An improved GC-ECD method for measuring atmospheric N2O

Gas chromatography equipped with an electron capture detector (GC-ECD) has been widely used for measuring atmospheric N2O,but nonlinear response and the influence of atmospheric CO2 have been recognized as defects for quantification.An original GCECD method using N 2 as carrier gas was improved by introducing a small flow rate of CO2 makeup gas into the ECD,which could well remedy the above defects.The N2O signal of the improved method was 4-fold higher than that of the original method and the relative standard deviation was reduced from > 1% to 0.31%.N2O concentrations with different CO2 concentrations (172.2×10-6-1722×10-6mol/mol) measured by the improved GC-ECD method were in line with the actual N2O concentrations.However,the N2O concentrations detected by the original method were largely biased with a variation range of-4.5%～7%.The N2O fluxes between an agricultural field and the atmosphere measured by the original method were greatly overestimated in comparison with those measured by the improved method.Good linear correlation (R2=0.9996) between the response of the improved ECD and N2O concentrations (93×10-9-1966×10-9mol/mol) indicated that atmospheric N2O could be accurately quantified via a single standard gas.Atmospheric N2O concentrations comparatively measured by the improved method and a high precision GC-ECD method were in good agreement.     

三种生活垃圾填埋场渗滤液处理工艺比较

介绍了国内目前应用最广泛的三种生活垃圾填埋场渗滤液处理工艺,并对这三种工艺从设备投资、运行成本、操作难度、技术风险等方面进行了综合比较,旨在为我国新建及改扩建渗滤液处理工程的工艺选择提供参考。     

区域产业结构演进的节能效应比较

产业结构是影响能源消费的重要因素,处在不同发展阶段的区域,其产业结构演进的节能效应有所差异。根据产业结构和能源消费强度两个因子,将全国30个省（直辖市、自治区）划分为四类区域,并从中选择北京、广东、贵州、山西作为典型代表,对其1995—2007年期间产业结构演进的节能效应情况进行纵向分析,并进一步进行横向比较。研究结果表明,各类区域在产业结构的节能效应方面既有相同之处,又有所差异。相同之处表现在：能源强度都呈现出下降态势;效率因素对能源强度的影响都比结构因素的影响大;影响能源强度变化的主要部门是能耗较高的工业和交通运输邮电仓储业,这两个部门在GDP中的比重变化以及单位能耗分别决定着结构和效率因素的节能效果。差异之处表现在：能源强度的下降幅度和阶段变化不同;结构和效率因素对能源强度的影响方向和效果不同。     

上海市水环境应急监测设备查询系统开发研究

对水环境应急现场快速检测设备查询系统的需求进行了探讨;对国内外常用环境应急监测数据库的优缺点进行研究比较;从6个方面对设备库的研制内容进行描述并分类。     

两种空气自动监测系统的比较

国产长光程空气自动监测系统是中国自行研制的更为先进、更具自动化的系统，24h点式仪器是老式空气检测仪器，对这两种新、老仪器的比较可以看出在运行过程中的利弊。     

提升我国城市化水平的重要意义和政策调整

我国的城市化水平落后于工业化水平，已成为制约我国经济与社会发展的重要因素。提升我国城市化水平，从经济上讲，具有如下重要意义：（1）有利于化解有效需求不足矛盾。（2）有利于带动相关产业增长和主人口增加。（3）有利于促进我国产业结构优化，提高经济运行质量。（4）有利于资源的综合利用和耕地保护。（5）有利于缩小城乡差距。提升我国城市化水平是我国新世纪的战略任务，必须进行相关的政策调整与选择。     

Dynamic analysis of a one-prey multi-predator impulsive system with Ivlev-type functional

Considering the Ivlev-type functional response, we develop and analyze a class of one-prey multi-predator system with impulsive effect at different fixed times. Some sufficient conditions ensuring the prey to be extinct are obtained via the Floquent theory and small amplitude perturbation skill. Using the method of comparison involving multiple Laypunov functions, we derive some conditions for the permanence of the system. Numerical simulations of the impulsive system exhibit the rich complex dynamics for the key parameters, such as symmetry-breaking pitchfork bifurcation, periodic doubling bifurcation, chaos, periodic halving cascade and crisis.     

烟气连续排放监测系统（CEMS）比对监测工作探讨

以陕西省18家30万kW以上火电机组自动监测仪器设备、比对监测的结果作为参考依据,指出CEMS比对监测存在缺乏统一管理、监管薄弱、监测方法不同、设备安装位置不规范、参数缺项的问题,并针对问题提出规范设备供应商、严把CEMS验收关、加强监管、贯彻执行国家相关文件及技术规范、强化环境执法等具体建议。     

Selecting suitable sites for animal waste application using a raster GIS

Rapid growth of intensive animal industries in southeast Queensland, Australia, has led to large volumes of animal waste production, which posses serious environmental problems in the Murray Darling Basin (MDB). This study presents a method of selecting sites for the safe application of animal waste as fertiliser to agricultural land. A site suitability map for the Westbrook subcatchment within the MDB was created using a geographic information system (GIS)-based weighted linear combination (WLC) model. The factors affecting the suitability of a site for animal waste application were selected, and digital data sets derived from up to 1:50,000 scale maps were acquired. After initial preprocessing, digital data sets were clipped to the size of the delineated subcatchment boundary producing input factors. These input factors were weighted using the analytical hierarchy process (AHP) that employed an objectives-oriented comparison (OOC) technique to formulate the pairwise comparison matrix. The OOC technique, which is capable of deriving factor weight independently, formulated the weight derivation process by making it more logical and systematic. The factor attributes were classified into multiple classes and weighted using the AHP. The effects of the number of input factors and factor weighting on the areal extent and the degree of site suitability were examined. Due to the presence of large nonagricultural and residential areas in the subcatchment, only 16% of the area was found suitable for animal waste application. The areal extent resulting from this site suitability assessment was found to be dependent on the areal constraints imposed on each input factor, while the degree of suitability was principally a function of the weight distribution between the factors.     

Ozone Episode in the Milan Metropolitan Area A Comparative Evaluation of UAM-V and CALGRID Models

Data from an ozone episode (2–5 June, 1998) in the Milan metropolitan area were used for an application of two photochemical grid models: UAM-V and CALGRID. To assure a fair comparison, the models were run on the same domain and grid size, with same source emission inputs, CALMET diagnostic meteorology, and initial and boundary conditions taken from air quality data and literature values. Hourly emissions were derived from the AutoOil-II programme inventory except for on-road mobile source emissions; a new traffic emission inventory, based on both COPERT II methodology and road classification has been developed. NO_x and O₃ concentration results were compared to local network monitoring data. Results indicate that both models predict the highest ozone values along the north-east direction and are able to reproduce the ozone daytime trend though differences can be found between the two models on ozone spatial distribution. Average normalised bias for both models is about 50%, peak daily ozone concentrations are underestimated, with simulated peak shapes broader than the observed ones and a temporal shift between the two models. Night-time concentration levels of pollutants were not successfully reproduced due to an incorrect parameterisation of vertical turbulence calling for further work.