全文获取类型
收费全文 | 248篇 |
免费 | 25篇 |
国内免费 | 66篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 22篇 |
环保管理 | 113篇 |
综合类 | 116篇 |
基础理论 | 23篇 |
污染及防治 | 13篇 |
评价与监测 | 25篇 |
社会与环境 | 22篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 10篇 |
2022年 | 9篇 |
2021年 | 4篇 |
2020年 | 9篇 |
2019年 | 11篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 12篇 |
2015年 | 9篇 |
2014年 | 11篇 |
2013年 | 11篇 |
2012年 | 12篇 |
2011年 | 16篇 |
2010年 | 16篇 |
2009年 | 7篇 |
2008年 | 20篇 |
2007年 | 10篇 |
2006年 | 21篇 |
2005年 | 16篇 |
2004年 | 8篇 |
2003年 | 7篇 |
2002年 | 17篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1987年 | 3篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 3篇 |
排序方式: 共有339条查询结果,搜索用时 15 毫秒
11.
Mara C. Diguez Claudia P. Queimalios Sergio Ribeiro Guevar Mark Marvin-DiPasquale Carolina Soto Crdenas Mara A. Arribre 《环境科学学报(英文版)》2013,25(10):1980-1991
Ligands present in dissolved organic matter (DOM) form complexes with inorganic divalent mercury (Hg^2+) affecting its bioavailability in pelagic food webs. This investigation addresses the influence of a natural gradient of DOM present in Patagonian lakes on the bioaccumulation of Hg^2+ (the prevailing mercury species in the water column of these lakes) by the algae Cryptomonas erosa and the zooplankters Brachionus calyciflorus and Boeckella antiqua. Hg^2+ accumulation was studied through laboratory experiments using natural water of four oligotrophic Patagonian lakes amended with^197Hg^2+. The bioavailability of Hg^2+ was affected by the concentration and character of DOM. The entrance of Hg^2+ into pelagic food webs occurs mostly through passive and active accumulation. The incorporation of Hg^2+ by Cryptomonas, up to 27% of the Hg^2+ amended, was found to be rapid and dominated by passive adsorption, and was greatest when low molecular weight compounds with protein-like or small phenolic signatures prevailed in the DOM. Conversely, high molecular weight compounds with a humic or fulvic signature kept Hg^2+ in the dissolved phase, resulting in the lowest Hg^2+ accumulation in this algae. In Brachionus and Boeckella the direct incorporation of Hg from the aqueous phase was up to 3% of the Hg^2+ amended. The dietary incorporation of Hg^2+ by Boeckella exceeded the direct absorption of this metal in natural water, and was remarkably similar to the Hg^2+ adsorbed in their prey. Overall, DOM concentration and character affected the adsorption of Hg^2+ by algae through competitive binding, while the incorporation of Hg^2+ into the zooplankton was dominated by trophic or dietary transfer. 相似文献
12.
13.
藏南干旱区湖泊及地热水体氢氧同位素研究 总被引:3,自引:3,他引:0
青藏高原水循环过程情况复杂,水体氢氧同位素包含了其重要信息.选取西藏南部干旱区淡水湖、咸水湖及地热水水体为研究对象,分析研究区内不同水体氢氧同位素组成、变化特征、影响因素及水循环过程.结果表明,3种水体均表现出了高海拔地区氢氧同位素组成偏负的特点,淡水湖打加芒错δ18O平均值为-17.0‰,δD平均值为-138.6‰,咸水湖朗错δ18O平均值为-6.4‰,δD平均值为-87.4‰,搭格架地热区热水δ18O平均值为-19.2‰,δD平均值为-158.2‰;受内陆干旱区强烈的蒸发作用影响,湖泊及地热水蒸发线斜率均小于8,氘过量d值均为负值;搭格架地热区热储温度较高,氢氧同位素关系存在氧漂移现象. 相似文献
14.
15.
