全文获取类型
收费全文 | 5389篇 |
免费 | 671篇 |
国内免费 | 2913篇 |
专业分类
安全科学 | 322篇 |
废物处理 | 209篇 |
环保管理 | 600篇 |
综合类 | 4939篇 |
基础理论 | 1073篇 |
环境理论 | 1篇 |
污染及防治 | 917篇 |
评价与监测 | 416篇 |
社会与环境 | 277篇 |
灾害及防治 | 219篇 |
出版年
2024年 | 34篇 |
2023年 | 176篇 |
2022年 | 309篇 |
2021年 | 323篇 |
2020年 | 352篇 |
2019年 | 323篇 |
2018年 | 321篇 |
2017年 | 309篇 |
2016年 | 389篇 |
2015年 | 350篇 |
2014年 | 382篇 |
2013年 | 602篇 |
2012年 | 511篇 |
2011年 | 558篇 |
2010年 | 406篇 |
2009年 | 378篇 |
2008年 | 328篇 |
2007年 | 407篇 |
2006年 | 377篇 |
2005年 | 312篇 |
2004年 | 262篇 |
2003年 | 292篇 |
2002年 | 221篇 |
2001年 | 181篇 |
2000年 | 156篇 |
1999年 | 158篇 |
1998年 | 84篇 |
1997年 | 89篇 |
1996年 | 82篇 |
1995年 | 62篇 |
1994年 | 55篇 |
1993年 | 57篇 |
1992年 | 38篇 |
1991年 | 33篇 |
1990年 | 15篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1972年 | 1篇 |
排序方式: 共有8973条查询结果,搜索用时 31 毫秒
991.
城市生态系统服务功能的价值结构分析 总被引:28,自引:0,他引:28
本文从城市生态系统价值体系出发,探讨城市自然资本,经济资本和社会资本综合测算的理论与方法,结果表明:示范区的自然总资本以年均4%的速度递减,其真实总资本年均增长率为4.5%而不是国内生产总值的12.6%,自然资本的增减应成为衡量一个城市或区域是否实现可持续发展的核心指标。城市生态系统中自然资本由持续递减变为递增,是实现人类共同追求的可持续发展目标必由之路。 相似文献
992.
应用大量的调查和试验数据,论述了红壤区耕地有机物质资源的种类、数量及分布状况;分析了目前有机物质利用的现状及存在问题;探讨了开发有机肥料资源的对策。 相似文献
993.
994.
Gerald Spindler Konrad Müller Hartmut Herrmann 《Environmental science and pollution research international》1999,6(2):89-94
Aerosol filter samples have been collected nearby the industrialised basin of Leipzig in Saxony (Germany) at the research station Melpitz of the Institut für Troposphärenforschung e.V. (IfT). Time series (1992–1998) and a three year comparison (1995–1997) of two different aerosol filter sampling systems, the Sierra-Andersen-PM 10 high volume sampler (daily sample, PM 10 inlet) and the Rupprecht and Patashnik Co. Inc. Model Partisol 2000 (weekly sample, PM 10 and PM 2.5 inlet) are presented and discussed. The comparison of the different sampling systems and strategies yields small differences between the daily and weekly samples for mass and different ions, which may be influenced by sampling duration and flow rates. A general trend of change in aerosol composition was observed: Soot and Sulphate concentrations decreased whereas Nitrate and Ammonium concentrations increased. During summers the mass of coarse particles is higher than in other seasons. One reason could be found in the occurence of longer periods of dry ground surfaces enabling reemission of crustal and biological material. The time series have been integrated in a longer historical aerosol mass trend for Saxony and do show a good agreement. Since 1990 a significant downward trend in gravimetric mass concentration was found. 相似文献
995.
An overview of the application of organic geochemistry to the analysis of organic matter on aerosol particles is presented
here. This organic matter is analyzed as solvent extractable bitumen/ lipids by gas chromatography-mass spectrometry. The
organic geochemical approach assesses the origin, the environmental history and the nature of secondary products of organic
matter by using the data derived from specific molecular analyses. Evaluations of production and fluxes, with cross-correlations
can thus be made by the application of the same separation and analytical procedures to samples from point source emissions
and the ambient atmosphere. This will be illustrated here with typical examples from the ambient atmosphere (aerosol particles)
and from emissions of biomass burning (smoke).
Organic matter in aerosols is derived from two major sources and is admixed depending on the geographic relief of the air
shed. These sources are biogenic detritus (e.g., plant wax, microbes, etc.) and anthropogenic particle emissions (e.g., oils,
soot, synthetics, etc.). Both biogenic detritus and some of the anthropogenic particle emissions contain organic materials
which have unique and distinguishable compound distribution patterns (C14-C40). Microbial and vascular plant lipids are the dominant biogenic residues and petroleum hydrocarbons, with lesser amounts
of the pyrogenic polynuclear aromatic hydrocarbons (PAH) and synthetics (e.g., chlorinated compounds), are the major anthropogenic
residues.
Biomass combustion is another important primary source of particles injected into the global atmosphere. It contributes many
trace substances which are reactants in atmospheric chemistry and soot paniculate matter with adsorbed biomarker compounds,
most of which are unknown chemical structures. The injection of natural product organic compounds into smoke occurs primarily
by direct volatilization/steam stripping and by thermal alteration based on combustion temperature. Although the molecular
composition of organic matter in smoke particles is highly variable, the molecular tracers are generally still source specific.
