全文获取类型
收费全文 | 1136篇 |
免费 | 155篇 |
国内免费 | 851篇 |
专业分类
安全科学 | 51篇 |
废物处理 | 48篇 |
环保管理 | 71篇 |
综合类 | 1197篇 |
基础理论 | 246篇 |
污染及防治 | 314篇 |
评价与监测 | 203篇 |
社会与环境 | 12篇 |
出版年
2024年 | 3篇 |
2023年 | 59篇 |
2022年 | 84篇 |
2021年 | 89篇 |
2020年 | 111篇 |
2019年 | 88篇 |
2018年 | 74篇 |
2017年 | 61篇 |
2016年 | 78篇 |
2015年 | 87篇 |
2014年 | 88篇 |
2013年 | 165篇 |
2012年 | 114篇 |
2011年 | 150篇 |
2010年 | 84篇 |
2009年 | 91篇 |
2008年 | 90篇 |
2007年 | 107篇 |
2006年 | 77篇 |
2005年 | 67篇 |
2004年 | 48篇 |
2003年 | 59篇 |
2002年 | 42篇 |
2001年 | 31篇 |
2000年 | 37篇 |
1999年 | 40篇 |
1998年 | 22篇 |
1997年 | 30篇 |
1996年 | 16篇 |
1995年 | 13篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 9篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
排序方式: 共有2142条查询结果,搜索用时 843 毫秒
841.
Mort Webster Junsang Nam Yosuke Kimura Harvey Jeffries William Vizuete David T. Allen 《Atmospheric environment (Oxford, England : 1994)》2007,41(40):9580-9593
Ambient observations have indicated that high concentrations of ozone observed in the Houston/Galveston area are associated with plumes of highly reactive hydrocarbons, mixed with NOx, from industrial facilities. Ambient observations and industrial process data, such as mass flow rates for industrial flares, indicate that the VOCs associated with these industrial emissions can have significant temporal variability. To characterize the effect of this variability in emissions on ozone formation in Houston, data were collected on the temporal variability of industrial emissions or emission surrogates (e.g., mass flow rates to flares). The observed emissions variability was then used to construct regionwide emission inventories with variable industrial emissions, and the impacts of the variability on ozone formation were examined for two types of meteorological conditions, both of which lead to high ozone concentrations in Houston. The air quality simulations indicate that variability in industrial emissions has the potential to cause increases and decreases of 10–52 ppb (13–316%), or more, in ozone concentration. The largest of these differences are restricted to regions of 10–20 km2, but the variability also has the potential to increase regionwide maxima in ozone concentrations by up to 12 ppb. 相似文献
842.
The most abundant volatile organochlorine compounds (VOCCs), trichloroacetic and dichloroacetic acids and AOX, were determined in bleaching effluent and waste water from three kraft pulp mills during ClO2 bleaching. 0.6–7.7 g of VOCCs per ton bleached pulp were formed, the most abundant being chloroform and dichloroacetic acid methyl ester. Most of the VOCCs were removed during treatment, and it was estimated that 2–30 t of VOCCs would be removed annually from activated sludge treatment plants in Finnish kraft pulp mills using elemental chlorine free bleaching, most likely by volatilization. Dichloroacetic acid was formed in considerably higher amounts than trichloroacetic acid, and both compounds were removed effectively during treatment. The formation of all organochlorine compounds decreased considerably when non-chlorinated bleaching was employed. 相似文献
843.
Organic compounds in the flue gas from a power station with circulating fluid bed combustion of coal
Numerous organic compounds have been analyzed by coupled gas chromatography-mass spectroscopy (GC-MS) in flue gas after fluid bed combustion of four coal species from South Africa, Poland, Spitsbergen and Ruhr area (Germany). Polynuclear aromatic hydrocarbons, aliphatic hydrocarbons, chlorinated, heterocyclic and nitro compounds as well as phthalate esters are detected. 相似文献
844.
845.
Marco Tasin Anna-Carin Bäckman Marie Bengtsson Nélia Varela Claudio Ioriatti Peter Witzgall 《Chemoecology》2006,16(2):87-92
Summary. Host plant volatiles which attract insect herbivores for egg-laying are of principal interest with respect to insect ecology
and evolution. Direct applications concern population monitoring and control through behavioural manipulation. Identification
of behaviourally active plant secondary metabolites is essential also for plant breeding for insect resistance. Grapevine
moth females Lobesia botrana are attracted by upwind flight to green grape berries Vitis vinifera. The headspace of grape berries was collected on air filters. A solvent extract of these filters, released from a sprayer,
attracted females in the wind tunnel. The results demonstrate that volatile cues mediate attraction of grapevine moth females
to grape berries, and that headspace collections capture the essence of this odour signal. The air filter extracts were examined
by gas chromatography coupled with electroantennographic detection, and the compounds eliciting a consistent antennal response
in L. botrana females were identified by mass spectrometry. The headspace collection apparatus was calibrated for collection efficiency
of the active compounds. Their recovery rate ranged from 35 % for methyl salicylate to 83 % for (E,E)-α-farnesene. A synthetic ten-component blend was then formulated. The blend consisted of compounds eliciting an antennal
response, formulated in a blend ratio corrected for differences in collection efficiency. Subsequent wind tunnel tests showed
that female attraction to this synthetic ten-component blend was not significantly different from attraction to grape berries,
or to headspace collections of the same berries. At a release rate of 35 ng/h of the most abundant compound (E)-β-caryophyllene,
20 % of the test females approached the source of sprayed headspace collections and the ten-component synthetic blend, respectively.
