全文获取类型
收费全文 | 830篇 |
免费 | 75篇 |
国内免费 | 303篇 |
专业分类
安全科学 | 50篇 |
废物处理 | 111篇 |
环保管理 | 84篇 |
综合类 | 603篇 |
基础理论 | 107篇 |
污染及防治 | 212篇 |
评价与监测 | 25篇 |
社会与环境 | 14篇 |
灾害及防治 | 2篇 |
出版年
2024年 | 2篇 |
2023年 | 6篇 |
2022年 | 12篇 |
2021年 | 22篇 |
2020年 | 15篇 |
2019年 | 14篇 |
2018年 | 30篇 |
2017年 | 18篇 |
2016年 | 27篇 |
2015年 | 39篇 |
2014年 | 49篇 |
2013年 | 95篇 |
2012年 | 76篇 |
2011年 | 78篇 |
2010年 | 53篇 |
2009年 | 77篇 |
2008年 | 69篇 |
2007年 | 81篇 |
2006年 | 68篇 |
2005年 | 51篇 |
2004年 | 35篇 |
2003年 | 65篇 |
2002年 | 45篇 |
2001年 | 28篇 |
2000年 | 34篇 |
1999年 | 27篇 |
1998年 | 20篇 |
1997年 | 5篇 |
1996年 | 16篇 |
1995年 | 19篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1208条查询结果,搜索用时 31 毫秒
871.
Effects of inorganic chlorine source on dioxin formation using fly ash from a fluidized bed incinerator 总被引:2,自引:0,他引:2
LU Sheng-yong YAN Jian-hu LI Xiao-dong Ni Ming-jiang CEN Ke-f DAI Hui-fen 《环境科学学报(英文版)》2007,19(6):756-761
Chlorine source is indispensable for polychlorinated dibenzo-p-dioxin and furan (PCDD/F) formation during municipal solid waste (MSW) incineration. Inorganic chlorine compounds were employed in this study to investigate their effects on PCDD/F formation through heterogeneous synthesis on fly ash surfaces. A fly ash sample obtained from a fluidized bed incinerator was sieved to different size fractions which served as the PCDD/F formation sources. The capability of different metal chlorides which facilitate the formation of PCDDs/Fs was found to follow the trends: Na < Mg < K < Al < Ca, when two particle fractions of >177 μm and 104-125 μm were used in the experiments. However, the capability of NaCl, MgCl2 and KCl did not seem much different from each other, whereas CaCl2 and AlCl3 were much more active in PCDD/F formation. NaCl and MgCl2 were relatively effective to produce more PCDDs, while KCl, AlCl3 and CaCl2 generated more PCDFs during heterogeneous reactions occurring on fly ash. 2,3,7,8-TCDF was the most significant contributor to the toxicity of the PCDDs/Fs formed from inorganic chlorine sources. Decreasing the sizes of fly ash particles led to more active formation of PCDDs/Fs when NaCl was used as inorganic chlorine in the experiment. The highest PCDDs/Fs produced from particles with size <37 μm, while the lowest PCDDs/Fs produced from particles with size >177 μm. The toxicity generally increased with decreasing size of the fly ash particles. The formation of PCDDs was mainly facilitated by the two size fractions, 104-125 μm and <37 μm, while formation of PCDFs was favored by the two other size fractions, >177 μm and 53-104 μm. 相似文献
872.
Simultaneous removal of ammonium and phosphate by zeolite synthesized
from coal fly ash as influenced by acid treatment 总被引:5,自引:0,他引:5
ZHANG Bao-hu WU De-yi WANG Chong HE Sheng-bing ZHANG Zhen-ji KONG Hai-nan 《环境科学学报(英文版)》2007,19(5):540-545
Zeolite synthesized from fly ash (ZFA) without modification is not efficient for the purification of NH4+ and phosphate at low concentrations that occur in real effluents, despite the high potential removal capacity. To develop an effective technique to enhance the removal efficiency of ammonium and phosphate at low concentrations, ZFA was modified with acid treatment and the simultaneous removal of ammonium and phosphate in a wide range of concentration was investigated. It was seen that when compared with untreated ZFA, only the treatment by 0.01 mol/L of H2SO4 significantly improved the removal efficiency of ammonium at low initial concentrations. The behavior was well explained by the pH effect. Treatment by more concentrated H2SO4 led to the deterioration of the ZFA structure and a decrease in the cation exchange capacity. Treatment by 0.01 mol/L H2SO4 improved the removal efficiency of phosphate by ZFA at all initial P concentrations, while the treatment by concentrated H2SO4 (≥0.9 mol/L) resulted in a limited maximum phosphate immobilization capacity (PIC). It was concluded that through a previous mild acid treatment (e.g. 0.01 mol/L of H2SO4), ZFA can be used in the simultaneous removal of NH4+ and P at low concentrations simulating real effluent. 相似文献
873.
