美国和中国油气系统甲烷排放状况

文章通过调研、分析美国和中国近年来油气系统中甲烷排放状况,对比分析美国与中国应用的主要甲烷计算方法,表明:美国油气系统中对甲烷排放量的计算方法可采用1996IPCC指南中提供的第一层次(Tier1)和第二层次(Tier2)法,计算结果相对比较准确,甲烷的排放呈逐年增加趋势;中国油气系统中甲烷排放量的计算方法目前只限于1996IPCC指南中提供的Tier1法,中国甲烷排放量相对于美国等发达国家较少,但整体呈增长趋势。     

海水中石油类国标分析方法存在的问题及改进建议

当前海水石油类分析三种国标方法存在代表性和适用性不足的问题,不同方法的数据间缺乏可比性,给政府和民众控制水体污染、评价水质状况带来偏差和不便。建议国家相关部门修订海水石油类分析方法,将水质石油类分析国标方法统一为红外分光光度法。通过海水样品加标实验验证了该方法的可行性,实际操作简便、准确。     

Assessing the Relationship Between Landscape Patterns and Nonpoint‐Source Pollution in the Danjiangkou Reservoir Basin in China1

Abstract: The constrained ordination method from quantitative ecology was utilized to assess the relationship between landscape patterns and nonpoint‐source (NPS) pollution for the purpose of identifying effective water‐quality improvement practices in Danjiangkou Reservoir (DJKR) basin, China. The soil and water assessment tool (SWAT) was applied to simulate NPS pollution and the Fragstats model was applied to calculate the landscape metrics. The study concluded that organic nutrients formed the main NPS pollutant in the DJKR basin and that most of the NPS pollution occurred along with soil loss. Based on partial redundancy analysis, the conclusion that landscape metrics were significantly correlated to NPS pollution indices was obtained. Specifically, the composition of LULC (land use/land cover) was the most effective factor to estimate NPS pollution. Dry cultivated land was identified as the main source of NPS pollution, and paddy fields were characterized with the most intensive soluble nutrients loss. In addition, the reason that fragmented and complex landscape patterns exacerbate NPS pollution was that natural landscape composed most of this area. Moreover, the fragmented natural landscape indicated intensive agricultural activities that were the crucial trigger for NPS pollution. Combined with the economic condition in China, Conversion of Cropland to Forests Program (CCFP) should be conducted selectively and gradually in the DJKR basin.     

Estimating chemical biotransformation rates from food web concentrations

Biotransformation is widely recognized as the most important and most uncertain determinant of bioaccumulation. A step-wise method for estimating organism-specific biotransformation half-lives from field observations and using established food web modeling is developed. As a proof of concept, the method is applied to the case of nine polycyclic aromatic hydrocarbons (PAHs) in a well-studied food web in Bohai Bay, China. The estimated half-lives are in good agreement with the existing literature. The proposed biotransformation estimation method, through data mining, for sufficiently defined ecosystems, may greatly reduce the necessary animal testing involved in chemical assessments by providing useful guidance to experimentalists and regulators.     

Hexavalent chromium reduction kinetics in rodent stomach contents

Reduction of hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) in the stomach prior to absorption is a well-recognized detoxification process thought to limit the toxicity of ingested Cr(VI). However, administration of high concentrations of Cr(VI) in drinking water cause mouse small intestinal tumors, and quantitative measures of Cr(VI) reduction rate and capacity for rodent stomach contents are needed for interspecies extrapolation using physiologically-based toxicokinetic (PBTK) models. Ex vivo studies using stomach contents of rats and mice were conducted to quantify Cr(VI) reduction rate and capacity for loading rates (1-400 mg Cr(VI) L⁻¹ stomach contents) in the range of recent bioassays. Cr(VI) reduction was measured with speciated isotope dilution mass spectrometry to quantify dynamic Cr(VI) and Cr(III) concentrations in stomach contents at select time points over 1 h. Cr(VI) reduction followed mixed second-order kinetics, dependent upon concentrations of both Cr(VI) and the native reducing agents. Approximately 16 mg Cr(VI)-equivalents of reducing capacity per L of fed stomach contents (containing gastric secretions, saliva, water and food) was found for both species. The second-order rate constants were 0.2 and 0.3 L mg⁻¹ h⁻¹ for mice and rats, respectively. These findings support that, at the doses that caused cancer in the mouse small intestine (?20 mg Cr(VI) L⁻¹ in drinking water), the reducing capacity of stomach contents was likely exceeded. Thus, for extrapolation of target tissue dose in risk assessment, PBTK models are necessary to account for competing kinetic rates including second order capacity-limited reduction of Cr(VI) to Cr(III).     

