全文获取类型
收费全文 | 5878篇 |
免费 | 658篇 |
国内免费 | 916篇 |
专业分类
安全科学 | 1577篇 |
废物处理 | 513篇 |
环保管理 | 815篇 |
综合类 | 2924篇 |
基础理论 | 351篇 |
环境理论 | 5篇 |
污染及防治 | 484篇 |
评价与监测 | 410篇 |
社会与环境 | 314篇 |
灾害及防治 | 59篇 |
出版年
2024年 | 18篇 |
2023年 | 81篇 |
2022年 | 153篇 |
2021年 | 226篇 |
2020年 | 232篇 |
2019年 | 211篇 |
2018年 | 167篇 |
2017年 | 255篇 |
2016年 | 274篇 |
2015年 | 333篇 |
2014年 | 346篇 |
2013年 | 478篇 |
2012年 | 530篇 |
2011年 | 515篇 |
2010年 | 352篇 |
2009年 | 365篇 |
2008年 | 220篇 |
2007年 | 376篇 |
2006年 | 382篇 |
2005年 | 278篇 |
2004年 | 201篇 |
2003年 | 237篇 |
2002年 | 205篇 |
2001年 | 179篇 |
2000年 | 168篇 |
1999年 | 131篇 |
1998年 | 106篇 |
1997年 | 101篇 |
1996年 | 97篇 |
1995年 | 61篇 |
1994年 | 58篇 |
1993年 | 34篇 |
1992年 | 26篇 |
1991年 | 14篇 |
1990年 | 18篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有7452条查询结果,搜索用时 869 毫秒
561.
按照水质情况,将多种来源于不同工业生产过程中的高浓度有机废水划分为高悬浮固体乳化液废水、难生化高浓度有机废水、高悬浮固体不含油有机废水、含铬有机废水和杂质含量较少的乳化液废水5类,分别采用酸化破乳/Fen-ton氧化/混凝/絮凝、Fenton氧化/混凝/絮凝、混凝/絮凝、还原/混凝/絮凝、震动膜过滤技术作为生化预处理技术,并通过小试和中试验证了各技术的效果。实验结果表明,按照上述分类结果,采用不同预处理技术可以得到良好的效果,废水水质明显改善,满足继续生化处理的基本条件。各预处理生产装置处理效果稳定,同时生化系统已经稳定运行120天以上,COD去除率超过90%,出水经过低剂量的Fenton试剂处理后可达到《污水排入城镇下水道水质标准》(CJ343-2012)。 相似文献
562.
电吸附技术作为高效、环境友好型的除盐、除氨氮技术,可应用与水的深度处理领域内。为了使污水回用达到工业用水的水质标准,对电吸附去除水中盐类、氨氮、COD的效果进行分析,结果表明,电吸附设备处理不同氨氮浓度的废水,对中低浓度的氨氮去除效果稳定,当进水氨氮浓度低于20 mg/L时,处理后出水氨氮浓度低于5 mg/L,COD浓度小于25 mg/L,达到回用标准;随着进水盐浓度的增大电吸附处理效果逐渐变差,在电导率低于2 500 μS/cm时除盐率在75%左右,氨氮去除率达到70%左右,COD去除率达到60%左右。经电吸附处理后的低氨氮浓度废水,TDS、氨氮浓度均可达到工业回用水标准。 相似文献
563.
为研究间歇运行式生物滴滤池对油漆生产厂废气净化能力,建立一座中试规模生物滴滤池(BTF),接种降解菌群,采用8 h/d运行方式净化某油漆厂包装车间废气,并用PCR-DGGE技术揭示BTF细菌群落结构与工艺运行条件间的联系。油漆厂包装车间废气中挥发性有机物(VOCs)主要为甲苯、乙苯、混合二甲苯(间、对和邻二甲苯),BTF对甲苯、乙苯、混合二甲苯最大去除率分别为88.8%、83.7%和86.3%。DGGE分析显示,BTF稳定运行时,主要优势菌相对丰度较为稳定(F,P>0.05),其细菌多样性显著低于启动期(F,P>0.05);同时,下层填料细菌多样性高于上层填料,其细菌结构变化也较上层明显;另外,提升培养液浓度至2倍和4倍对菌群结构亦无显著影响。 相似文献
564.
采用浸渍法制备了不同NiO和CuO质量分数的NiO-CuO/ZSM-5催化剂,并以CH4为还原剂研究了NiO-CuO/ZSM-5催化剂对催化裂化烟气的脱硫脱硝活性。XRD分析结果表明,NiO质量分数为4%、CuO质量分数为6%的催化剂4%NiO-6%CuO/ZSM-5中的ZSM-5结构完好,CuO和NiO高度分散在ZSM-5骨架中,表明具有较好的催化活性。4%NiO-6%CuO/ZSM-5的脱硫脱硝起活温度均较低,无氧条件下最高NO转化率和SO2转化率分别为94.7%和95.9%,O2体积分数为1.0%时的NO转化率和SO2转化率分别为97.7%和89.0%。 相似文献
565.
