量先下降后上升,绝对含量则表现为净释放.分析表明,植物分解速率与C/N比没有显著的相关关系,而受C/P比的影响较大.环境因子中的大气温度对分解也有影响.立枯阶段和分解袋法模拟下植物所处的环境不同是影响两者分解过程差异的主要原因.  相似文献   
276.
绿潮硬毛藻分解对天鹅湖水体氮磷水平的影响   总被引:1,自引:0,他引:1       下载免费PDF全文
为了解绿潮硬毛藻衰亡分解对上覆水体营养水平的影响,以荣成天鹅湖不同湖区的沉积物和暴发的硬毛藻为试材,通过室内模拟研究了藻类分解过程中水体氮磷水平及理化性质的变化,并评价了不同湖区沉积物中氮磷的释放潜力.结果表明:硬毛藻衰亡分解使上覆水体中ρ(TN)和ρ(NH4+-N)均明显上升,并且前期(0~16 d)上升较快,ρ(TN)和ρ(NH4+-N)最高分别可达12.40和7.98 mg/L;水体中ρ(TP)和ρ(SRP)表现为前期变化不大,19 d后大幅增加,含量变幅分别为0.02~1.14和0.01~0.40 mg/L.在试验中后期(约16 d后),不同湖区沉积物处理的水体中ρ(TN)、ρ(NH4+-N)、ρ(TP)、ρ(SRP)均表现为有沉积物含藻处理>无沉积物含藻处理>有沉积物无藻处理.在藻分解的条件下,不同湖区沉积物的氮磷释放能力存在很大差异,氮释放量的顺序为湖中心>西北部>南部,而磷表现为西北部>湖中心>南部.在硬毛藻绿潮的衰亡阶段,由于初期藻体营养盐的直接释放和后期促进沉积物内源释放的间接影响,水体中ρ(TN)和ρ(TP)均明显增加,进而加重了天鹅湖水体的富营养化水平.   相似文献   
277.
姚亮  刘晶茹  袁野 《环境科学学报》2017,37(6):2403-2408
近年来,伴随着社会经济的快速发展,我国已成为全球温室气体排放量最大的经济体,而居民消费活动造成的碳排放始终是可持续消费领域的研究热点.本研究综合采用基于投入产出的生命周期评价、结构分解分析、截面分析等方法,并借助EORA数据库,系统研究了近20年中国居民消费碳足迹的总量与组成、驱动因素贡献及未来增长趋势.结果表明,居民消费碳足迹的快速上升通道已经形成,且内在结构演化也呈现规律性,即间接排放和城镇居民排放已占主导地位并且该趋势仍在加强.驱动因素方面,人口增长、城市化进程、消费水平提高是推动碳足迹增长的主要正向力量,同时另外三因素(排放强度、消费结构及经济结构)则构成了延缓碳足迹过快增长的减排力量.截面分析结果显示,未来中国居民消费跨越世界平均水平时其碳排放总量将达到2010年基数的1.45倍,当接近于美国人均消费水平时将达到5.45倍.可以预期,未来我国居民消费碳足迹将会加速增长.  相似文献   
278.
新型溴代苯酚类消毒副产物的氯化降解机制   总被引:1,自引:1,他引:0  
李欢  李正魁  李爱民  周庆  王莹  潘旸 《环境科学》2017,38(8):3273-3280
最近,13种新型极性卤代苯酚类消毒副产物在氯化消毒后的饮用水中被发现,它们按结构被分成4组,分别是二卤-4-羟基苯甲醛、二卤-4-羟基苯甲酸、二卤水杨酸和三卤苯酚.为研究它们在氯化消毒过程中的降解机制,选取了其中的4种全溴代种类,即3,5-二溴-4-羟基苯甲醛、3,5-二溴-4-羟基苯甲酸、3,5-二溴水杨酸以及2,4,6-三溴苯酚,利用UPLC/ESI-tq MS中的前体离子扫描,多反应监测和子离子扫描,鉴定了这几种消毒副产物在氯化消毒过程中的中间产物以及终产物,并根据这些中间产物和终产物与消毒时间的关系推测了其降解路径.结果表明,除了3,5-二溴水杨酸相对较稳定外,其余3种消毒副产物在氯化消毒过程中不稳定,通过取代、水解以及氧化等过程最终降解为卤乙酸等脂肪族小分子消毒副产物.在降解过程中有许多中间产物被检测并鉴定出来,其中包含一组具有五元环结构的新型消毒副产物(三卤代-羟基环戊烯二酮).  相似文献   
279.
The energetic decomposition of methyl ethyl ketone peroxide (MEKP) and its formulations have long been known to present a significant risk. Indeed, MEKP has the highest number of reported decomposition incidents of all organic peroxides, many of which have led to significant numbers of fatalities, injuries and damage. It is noteworthy that incidents have been reported at all stages of the product lifecycle.This paper is derived from incident-investigation work and provides a summary of serious incidents involving MEKP, followed by details of calorimetric experiments performed to investigate thermal stability of representative MEKP formulations containing varying amounts of MEKP monomer. In particular we report the wide degree of variation that exists between commercial MEKP formulations, even between materials that are of the same nominal formulation. Such variations are detectable using differential scanning calorimetry (DSC).Follow-up studies performed on a representative MEKP formulation containing MEKP monomer indicate that a risk of decomposition exists at temperatures well below the reported self-accelerating decomposition temperature (SADT) of the products. As such, the experimental results reported here suggest that lower storage temperatures (commonly recommended by manufacturers to maximise shelf life) should be considered as being essential throughout the product lifecycle to reduce the risk of accidents in storage and transportation.  相似文献   
280.
烟草凋萎叶早期腐解液对莴苣的化感作用   总被引:2,自引:0,他引:2  
为了研究烟草凋萎叶早期腐解液及其不同组分的化感作用,以对化感物质具有高敏感性的莴苣(Lactuca sativa)为指示材料,对烟草品种K326凋萎叶早期腐解液及其分离后的各组分分别进行了化感潜力的生物测定.结果表明:1)早期腐解液及其组分随处理浓度的增大对莴苣种子萌发的抑制效应逐渐增强,且显著降低了种子萌发速率,并延...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号