全文获取类型
收费全文 | 2211篇 |
免费 | 251篇 |
国内免费 | 768篇 |
专业分类
安全科学 | 227篇 |
废物处理 | 92篇 |
环保管理 | 784篇 |
综合类 | 1187篇 |
基础理论 | 342篇 |
污染及防治 | 292篇 |
评价与监测 | 231篇 |
社会与环境 | 45篇 |
灾害及防治 | 30篇 |
出版年
2024年 | 10篇 |
2023年 | 98篇 |
2022年 | 127篇 |
2021年 | 148篇 |
2020年 | 136篇 |
2019年 | 123篇 |
2018年 | 76篇 |
2017年 | 132篇 |
2016年 | 93篇 |
2015年 | 114篇 |
2014年 | 119篇 |
2013年 | 149篇 |
2012年 | 134篇 |
2011年 | 156篇 |
2010年 | 100篇 |
2009年 | 166篇 |
2008年 | 101篇 |
2007年 | 128篇 |
2006年 | 123篇 |
2005年 | 114篇 |
2004年 | 80篇 |
2003年 | 100篇 |
2002年 | 83篇 |
2001年 | 74篇 |
2000年 | 92篇 |
1999年 | 72篇 |
1998年 | 48篇 |
1997年 | 31篇 |
1996年 | 48篇 |
1995年 | 35篇 |
1994年 | 26篇 |
1993年 | 22篇 |
1992年 | 16篇 |
1991年 | 11篇 |
1990年 | 12篇 |
1989年 | 14篇 |
1988年 | 11篇 |
1987年 | 11篇 |
1986年 | 7篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 9篇 |
1980年 | 13篇 |
1979年 | 15篇 |
1978年 | 12篇 |
1977年 | 4篇 |
1974年 | 2篇 |
1970年 | 2篇 |
排序方式: 共有3230条查询结果,搜索用时 31 毫秒
291.
292.
臭氧活性炭工艺中卤乙酸生成潜能与相对分子质量分布关系的研究 总被引:4,自引:0,他引:4
通过臭氧生物活性炭和微曝气生物活性炭(O3/BAC和micro-aeration/BAC)2套工艺研究其对不同相对分子质量有机物去除特点和不同相对分子量有机物生成的卤乙酸及其去除特性.结果表明,O3/BAC工艺对相对分子质量区间>30×103的有机物去除率超过90%.O3/BAC与micro-aeration/BAC出水中,UV254值表示相对分子质量<103的有机物超过50%,相对分子量区间在10×103~30×103的有机物占20%~30%;在O3/BAC和微曝气/BAC工艺出水中,以相对分子质量<103的有机物生成的卤乙酸最多,生成DCAA、TCAA、DBAA分别为97.00、38.55、2.10μg/L和104.00、42.75和2.92μg/L;采用各处理单元不同分子量有机物与氯反应生成的DCAA、TCAA、DBAA和THAAs与相对应的UV254值进行线性拟合,相关系数分别为0.827、0.851 3、0.815 7和0.878.UV254与臭氧生物活性炭处理工艺出水中的卤乙酸生成潜能具有较好的线性关系. 相似文献
293.
Remediation schemes for contaminated sites are often evaluated to assess their potential for source zone reduction of mass, or treatment of the contaminant between the source and a control plane (CP) to achieve regulatory limits. In this study, we utilize a stochastic stream tube model to explain the behavior of breakthrough curves (BTCs) across a CP. At the local scale, mass dissolution at the source is combined with an advection model with first-order decay for the dissolved plume. Field-scale averaging is then employed to account for spatial variation in mass within the source zone, and variation in the velocity field. Under the assumption of instantaneous mass transfer from the source to the moving liquid, semi-analytical expressions for the BTC and temporal moments are developed, followed by derivation of expressions for effective velocity, dispersion, and degradation coefficients using the method of moments. It is found that degradation strongly influences the behavior of moments and the effective parameters. While increased heterogeneity in the velocity field results in increased dispersion, degradation causes the center of mass of the plume to shift to earlier times, and reduces the dispersion of the BTC by lowering the concentrations in the tail. Modified definitions of effective parameters are presented for degrading solutes to account for the normalization constant (zeroth moment) that keeps changing with time or distance to the CP. It is shown that anomalous dispersion can result for high degradation rates combined with wide variation in velocity fluctuations. Implications of model results on estimating cleanup times and fulfillment of regulatory limits are discussed. Relating mass removal at the source to flux reductions past a control plane is confounded by many factors. Increased heterogeneity in velocity fields causes mass fluxes past a control plane to persist, however, aggressive remediation between the source and CP can reduce these fluxes. 相似文献
294.