国内外油田污水处理技术发展概况

随着国内外油田开发,各种采油废水处理技术在油田得到了应用和发展。但由于采油废水的复杂性,导致在选择合适的水处理技术时难度加大,文章将当前众多采油废水处理技术进行综述,以期为选择有针对性的采油废水处理技术提供依据。     

动态稀释法在汽车涂装行业固定污染源挥发性有机物测定中的应用

介绍了固定污染源中挥发性有机物(VOCs)的主要采样方法,并重点介绍了动态稀释法在固定污染源中采样的应用。采用动态稀释法取样,对某汽车企业涂装车间的排放废气进行了定性分析,并对其中主要的10种VOCs进行了定量分析。研究了方法测定的稳定性,10种化合物相对标准偏差为9%~32%,符合工况变动范围。将不同采样时间及不同吸附材料的测定结果与在线监控数据进行比较,结果显示动态稀释法的测定结果均在实际工况波动范围内,说明该方法能够较好地满足汽车涂装行业VOCs的采样要求。     

VOCs快速检测在某化工企业搬迁遗留污染场地调查中的应用

以天津市某化工企业搬迁遗留污染场地为例,采用VOCs快速检测法辅助现场钻孔取样,以初步判断土壤污染深度,同时将现场样品送实验室检测。试验表明,VOCs快速检测法与实验室检测法结果基本一致。将452个样品测定结果做比对,结果表明实验室检测数据VOCs加和值与快速检测法现场检测数据存在显著相关,R2为0.803 7。污染物主要集中于场地5 m~9 m的粉土层中。其中,13种VOCs检出,4种VOCs超过《场地土壤环境风险评价筛选值》(DB11/T 811—2011)商业用地筛选值。     

One common way — The strategic and methodological influence on environmental planning across Europe

In the last decades the European Union exerted influence on precautionary environmental planning by the establishment of several Directives. The most relevant were the Habitat-Directive, the EIA-Directive, the SEA-Directive and the Water Framework Directive. Comparing these EU policies in the area of environmental precaution it becomes obvious that there is a lot of common ground. Thus, the conclusion seems likely that the European Union, in doing so, has intended to establish general planning concepts through introducing several methodological steps indicated by the regulations. The goal of this article is firstly to point out, which are the common planning principles, converted by methodological elements and secondly examine the consideration of these planning concepts by the implementation and application in the member states. In this context it is analysed whether the connections and divergences between the directives lead to significant differences in the implementation process. To this aim the directives are shortly introduced and significant steps of the processes regulated by them are outlined. In the second steps the national legal implementation in the Alpine states and its consequences for the practical application are discussed. The results show a heterogeneous application of the EU principles. Within the comparative view on the four directives influence and causalities between the national implementation and the practical application were identified, which can be simplified as four types. Since a coherent strategic and methodological concept for improving environmental precaution planning from part of the EU is noticeable, more unity and comparability within the implementation is desirable, particularly in areas with comparable habitats such as the alpine space. Beyond this the trade-off between the directives poses an important task for the future.     

An Application of the Pump-to-Fill Policy for Management of Urban Stormwater

We consider the management of urban stormwater in two connected dams. Stormwater generated by local rainfall flows into a capture dam and is subsequently pumped into a similar sized holding dam. We assume random gross inflow and constant demand. If we wish to minimise overflow from the system then the optimal management policy is to pump as much water as possible each day from the capture dam to the holding dam without allowing the holding dam to overflow. We shall refer to this policy as the pump-to-fill policy. The model is based on the Parafield stormwater management system in the City of Salisbury (CoS) but assumes constant demand instead of level dependent outflow. If there is insufficient water in the holding dam to meet the desired daily demand then all water in the holding dam is used and the shortfall is obtained from other sources. CoS, in suburban Adelaide in South Australia, is recognised in local government circles as a world leader in urban stormwater management. The water is supplied to local industry to replace regular mains water and is also used to restore and maintain urban wetlands. In mathematical terms the pump-to-fill policy defines a Markov chain with a large transition matrix and a characteristic regular block structure. We use specialised Matrix Analytic Methods to decompose the event space and find simplified equations for the steady state probability vector. In this way we enable an elementary solution procedure which we illustrate by solving the modified Parafield problem. The optimal nature of the pump-to-fill policy is established in a recent paper by Pearce et al. (JIMO 3(2):313–320, 2007). The purpose of the current study is to find optimal management policies for urban stormwater systems. Work supported by the Australian Research Council.