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大气颗粒物中元素碳的直接测定 总被引:4,自引:1,他引:4
对原来用元素分析仪测定大气颗粒物样品中有机碳、元素碳的方法[1 ] 进行改进 ,将差减法间接测定元素碳改为一步直接测定元素碳。有机碳、元素碳的测量标准偏差的平均值分别为 0 35 %、0 34% ,提高了元素碳的测量精度 ,同时避免了误差传递 ,解决了差减法测定元素碳时出现负值的情况。 相似文献
44.
介绍了广东省地方污染物排放标准中的《水污染物排放限值》和《大气污染物排放限值》的主要特点 ,对今后标准修订提出了建议 相似文献
45.
A positive correlation has been established between increased levels of airborne particulate pollution and adverse health effects, the toxicological mechanisms of which are poorly understood. For toxicologists to unambiguously determine thesemechanisms, truly representative samples of ambient PM10 are required. This presents problems, as PM10 collecting equipment commonly employed, such as the Tapered Element Oscillating Microbalance (TEOM®), heat the inflow toexclude moisture or use fibrous filters, resulting in a PM10sample that may have undergone significant chemical change on thefilter surface or is contaminated by filter fibres. Other systems(i.e. Negretti and Partisol) can successfully collect PM10 without chemical alteration or filter contamination. Comparativecollections from Port Talbot, S. Wales suggest that TEOMs and Negretti/Partisol systems collect different PM10's; the principle difference arising from the TEOM's heating chamber, which precipitates water-soluble ions and volatilises some organic components. This results in both the mass and compositionof the PM10's being altered. Particle size distributionsfor Negretti and Partisol collections highlighted differences mainly attributed to different flow rates. The results of thiswork demonstrate that simple correlations between PM10 massand adverse health effects are problematic. Furthermore, elucidation of the complex fractionation and chemical changes indifferent collectors is necessary. 相似文献
46.
Continuous visibility monitoring has been carried out inKwangju, Korea since May 1999. The total light extinctioncoefficient b
ext measured by a transmissometer andreveals seasonal trends in urban visual air quality,especially under hazy conditions with a visual range of lessthan 15 km. Seasonal atmospheric visibility under lowrelative humidity during the winter was observed to be betterthan during any other seasons. Summertime visibility wasseverely degraded due to highly increased light scattering byhygroscopic particles under high humidity atmosphericconditions. Visibility during spring and fall was alsomoderate. However, yellow sand in spring caused the lowestvisibility conditions over the measurement area for a fewdays. With continuous monitoring using the transmissometer,the daily average seasonal visual range was measured to be13.1, 9.2, 11.0, and 13.9 km in spring, summer, falland winter, respectively. Under the atmospheric humiditycondition less than 60%, visual range was observed tobe 16.1, 13.9, 15.1, and 16.6 km in spring, summer,fall, and winter, respectively. The mean light extinctionbudget by sulfate and nitrate aerosols was determined to bethe highest value of 63.71% during the summer and thelowest value of 27.08% during spring. During the `yellow sand dust' period, a mean light extinction budget by soil particles was estimated to be at an unusually high value of 44.22%. 相似文献
47.
为修复灌区内土壤有机氯农药污染,降低六氯环己烷对土壤环境的危害,对内蒙古某灌域表层土壤进行采样,利用气相色谱测定50个土壤样品中六氯环己烷及其异构体的含量,并利用ArcGIS空间分析技术确定表层土壤中六氯环己烷的分布状况。样本中六氯环己烷的检出率为96%,各样本中六氯环己烷的浓度范围为未检出~23.0 ng/g,平均浓度为4.4 ng/g。4种异构体含量平均值顺序为γ-六氯环己烷>δ-六氯环己烷>β-六氯环己烷>α-六氯环己烷。灌域东北部和西南部残留浓度较高,并由这2个方向向中部地区逐渐递减,表层土壤中的六氯环己烷分布受土壤黏粒量、不同种植种类和灌溉水源的影响较大。虽受人类耕作的影响,但表层土壤中的六氯环己烷污染水平相对较低。 相似文献
48.
Kalra N Jain MC Joshi HC Chaudhary R Kumar S Pathak H Sharma SK Kumar V Kumar R Harit RC Khan SA Hussain MZ 《Environmental monitoring and assessment》2003,87(1):93-109
Field experiments were carried out during 1996–97at Gulawathi, Muthiani and Salarpur Villages, IARI Farm, NewDelhi and NCPP Campus, Dadri to evaluate changes in soilcharacteristics and growth of wheat (Triticum aestivum L.),mustard (Brassica juncea L.), lentil (Lence esculentaMoench.), rice (Oryza sativa L.) and maize (Zea mays L.) byvarying amounts of flyash addition (up to 50t ha-1) in soils atsowing/transplanting time of crops. Flyash addition in areasadjoining NCPP Thermal Power Plant, Dadri, Ghaziabad, U.P.ranged from 5–12 t ha-1 yr-1 in 1995–96. Shoot and root growthand yield of test crops at different locations after flyashincorporation resulted in beneficial effects of flyashaddition in most cases. The silt dominant texture of flyashimproved loamy sand to sandy loam textures of the surfacesoils at the farmers' fields. The increased growth in yield ofcrops with flyash incorporation was possibly due tomodifications in soil moisture retention and transmissioncharacteristics, bulk density, physico-chemical characterssuch as pH and EC and organic carbon content. The response offlyash addition in the soil on soil health and cropproductivity needs to be evaluated on long-term sustainableaspects. 相似文献
49.
SBR法处理中药材有机废水工艺研究 总被引:2,自引:0,他引:2
应用SBR法对中药材有机废水进行了研究。考察了CODCR、BOD5、SS、NH3-H的处理效果,以及PH、水温、污泥负荷等条件对去除率的影响。运行结果表明,PHO 6.0-9.0、t为15-30℃、污沁荷0.3kgBOD5/kgMLSS.d,运行程序:进水0.5h(限制曝气)、曝气10h、脱氮1.5h,沉降0.5h,排水0.5h、闲置11h,周期时间24h时CODCR去除率88%、BOD594%、 相似文献
50.