Optimization for solidification of low-level-radioactive resin using Taguchi analysis 总被引:3,自引:0,他引:3
Solidification of low-level-radioactive (LLW) resin was optimized using Taguchi analytical methodology. The ingredients in LLW mortar which caused the solidification of cement were evaluated through consecutive measurements of the effects of various concentrations of ingredients. Samples selected according to Taguchi's method were separated into 18 different categories and measured at the 7th, 21st, and 28th day after fabrication on developing effects. Evaluations of the various samples focused on whether the compressive and bending strength fulfilled the special criteria of the Taiwan Power Company (TPC). Similar results indicated that both furnace slag and fly ash were the dominant material resulting from the solidification of LLW mortar. The superior combination was obtained as furnace slag 24 wt.%, fly ash 24 wt.%, and cement 8 wt.% to mix 24 wt.% of resin with 20 wt.% of water, to fulfill the contemporary requirements of TPC. 相似文献
874.
875.
876.
为研究谷壳灰制备硅肥对水稻不同生育期土壤重金属镉(Cd)和砷(As)生物有效性、酶活性、微生物群落结构和糙米重金属含量的影响,开展水稻盆栽试验.结果表明,施用0.1%~1.0%谷壳灰硅肥能提高土壤pH值0.04~0.24个单位,有效硅含量44.2%~97.5%,也能降低土壤有效态Cd含量16.2%~21.4%,有效态As含量16.0%~24.9%;随施加量的增大各生育期土壤酶活性增大,其中蔗糖酶活性显著增大6.3%~145.7%,脱氢酶活性显著增大6.7%~224.1%;分析土壤成熟期微生物群落结构显示,施用谷壳灰硅肥不影响微生物α-多样性,但对微生物β-多样性产生显著影响,促进微生物生长,维持群落结构稳定性;随施加量的增大,糙米Cd含量降低了29.3%~89.7%,糙米总As和无机As含量分别降低7.8%~42.3%和17.2%~44.5%,当施用量在0.5%和1.0%时水稻糙米ω(Cd)<0.2 mg·kg-1,ω(无机As)<0.35 mg·kg-1.综上,谷壳灰硅肥能改善土壤质量、降低糙米Cd和As含量,具有环境友好性,可用于Cd和As复合污染稻田土壤的治理. 相似文献
877.
878.
煤矸石-粉煤灰-废石膏烧结陶粒 总被引:2,自引:0,他引:2
采用制粒烧结工艺成功地把煤矸石、粉煤灰及废石膏(或烟气脱硫污泥)制备成建筑用轻质陶粒,实现了对上述固体废物的资源化和稳定化。煤矸石等的配料比以及粉状原料的颗粒尺寸分布是在成球盘中制粒的主要影响因素。烧结过程中的影响因素较多,但烧结温度是影响产品质量的主要因素。煤矸石-粉煤灰-废石膏陶粒烧结过程发生在950—1250℃,最佳烧结温度为1200±50℃,制得的陶位坚硬如岩石,容重等级为900,筒压强度为9—15MPa,超过GB2838-81的筒压强度≥6.5MPa的规定。 相似文献
879.
880.
循环流化床电站排放烟尘特性及痕量重金属分析 总被引:3,自引:1,他引:2
对35t h循环流化床电厂电除尘器入口和出口的烟气气溶胶进行分级取样,得到飞灰浓度和粒度分布以及电除尘器的分级脱除效率.电除尘器对PM10、PM2 5的脱除效率分别为94 34%和91 38%,使部分可吸入烟尘颗粒穿透除尘设备而直接排放到大气环境中.同时对不同粒度飞灰中重金属含量进行了测试,得到痕量元素浓度从高到低依次为Ni,Cr,Cu,Cd,Pb,Hg.痕量重金属含量与飞灰粒径有一定依附关系,其分布规律与煤成分、锅炉燃烧方式和痕量元素自身的挥发特性等因素有关. 相似文献