J. Hejzlar K. Šámalová P. Boers B. Kronvang 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):487-494
Steady-state models for the prediction of P retention coefficient (R) in lakes were evaluated using data from 93 natural lakes and 119 reservoirs situated in the temperate zone. Most of the
already existing models predicted R relatively successfully in lakes while it was seriously under-estimated in reservoirs. A statistical analysis indicated the
main causes of differences in R between lakes and reservoirs: (a) distinct relationships between P sedimentation coefficient, depth, and water residence
time; (b) existence of significant inflow–outflow P concentration gradients in reservoirs. Two new models of different complexity
were developed for estimating R in reservoirs: , where τ is water residence time (year), was derived from the Vollenweider/Larsen and Mercier model by adding a calibrated parameter
accounting for spatial P non-homogeneity in the water body, and is applicable for reservoirs but not lakes, and , where [Pin] is volume-weighted P concentration in all inputs to the water body (μg l−1), was obtained by re-calibrating the OECD general equation, and is generally applicable for both lakes and reservoirs. These
optimised models yield unbiased estimates over a large range of reservoir types. 相似文献
16.
河北水库及湖泊沉积物中DDT农药的残留特征与风险评估 总被引:11,自引:0,他引:11
分析了河北省主要湖泊水库沉积物中有机氯农药(DDT)的残留特征与生态风险.2004年秋季采集了河北12个水库和2个湖泊的表层沉积物样品,利用GC-ECD测定DDTs农药的含量,在此基础上分析了其残留与组成特征以及生态风险.结果表明:1)河北省主要湖泊水库沉积物中DDTs的平均含量为3.328 ng·g-1,其含量范围为1.014~9.022 ng·g-1;并且,不同样品中DDTs的含量的差异较大,变异系数均超过65%.2)临城水库、陡河水库、龙门水库3个样点的表面沉积物中wDDT/(wDDD wDDE)>1,表明有新的DDT输入;岗南水库、邱庄水库、黄壁庄水库3个样点的表面沉积物中wDDD/wDDE>1,说明DDD降解环境为厌氧条件;其余8个样点wDDD/wDDE<1,说明DDD降解环境为好氧条件.3)所有样点中DDT、DDD和DDE浓度均低于ERM,并且大部分小于ERL,表明其生态风险大多低于10%;但11个样点的DDTs含量介于ERL和ERM之间,表明其生态风险大多介于10%~50%. 相似文献
17.
长江中下游湖泊保护和管理的若干建议 总被引:8,自引:2,他引:8
长江中下游地区是我国面向21世纪的经济重地,长江是我国唯一具有全国意义的战略水源地,是我国水资源供需平衡的最后防线。然而在自然演化宏观背景下,流域经济的高速发展,大规模开发利用等人类活动的强烈影响,引发了一系列负面环境效应。湖泊湿地生态环境被破坏问题严重,突出表现在生态调节和自我恢复功能大幅度降低,并已造成了严重的生态后果,危及长江水系的生态平衡,影响了区域经济的可持续发展。在大量野外考察和调查基础上,针对长江中下游湖泊湿地当前的生态环境状况及存在的问题,提出了若干对策和建议。 相似文献
18.
Temporal and Spatial Trends in Nutrient and Sediment Loading to Lake Tahoe,California‐Nevada,USA 下载免费PDF全文
Robert Coats Jack Lewis Nancy Alvarez Patricia Arneson 《Journal of the American Water Resources Association》2016,52(6):1347-1365
Since 1980, the Lake Tahoe Interagency Monitoring Program (LTIMP) has provided stream‐discharge and water quality data—nitrogen (N), phosphorus (P), and suspended sediment—at more than 20 stations in Lake Tahoe Basin streams. To characterize the temporal and spatial patterns in nutrient and sediment loading to the lake, and improve the usefulness of the program and the existing database, we have (1) identified and corrected for sources of bias in the water quality database; (2) generated synthetic datasets for sediments and nutrients, and resampled to compare the accuracy and precision of different load calculation models; (3) using the best models, recalculated total annual loads over the period of record; (4) regressed total loads against total annual and annual maximum daily discharge, and tested for time trends in the residuals; (5) compared loads for different forms of N and P; and (6) tested constituent loads against land use‐land cover (LULC) variables using multiple regression. The results show (1) N and P loads are dominated by organic N and particulate P; (2) there are significant long‐term downward trends in some constituent loads of some streams; and (3) anthropogenic impervious surface is the most important LULC variable influencing water quality in basin streams. Many of our recommendations for changes in water quality monitoring and load calculation methods have been adopted by the LTIMP. 相似文献
19.
