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The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity. 相似文献
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54.
针对厦门"金砖会晤"空气质量保障活动,本研究选取2017年8月10日—9月10日的O3、NO2和挥发性有机物(VOCs),以及气象因子等在线观测数据,开展人为减排、副热带高压、台风等对东南沿海城市大气O3污染特征的影响研究.结果表明,研究期间厦门大气O3-8 h平均浓度为(110.0±40.6)μg·m-3.与管控前相比,无台风影响的管控I期的O3-8 h浓度上升了19.9 μg·m-3,而管控II期的O3-8 h浓度下降了27.9 μg·m-3.对于管控I期和II期,台风影响下O3-8 h浓度较无台风时段分别下降85.2 μg·m-3和8.9 μg·m-3.在排放控制和台风的共同作用下,峰会期间厦门大气O3浓度的日变化显现出"削峰填谷"的特征.另外,与管控I期相比,管控II期O3前体物VOCs浓度显著下降,其臭氧生成潜势(OFP)下降了44.6%.总之,运用区域联防联控策略,对臭氧前体物(NOx和VOCs)实施针对性减排,可有效地降低沿海城市大气O3日间最高浓度. 相似文献
55.
实验研究发现,在碱性环境中臭氧破解污泥的效果下降;将污泥pH调至11,24 h后,MLSS减少率=38.3%、MLVSS减少率=45.1%;通入臭氧18 min后,MLSS减少率=18.3%、MLVSS减少率=27.2%;污泥减量过程中pH呈下降趋势. 相似文献
56.
James R Payne John R Clayton Jr. Bruce E Kirstein 《Spill Science & Technology Bulletin》2003,8(2):201-221
The interactions of physically dispersed oil droplets with suspended particulate material (SPM) can be important for the transport of bulk quantities of spilled crude oil and polycyclic aromatic hydrocarbons (PAH) to subtidal sediments. The literature regarding oil/SPM interactions is reviewed, and results from whole-oil droplet/SPM interaction kinetics and pure-component (Prudhoe Bay crude oil distillate cut) equilibrium partitioning experiments are presented. The effects of oil type, SPM characteristics, and salinity on the interaction rates are examined, and the importance of whole-oil droplet/SPM interactions on particle agglomeration and settling behavior are discussed. Whole-oil droplet/SPM interactions are retarded as oil droplet dispersion into the water column is inhibited by oil viscosity increases due to evaporation weathering and water-in-oil emulsification. Compared to whole oil droplet/SPM interactions, dissolved-component/SPM adsorption is not as significant for transport of individual components to sediments. The information presented in this paper can be used to augment computer-based models designed to predict oil-spill trajectories, oil-weathering behavior, and spilled oil impacts to the marine environment. 相似文献
57.
Jonathan B. Butcher 《Journal of the American Water Resources Association》2003,39(6):1521-1528
ABSTRACT: Most watershed water quality simulation models require the user to specify pollutant buildup and washoff rate parameters for pollutants, by land use. Buildup and washoff rates are difficult to measure directly, and only limited guidance and few observed data are available from the literature. Many studies, however, report storm event mean concentrations (EMCs). These EMCs must arise as a result of the buildup and washoff processes, but typically represent the net contribution from a variety of pervious and impervious surfaces. This paper explores the relationship between EMCs and buildup/washoff parameters. An assumption of the mathematical form of the buildup/washoff relationship gives an algebraic expression for the EMC consistent with model assumptions. This yields techniques to separate observed EMCs into contributions from different land uses and from pervious and impervious surfaces. Given this relationship, numerical optimization may be used to estimate site specific values of buildup and washoff parameters from observed storm EMCs for use in modeling. Use of this approach helps ensure that model parameters are consistent with observed data, providing a rational starting point for final model calibration. Several site examples demonstrate use of the method. 相似文献
58.
