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181.
1 IntroductionVolatileorganiccompounds (VOCs)areimportantairpollutantsintheurbanatmosphere .SomeVOCsaretoxicandpotentiallycarcinogenic.ExposuretoVOCsisofconcernasitmayresultinsignificantrisktohumanhealth .AmbientVOCsareemittedfromvariousurban ,industrial… 相似文献
182.
Helena Bichão Anna-Karin Borg-Karlson Atle Wibe Jorge Araújo Hanna Mustaparta 《Chemoecology》2005,15(4):211-226
Summary. An important question in insect-plant interactions is which of the numerous plant compounds contribute to the perception of
odour qualities in herbivorous insects and are likely to be used as cues in host-searching behaviour. In order to identify
which plant-produced volatiles the strawberry blossom weevil Anthonomus rubi detects, we have used electrophysiological recordings from single olfactory neurones linked to gas chromatography and mass
spectrometry. We here present 15 receptor neurone types specialised for naturally produced compounds present in the host and
nonhost plants and two types for two aggregation pheromone components. The active compounds were terpenoids, aromatic and
aliphatic esters, alcohols and aldehydes, some of which are induced by feeding activity of the weevils. The neurones were
characterised by a strong response to one or two primary odorants and weaker responses to a few others having similar chemical
structure. With one exception, the molecular receptive range of each neurone type was within one chemical group. Enantiomers
of linalool separated on a chiral column activated two neurone types with different enantioselectivity. Inhibition by linalool
of another neurone type, excited by α-pinene, indicated an additional mechanism for coding the information about this compound.
Altogether, detection of 54 compounds by olfactory receptor neurones is shown, of which 40 have been chemically identified
in this study. Thus A. rubi has the ability to detect a large number of odorants that may be used in host selection behaviour. 相似文献
183.
Sabine?HeimEmail author Jan?Schwarzbauer Ralf?Littke 《Environmental Chemistry Letters》2004,2(1):21-25
Specific anthropogenic substances derived from seepage and leakage water from a waste deposit landfill were analysed in groundwater and drainage effluents using gas chromatography-mass spectrometry (GC/MS). Here, we demonstrate the application of an organic marker approach to study lateral and vertical distribution of contamination as well as the long-term emission behaviour. Source-specific and environmentally-stable pesticides, plasticisers and pharmaceuticals, such as N,N-diethyl toluamide, N-butyl benzene sulfonamide, clofibric acid, mecoprop and bisphenol A, were quantitatively analysed. A distinct lateral expansion was detected. Although temporal variations were high, no significant trend was observed. 相似文献
184.
水溶液中硝基苯的超声微电场降解 总被引:13,自引:0,他引:13
研究了超声微电场中硝基苯的降解过程,并探讨了降解机理及反应历程。结果表明,硝基苯的降解符合拟一级反应,超声与微电场的耦合协同作用大大提高了硝基苯的降解效率,在槽电压10V条件下,协同作用的降解速率比简单加和作用的速率高一倍以上,经过30min协同处理后可以获得93.8%的去除率,而溶液中饱和气体种类等对降民产生一定的影响,经紫外和SMPE-GC-MS分析,推断硝基苯在电超声场作用下存在氧化还原反应与热解、自由基作用等协同作用。主要中间降解产物为苯胺、偶氮苯、1-氧,2-苯基-二氮烯、1,2-苯二甲酸二丁酯、1,2-苯二甲酸丁酯异丁酯等,最终产物为CO2、水及无机盐类。 相似文献
185.
Potential allelopathic effect of Pinus halepensis in the secondary succession: an experimental approach 总被引:1,自引:0,他引:1
Catherine Fernandez Benjamin Lelong Bruno Vila Jean-Philippe Mévy Christine Robles Stéphane Greff Sylvie Dupouyet Anne Bousquet-Mélou 《Chemoecology》2006,16(2):97-105
Summary. Recent economic and social changes in north Mediterranean regions have led to an important rural depopulation. Consequently,
meadows developed on abandoned agricultural lands (characterized by high species richness) undergo reforestation. These former
fields are mainly colonized by Pinus halepensis Miller, which is known to synthetize a wide range of secondary metabolites, among these, some could influence plant succession
through allelopathy. The allelopathic potential of P. halepensis, was tested against two target species (Lactuca sativa L. and Linum strictum L.) with aqueous extracts obtained from different organs (root and needle) taking into account the individual age (±10, ±30
and > 60 years old). Root and needle extracts affected differently germination and growth of the two target species, the responses
varying with concentration of extracts, age and organs tested. The strongest inhibitory effect was observed on the germination
and growth of L. strictum, exposed to needle extracts of young P. halepensis (±10 years old), and root extracts of older P. halepensis (> 30 years old). These extracts contained several phenolic acids (e.g. 4-hydroxybenzoic acid and p-coumaric acid), which are known as allelochemicals and their concentrations vary with age and
organ tested. Hence, P. halepensis could influence secondary succession through the release of potential allelochemicals in the environment by leaf leachates
or root exudates. 相似文献
186.
Summary. Pyrrolizidine alkaloids (PAs) present a model system in the investigation of tritrophic interactions mediated by plant secondary compounds. However, their toxicity for insect herbivores has never been experimentally proven. Here, we demonstrate the toxic effects of a PA on growth and survival of the eri silk moth Philosamia ricini. In a feeding experiment, larvae of this generalist herbivore fed with an artificial PA diet gained weight significantly slower than control animals, and died as pupae. We suggest that derivatives of the ingested PA N-oxide damage developmental functions during metamorphosis. A tracer test with [14C]senecionine N-oxide revealed that the caterpillars lack adaptations that would prevent conversion of the chemical into the pro-toxic free base. In contrast, the PA adapted leaf beetle Longitarsus anchusae accumulates PAs as N-oxides. We tested the purpose of sequestration in this species as defence against predators. Through a series of prey choice experiments with three carabid predator species, chemically non-protected bark beetle pupae were chosen almost uniformly over L. anchusae pupae. In a following choice test with one of these predators, artificially PA-treated mealworm segments deterred the predator from feeding. Overall the study corroborates the immediate toxic effect of PAs on non-adapted herbivores and the protective effect that adapted insects may gain by sequestering them. It thereby underlines the potential for PAs to play a central role in multitrophic interactions between plants, phytophages and their predators. 相似文献
187.
188.
有机化合物的生物降解性能和生物毒性 总被引:6,自引:0,他引:6
有机化合物在环境中的出现是当今世界的重大挑战之一,80年代以来,对于有机化合物在生化处理系统中的归宿和对生物的影响已引起普遍的关注。迄今为止,有关这个课题的研究和资料仍然很少。文章对有机化合物的生物降解性能和生物毒性作一综述,以供同行参考。 相似文献
189.
化学修饰电极在环境微量及痕量有机物分析中的应用 总被引:1,自引:0,他引:1
根据实验研究及国内外文献,从伏安及电位溶出分析,流动注射/液相色谱电化学检测,化学修饰电极生物传感器及化学修饰电极预富集—石墨炉原子吸收法联用等方面,重点综述了化学修饰电极在环境微量及痕量有机物分析中的应用。 相似文献
190.
气溶胶中的水溶性有机物研究进展 总被引:1,自引:0,他引:1
首先指出了对气溶胶中水溶性有机物( WSOC) 研究的意义,接着对气溶胶中水溶性有机物的分子组成、来源和浓度水平进行了介绍,综述了采样和分析方法的历史及其进展,并对当前研究工作中存在的问题和在中国的应用前景进行了评述 相似文献