Benjamin M. Jones Christopher D. Arp Kenneth M. Hinkel Richard A. Beck Joel A. Schmutz Barry Winston 《Environmental management》2009,43(6):1071-1084
Lakes are dominant landforms in the National Petroleum Reserve Alaska (NPRA) as well as important social and ecological resources.
Of recent importance is the management of these freshwater ecosystems because lakes deeper than maximum ice thickness provide
an important and often sole source of liquid water for aquatic biota, villages, and industry during winter. To better understand
seasonal and annual hydrodynamics in the context of lake morphometry, we analyzed lakes in two adjacent areas where winter
water use is expected to increase in the near future because of industrial expansion. Landsat Thematic Mapper and Enhanced
Thematic Mapper Plus imagery acquired between 1985 and 2007 were analyzed and compared with climate data to understand interannual
variability. Measured changes in lake area extent varied by 0.6% and were significantly correlated to total precipitation
in the preceding 12 months (p < 0.05). Using this relation, the modeled lake area extent from 1985 to 2007 showed no long-term trends. In addition, high-resolution
aerial photography, bathymetric surveys, water-level monitoring, and lake-ice thickness measurements and growth models were
used to better understand seasonal hydrodynamics, surface area-to-volume relations, winter water availability, and more permanent
changes related to geomorphic change. Together, these results describe how lakes vary seasonally and annually in two critical
areas of the NPRA and provide simple models to help better predict variation in lake-water supply. Our findings suggest that
both overestimation and underestimation of actual available winter water volume may occur regularly, and this understanding
may help better inform management strategies as future resource use expands in the NPRA. 相似文献
20.
L. León Vintró P.I. Mitchell A. Omarova M. Burkitbayev H. Jiménez Nápoles N.D. Priest 《Journal of environmental radioactivity》2009
New data are reported on the concentrations, isotopic composition and speciation of americium, plutonium and uranium in surface and ground waters in the Sarzhal region of the Semipalatinsk Test Site, and an adjacent area including the settlement of Sarzhal. The data relate to filtered water and suspended particulate from (a) streams originating in the Degelen Mountains, (b) the Tel′kem 1 and Tel′kem 2 atomic craters, and (c) wells on farms located within the study area and at Sarzhal. The measurements show that 241Am, 239,240Pu and 238U concentrations in well waters within the study area are in the range 0.04–87 mBq dm−3, 0.7–99 mBq dm−3, and 74–213 mBq dm−3, respectively, and for 241Am and 239,240Pu are elevated above the levels expected solely on the basis of global fallout. Concentrations in streams sourced in the Degelen Mountains are similar, while concentrations in the two water-filled atomic craters are somewhat higher. Suspended particulate concentrations in well waters vary considerably, though median values are very low, at 0.01 mBq dm−3, 0.08 mBq dm−3 and 0.32 mBq dm−3 for 241Am, 239,240Pu and 238U, respectively. The 235U/238U isotopic ratio in almost all well and stream waters is slightly elevated above the ‘best estimate’ value for natural uranium worldwide, suggesting that some of the uranium in these waters is of test-site provenance. Redox analysis shows that on average most of the plutonium present in the microfiltered fraction of these waters is in a chemically reduced form (mean 69%; 95% confidence interval 53–85%). In the case of the atomic craters, the proportion is even higher. As expected, all of the americium present appears to be in a reduced form. Calculations suggest that annual committed effective doses to individual adults arising from the daily ingestion of these well waters are in the range 11–42 μSv (mean 21 μSv). Presently, the ground water feeding these wells would not appear to be contaminated with radioactivity from past underground testing in the Degelen Mountains or from the Tel′kem explosions. 相似文献