In comparison, 100 g of green berries, releasing the main compound (E)-β-caryophyllene at a rate of ca. 4.7 ng/h, attracted
10 % of the females by upwind flight followed by source contact. 相似文献
846.
Anne Bousquet-Mélou Sophie Louis Christine Robles Stéphane Greff Sylvie Dupouyet Catherine Fernandez 《Chemoecology》2005,15(4):193-198
Summary. Biological invasions are nowadays a major problem in ecology. Allelopathy has been shown to be involved in such invasions,
but this mechanism has been little studied in France. The objectives of this study were to evaluate the allelopathic potential
of Medicago arborea, an invasive species in the French Mediterranean region. Foliar extracts were tested on three target species (Lactuca sativa, Lepidium sativum and Linum strictum). We showed that Medicago arborea has high allelopathic potential to affect the growth and germination of other species. Yellow flax (Linum strictum), native to the invaded area, was the most sensitive of the tested plant species to foliar extracts of Medicago arborea. Our study pointed out the role of allelopathy in processes leading to biological invasion, and more generally in population
dynamics. 相似文献
847.
在9L、4格室的厌氧折流反应器(ABR)中,处理以葡萄糖为共基质的含硝基苯废水,温度为5~10℃,进水COD浓度为200-400mg/L,HRT为3h。结果表明ABR对有毒废水浓度变化的适应能力强,当进水硝基苯的浓度为0.48mg/L时,出水COD在21天恢复正常,运行稳定,反应器经硝基苯连续3天冲击(0.48mg/L)后,经历了原有微生物死亡、新微生物生长直到最终项级群落和稳定发酵类型的形成的过程。 相似文献
848.
粘土颗粒吸附直接染料的分形特征 总被引:2,自引:0,他引:2
粘土颗粒对直接耐晒黑和直接大红染料的吸附均可分为快速的边缘覆盖和慢速的晶层吸附2个过程,整个吸附过程符合准-二级反应动力学方程式,除了伊利土-直接耐晒黑染料的吸附体系之外,其它体系的吸附过程中以晶层吸附为主的阶段均具有类分形特征.体系的非线性吸附等温线符合Langmuir型吸附等温模式,并且除了蒙脱土吸附直接大红染料之外,也可以用分形Langmuir吸附等温模式获得较好的模拟效果.在不同原始浓度下直接大红染料在粘土颗粒表面发生的边缘覆盖和晶层吸附这2个过程的程度是不同的,从而导致了吸附等温线在原始染料为150mg·L-1时出现最大的吸附量,而且颗粒边缘覆盖的直接大红染料的比例较高.染料进入粘土颗粒的晶层后,扩大了晶层间距,改变了其表面微孔几何结构.颗粒表面棱角变得光滑,结构疏松,片层结构逐渐减少,上述效果在蒙脱土颗粒上或直接耐晒黑染料吸附时表现地更为显著.而且吸附染料后蒙脱土颗粒对N2的吸附量比伊利土下降的幅度小,其比表面积、孔体积和平均孔径的下降比例也比伊利土小,其中平均孔径的差异比较明显.吸附染料之后粘土颗粒表面分形维数Ds均升高了,晶层膨胀和开孔作用抵消了"表面粗糙度屏蔽"、"孔阻塞效应"机理降低Ds的影响.增加了表面粗糙度. 相似文献
849.
Prediction of the environmental fate and aquatic ecological impact
of nitrobenzene in the Songhua River using
the modified AQUATOX model 总被引:5,自引:0,他引:5
An accidental discharge of nitrobenzene happened in November 2005 in the Songhua River,China.The AQUATOX model was modified and adapted to simulate the time-dependent nitrobenzene distribution in this multimedia aquatic system and its potential ecological impacts.Nitrobenzene concentrations in flowing water,sediment,and biota were predicted.Based on the initial concentrations of nitrobenzene observed in the field during the accidental discharge,that is,0.167-1.47 mg/L at different river segments, the pre... 相似文献
850.
WANG Aimin HU Chun QU Jiuhui YANG Min LIU Huijuan RU Ji QI Rong SUN Jingfang 《环境科学学报(英文版)》2008,20(7):787-795
Nitrobenzene (NB) pollution of the Songhua River caused by an explosion at a petrochemical plant in Jilin City,Jilin Province, China,attracted public concern over the fate of NB in the river.As one of the efforts to predict the fate of residual NB in the river,the kinetics and mechanism of phototransformation of NB in natural water from four sections of the Songhua River were investigated.It was found that photodegradation of NB in water proceeded via pseudo-first-order reaction kinetics under simulated ... 相似文献