John Doherty John M. Johnston 《Journal of the American Water Resources Association》2003,39(2):251-265
ABSTRACT: The use of a fitted parameter watershed model to address water quantity and quality management issues requires that it be calibrated under a wide range of hydrologic conditions. However, rarely does model calibration result in a unique parameter set. Parameter nonuniqueness can lead to predictive nonuniqueness. The extent of model predictive uncertainty should be investigated if management decisions are to be based on model projections. Using models built for four neighboring watersheds in the Neuse River Basin of North Carolina, the application of the automated parameter optimization software PEST in conjunction with the Hydrologic Simulation Program Fortran (HSPF) is demonstrated. Parameter nonuniqueness is illustrated, and a method is presented for calculating many different sets of parameters, all of which acceptably calibrate a watershed model. A regularization methodology is discussed in which models for similar watersheds can be calibrated simultaneously. Using this method, parameter differences between watershed models can be minimized while maintaining fit between model outputs and field observations. In recognition of the fact that parameter nonuniqueness and predictive uncertainty are inherent to the modeling process, PEST's nonlinear predictive analysis functionality is then used to explore the extent of model predictive uncertainty. 相似文献
59.
Frank A. Ward James F. Booker 《Journal of the American Water Resources Association》2003,39(2):427-440
ABSTRACT: The U.S. Endangered Species Act (ESA) restricts federal agencies from carrying out actions that jeopardize the continued existence of any endangered species. The U.S. Supreme Court has emphasized that the language of the ESA and its amendments permits few exceptions to the requirement to give endangered species the highest priority. This paper estimates economic costs associated with one measure for increasing instream flows to meet critical habitat requirements of the endangered Rio Grande silvery minnow. Impacts are derived from an integrated regional model of the hydrology, economics, and institutions of the upper Rio Grande Basin in Colorado, New Mexico, Texas, and Mexico. One proposal for providing minimum streamflows to protect the silvery minnow from extinction would provide guaranteed year round streamflows of at least 50 cubic feet per second in the San Acacia reach of the upper Rio Grande. These added flows can be accomplished through reduced surface diversions by New Mexico water users in dry years when flows would otherwise be reduced below the critical level required by the minnow. Based on a 44‐year simulation of future inflows to the basin, we find that some agricultural users suffer damages, but New Mexico water users as a whole do not incur damages from a policy that reduces stream depletions sufficiently to provide habitat for the minnow. The same policy actually benefits downstream users, producing average annual benefits of over $200,000 per year for west Texas agriculture, and over $1 million for El Paso municipal and industrial water users, respectively. Economic impacts of instream flow deliveries for the minnow are highest in drought years. 相似文献
60.
运用土与结构动力相互作用 (SSI)有限元三维分析软件 SASSI2 0 0 0对一个土与结构动力相互作用体系振动台模型试验进行了模拟计算。对振动台模型试验作了简单的介绍 ,并详细叙述了试验的建模方法。对于试验中的刚性地基和柔性地基条件 ,El- centro波、Taft波和 5 0年超越概率为 10 %的南京人工波等三种地震波输入 ,三个加速度峰值水平 0 .1g、0 .2 g、0 .3g及两个水平向地震波输入的各种组合工况均进行了计算。在数值计算中 ,假设地基土为覆盖于基岩上的半无限粘弹性水平成层土 ,采用等效线性模型考虑土的动力非线性的影响 ;上部结构用三维杆系有限元单元模拟 ,楼板用四结点壳单元模拟 ,每个结点有三个平动自由度和三个转动自由度 ,模型试验中所施加的人工质量均匀分布于壳单元上 ;基础视为平板基础 ,用八结点块体单元模拟 ,每个结点有三个平动自由度。将试验结果与计算结果进行对比较 ,结果表明 :计算所建立的模型较好地模拟了相互作用体系在地震荷载下的反应性状 ,计算结果与试验结果吻合较好 ,SSI效应对结构地震反应有很大影响 相似文献