气温和湿度均为影响臭氧生成的要素,通过分析泸州市国控点数据,找出气温和湿度与臭氧浓度的关系,从而建立气温和湿度为变量的臭氧浓度预测模型.选取2019年泸州市主城区的气温和湿度数据,将气温按日最高温(Tmax)、日最低温(Tmin)和日平均气温(Tmean)划分,将湿度按四季划分,分别统计其与臭氧浓度的相关性.发现臭氧浓... 相似文献
295.
Leakage diagnosis of hydrocarbon pipelines can prevent environmental and financial losses. This work proposes a novel method that not only detects the occurrence of a leakage fault, but also suggests its location and severity. The OLGA software is employed to provide the pipeline inlet pressure and outlet flow rates as the training data for the Fault Detection and Isolation (FDI) system. The FDI system is comprised of a Multi-Layer Perceptron Neural Network (MLPNN) classifier with various feature extraction methods including the statistical techniques, wavelet transform, and a fusion of both methods. Once different leakage scenarios are considered and the preprocessing methods are done, the proposed FDI system is applied to a 20-km pipeline in southern Iran (Goldkari-Binak pipeline) and a promising severity and location detectability (a correct classification rate of 92%) and a low False Alarm Rate (FAR) were achieved. 相似文献
296.
Peng LianXiaodan Gao M. Sam Mannan 《Journal of Loss Prevention in the Process Industries》2012,25(1):103-113
Flammable aerosols have created many fire and explosion hazards in the process industry, but the flammability of aerosols has not been fully understood. The minimum ignition energy has been widely used as an indicator for flammability of combustible mixtures, but the amount of experimental data on the minimum ignition energy of aerosols is very limited. In this work, the minimum ignition energy of tetralin aerosols is predicted using an integrated model. The model applies the flame front propagation theory in aerosol systems to the growth of the flame kernel, which was created during the spark discharge in the ignition process. The aerosol minimum ignition energy was defined as the minimum level of energy in the initial flame kernel to maintain the kernel temperature above the minimum ignition temperature of 1073 K specific for tetralin aerosols during the kernel growth. The minimum ignition energy obtained in the model is influenced by the fuel-air equivalence ratio and the size of the aerosol droplets. For tetralin aerosols of 40 μm diameter, Emin decreases significantly from 0.32 mJ to 4.3 × 10 e−3 mJ when the equivalence ratio rises from 0.57 to 1.0. For tetralin aerosols of 0.57 equivalence ratio, Emin increases from as 0.09 mJ to 0.32 mJ when the droplet diameter rises from 10 μm to 60 μm. The trends are in agreement with previous experimental observations. The method used in current work has the potential to prediction of the minimum ignition energy of aerosol. 相似文献
297.
298.
采用介质阻挡放电联合金属氧化物催化降解气态H2S,考察了单组分及复合金属氧化物催化剂、催化剂与低温等离子体结合方式对H2S及副产物O3去除性能的影响,分析了等离子体联合Mn复合金属氧化物催化降解H2S机理。结果表明,金属负载量相同条件下,电压低于22kV时,Mn复合金属氧化物对H2S的催化活性高于单组分Mn金属氧化物,催化活性及对O3的分解能力从大到小依次为:Ag+Mn、Cu+Mn、Fe+Mn、Mn。当电压为18 kV时,Ag+Mn、Cu+Mn、Fe+Mn复合催化剂分别比单组分Mn催化剂对H2S的去除效率提高了近10%、6%、4%。等离子体后催化区域中Mn催化剂催化氧化H2S的效率明显低于等离子体催化区域。Mn催化剂在等离子体后催化区域中能有效催化分解O3。随着电压的升高,Mn金属氧化物在等离子体后催化区域对H2S催化作用逐渐增强。在电压22 kV时,等离子体联合后催化比单独等离子体作用时,H2S去除效率提高了近11%。 相似文献
299.
300.
Fatih Ilhan Kubra Ulucan-Altuntas Yasar Avsar Ugur Kurt Arslan Saral 《Frontiers of Environmental Science & Engineering》2019,13(5):73