Retene has been utilized as a tracer for conifer smoke in urban aerosols, but is not always detectable. Dehydroabietic acid
is generally more concentrated in the atmosphere from the same emission sources. Degradation products from biopolymers (e.g.,
levoglucosan from cellulose) are also excellent tracers. An overview of the biomarker compositions of biomass smoke types
is presented here. Defining additional tracers of thermally-altered and directly-emitted natural products in smoke aids the
assessment of the organic matter type and input from biomass combustion to aerosols. The precursor to product approach of
compound characterization by organic geochemistry can be applied successfully to provide tracers for studying the chemistry
and dispersion of ambient aerosols and smoke plumes.
Presented at the 6th FECS Conference on Chemistry and the Environment, Atmospheric Chemistry and Air Pollution, August 26–28,
1998, Copenhagen. 相似文献
996.
Organic residue decomposition: The minicontainer-system a multifunctional tool in decomposition studies 总被引:1,自引:0,他引:1
Gerhard Eisenbeis Ralf Lenz Thomas Heiber 《Environmental science and pollution research international》1999,6(4):220-224
The Minicontainer-test, first described by Eisenbeis (1993), was designed to study the kinetics of organic residue decomposition
at a microsite level. It is derived from the litterbag technique and consists of polyethylene minicontainers (volume about
1.5 cm3) filled with a test substrate (litter, straw, cellulose, etc.). The minicontainers (MCs) are closed at either end with plastic
gauze discs of variable mesh size (e.g. 20 μm, 250 μm, 500 μm or 2 mm). A definite number of such units are inserted into
PVC-bars, which can be implanted into the soil horizontally or vertically, or be exposed on the soil surface horizontally.
The bars are very stable and can be exposed in different environments for months to years. If required, the bars can be removed
temporarily and stored, e.g. during soil cultivation. Should fresh litter be used, two phases of decomposition can be distinguished:
a fast initial phase, which can be mainly related to the effect of leaching, and a second slow phase depending mainly on the
activity of soil organisms and litter quality. Several questions can be addressed to investigations using MCs, e.g. 1) parts
of the soil fauna which are involved in decomposition (nematodes, microarthropods, and smaller specimens of the macrofauna,
e.g. enchytraeidae, diplopods and dipteran larvae) can be extracted from the litter substrate using a miniscale high gradient
extractor, 2) the organic mass loss of litter can be determined, 3) microbial biomass (Cmic, Nmic) can be assessed by fumigation extraction and 4) microbial activity (respiration) in the test substrate can also be assessed
by use of standardised methods. Compared to litterbag studies, the larger number of small replicate units improves the statistical
evaluation. Until today the Minicontainer-test has been applied in forestry and agriculture, e.g. studying the effects of
liming, soil restoration and the application of insecticides, e.g. Diflubenzuron (Dimilin) and Btk (Bacillus thuringiensis var.kurstaki). 相似文献
997.
混合堆肥过程中挥发性固体含量的层次效应及动态变化 总被引:7,自引:1,他引:6
城市污泥与猪粪混合堆肥表明:升温期和高温期堆体上部有机物降解的差异较大,降温期堆体下部各层有机物降解的差异较大,且堆体内挥发性固体(VS)含量已形成明显的层次效应,腐熟期堆体中部有机物降解的差异较大,堆体内VS含量的层次效应仍很明显;不同堆肥期堆体内VS含量的差异由大到小分别为:降温期≥腐熟期>高温期>升温期,不同部位有机物降解程度由大到小为:上部>中部>下部;VS含量随时间的变化满足一级反应动力学方程,城市污泥和猪粪混合堆肥过程中VS的降解速率约为0.3kg·d-1,VS含量降低了8.2%. 相似文献
998.
渗滤液中有机化合物在电化学氧化和厌氧生物组合系统中的降解 总被引:14,自引:2,他引:12
根据GC-MS分析,垃圾渗滤液中有机组分大多是难生物降解的有机化合物,如酚类、杂环类、杂环芳烃、多环芳烃类化合物,约占渗滤液中有机组分的70%以上. 本文对渗滤液中典型有机化合物在电化学氧化和厌氧生物组合工艺系统中的降解特性进行了系统研究. 结果表明,在电化学处理系统中,杂酚类、酰胺类、苯并噻唑、苯醌、喹啉、萘等有机化合物降解速率高于外-2-羟基桉树脑和异喹啉等化合物,但前者在厌氧生物处理系统中去除率低;渗滤液原水经过电化学氧化处理后,挥发性脂肪酸(VFA)含量从原水中的0.68%增加到电化学出水中的16.18%;此组合工艺能够显著降低因渗滤液复杂组分间的增效协同作用和拮抗作用而引起的毒性,系统出水可生化性增强,为进一步研究垃圾渗滤液的处理技术和进行该组合处理系统的大规模开发提供参考. 相似文献
999.
1000.
北京市大气细颗粒物对Balb/c 3T3细胞周期的影响 总被引:2,自引:0,他引:2
研究了北京市大气细颗粒物有机提取物 (EOC)对Balb c 3T3细胞周期及调节因子的影响 .实验发现 116 μg mL细颗粒物EOC即有明显的细胞毒性 ,抑制细胞生长 ,并存在剂量 反应关系 ,IC50 为 4 0 2 2 μg mL ;流式细胞仪分析显示 136 6 μg mLPM2 5EOC可造成细胞周期改变 ,G0 G1期、G2 M期细胞分布增加 ,分别为 16 2 4 % (P <0 0 1)与 3 17% (P <0 0 5 ) ,S期细胞分布减少 2 0 4 % (P <0 0 1) ,并伴有P5 3含量的增加 ;4 0 9 8、4 78 1μg mL的PM2 5EOC可诱导Balb c3T3细胞凋亡 .提示PM2 5有机提取物可能通过P5 3途径引起Balb c 3T3细胞周期阻滞 ,并诱导细胞凋亡 . 相似文献