Evaluation of a classification method for biodegradable solid wastes using anaerobic degradation parameters 总被引:1,自引:0,他引:1
Wei Zheng Khamphe Phoungthong Fan Lü Li-Ming Shao Pin-Jing He 《Waste management (New York, N.Y.)》2013,33(12):2632-2640
We studied the biochemical and anaerobic degradation characteristics of 29 types of materials to evaluate the effects of a physical composition classification method for degradable solid waste on the computation of anaerobic degradation parameters, including the methane yield potential (L0), anaerobic decay rate (k), and carbon sequestration factor (CSF). Biochemical methane potential tests were conducted to determine the anaerobic degradation parameters of each material. The results indicated that the anaerobic degradation parameters of nut waste were quite different from those of other food waste and nut waste was classified separately. Paper was subdivided into two categories according to its lignin content: degradable paper with lignin content of <0.05 g g VS?1, and refractory paper with lignin content >0.15 g g VS?1. The L0, k, and CSF parameters of leaves, a type of garden waste, were similar to those of grass. This classification method for degradable solid waste may provide a theoretical basis that facilitates the more accurate calculation of anaerobic degradation parameters. 相似文献
566.
以堇青石蜂窝陶瓷(CC)为载体,采用浸渍法制备了堇青石负载Pd和过渡金属混合氧化物催化剂,记作Pd-M-Mn(M=Cu,Co,Fe,Ni)/CC。实验结果表明:Pd-Co-Mn/CC催化剂的催化活性最高;随着Pd负载量的增加,CO转化率提高;当Pd负载量为1.00%时,反应温度为150℃时CO转化率达到98%,200℃时CO转化率达到100%;在反应温度150℃条件下,Pd-Co-Mn/CC催化剂(Pd负载量1.00%)的CO转化率在前30h内小幅度下降,随后稳定在90%以上,反应100h后,催化剂表面颜色由黑色变为棕褐色。 相似文献
567.
Particle-bound polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in ambient air were monitored together with particulate matter less than 10 μm (PM10) at three sampling sites of the Andean city of Manizales, Colombia; during September 2009 and July 2010. PCDD/Fs ambient air emissions ranged from 1 fg WHO-TEQ m−3 to 52 fg WHO-TEQ m−3 in particulate fraction. The PM10 concentrations ranged from 23 μg m−3 to 54 μg m−3. Concentrations of PM10 and PCDD/Fs in ambient air observed for Manizales - a medium sized city with a population of 380 000 - were comparable to concentrations in larger cities. The highest concentrations of PCDD/Fs and PM10 found in this study were determined at the central zone of the city, characterized by public transportation density, where diesel as principal fuel is used. In addition, hypothetical gas fractions of PCDD/Fs were calculated from theoretical Kp data. Congener profiles of PCDD/Fs exhibited ratios associated with different combustion sources at the different sampling locations, ranging from steel recycling to gasoline and diesel engines. Taking into account particle and gas hypothetical fraction of PCDD/Fs, Manizales exhibited values of PCDD/Fs equivalent to rural and urban-industrial sites in the southeast and center of the city respectively. Poor correlation of PCDDs with PM10 (r = −0.55 and r = 0.52) suggests ambient air PCDDs were derived from various combustion sources. Stronger correlation was observed of PCDFs with PM10. Poor correlation between precipitation and reduced PM10 concentration in ambient air (r = −0.45) suggested low PM10 removal by rainfall. 相似文献
568.
The widespread occurrence of pesticide residues in different agricultural and food commodities has raised concern among the environmentalists and food chemists. In order to keep a proper track of these materials, studies on their decay profiles in the various segments of ecosystem under varying environmental conditions are needed. In view of this, the metabolites of quinalphos in water and soil under controlled conditions and in plants, namely tomato and radish in field conditions have been analysed and possible pathways suggested. In order to follow the decay of the pesticide, an HPLC procedure has been developed. Studies conducted in water at different temperatures, pH and organic content reveal that the persistence of the pesticide decreases with the increase in all the three variables. In the three different types of soils studied, the effect of pH is more or less apparent on a similar line. On an average a faster decay is observed in the case of plants than in water and soil. The decay profiles in all these cases follow first order kinetics. The metabolites were identified by GC-MS. The investigations reflect that degradation occurs through hydrolysis, S-oxidation, dealkylation and thiono-thiol rearrangement. The pathways seem to be complex and different metabolites were observed with the change in the matrix. Quinalphos oxon, O-ethyl-O-quinoxalin-2-yl phosphoric acid, 2-hydroxy quinoxaline and quinoxaline-2-thiol were observed in all the matrices. Results further indicate that the metabolites, 2-hydroxy quinoxaline and oxon, which are more toxic than parent compound, persist for a longer time. 相似文献
569.
570.