Load estimates obtained using an approach based on statistical distributions with parameters expressed as a function of covariates (e.g., streamflow) (distribution with covariates hereafter called DC method) were compared to four load estimation methods: (1) flow‐weighted mean concentration; (2) integral regression; (3) segmented regression (the last two with Ferguson's correction factor); and (4) hydrograph separation methods. A total of 25 datasets (from 19 stations) of daily concentrations of total dissolved solids, nutrients, or suspended particulate matter were used. The selected stations represented a wide range of hydrological conditions. Annual flux errors were determined by randomly generating 50 monthly sample series from daily series. Annual and interannual biases and dispersions were evaluated and compared. The impact of sampling frequency was investigated through the generation of bimonthly and weekly surveys. Interannual uncertainty analysis showed that the performance of the DC method was comparable with those of the other methods, except for stations showing high hydrological variability. In this case, the DC method performed better, with annual biases lower than those characterizing the other methods. Results show that the DC method generated the smallest pollutant load errors when considering a monthly sampling frequency for rivers showing high variability in hydrological conditions and contaminant concentrations. 相似文献
The purpose of this paper is to illuminate the spatio-temporal diffusion of rooftop household photovoltaic installations in Germany and to test whether localized imitation drives their adoption. Our study is based on a unique data set of some 576,000 household photovoltaic systems installed in Germany through 2009. We employ an epidemic diffusion model which includes a spatial dimension, and control for temporal and spatial heterogeneity. According to our results, imitative adoption behavior is highly localized and an important factor for the diffusion of household photovoltaic systems. 相似文献
The distribution and transportation of Dissolved and Dispersed Petroleum Hydrocarbon (DDPH) were investigated in the Aegean Sea with the hydrodynamics of the water masses of the region. It is clear that distribution of this pollutant is strongly affected by physical dynamics of environment. The data were collected during cruises in November 1994, in the framework of National Marine Measurement and Monitoring Programme in the Aegean Sea. In the present study additionally the Chlorophyll‐a was measured fluorometrically and there is good correlation between petroleum hydrocarbon and chlorophyll‐a in the Aegean Sea. DDPH data was used to search origin of hydrocarbons: biogenic or non biogenic. 相似文献
The biochemical basis for resistance to metal ion toxicity is emerging though it is complicated by the different resistance mechanisms. Several strategies for resistance to toxic metal ions have been identified:
The development of energy driven efflux pumps which keep toxic element levels low in the interior of the cell. Such mechanisms have been described for Cd(II) and As(V).
Oxidation (e.g. AsO2‐ to AsO43‐) or reduction (e.g. Hg2+ to Hg0) can enzymatically and intracellularly convert a more toxic form of an element to a less toxic form.
The biosynthesis of intracellular polymers which serve as traps for the removal of metal ions from solution such as traps have been described for cadmium, calcium, nickel and copper.
The binding of metal ions to cell surfaces.
The precipitation of insoluble metal complexes (e.g. metal sulfides and metal oxides) at cell surfaces.
Biomethylation and transport through cell‐membranes by diffusion controlled processes.
In this short review I shall discuss the implications of biomethylation as a detoxification mechanism for microorganisms as well as for certain higher organisms. 相似文献
Abstract Reef blocks made from stabilized oil ash were taken from the sea after five years in the ocean to examine the chemical behaviour of calcium. Experiments included (1) determination of the calcium leaching rate and a comparison with the rate for unexposed blocks to test the validity of a diffusion model for predicting long term (5 years) leaching rates, (2) determination of the effect of biological cover (shell) on the leaching rate, (3) determination of the leaching rate of the core of exposed reef blocks, (4) determination of the calcium content in ‘ring areas’ - regions of discoloration observed in sectioned exposed reef blocks, and (5) determination of the leachable fraction of the total calcium in exposed reef blocks. Results showed the presence of a pronounced calcium discontinuity zone located 3–7 cm from the outside surface of the reef blocks. Cumulated calcium release rates ranged from 2.81–3.14 μmol cm?2 day?1 for original unexposed reef blocks and the core of exposed (in the ocean for five years) blocks, respectively, to 0.47–0.50 μmol cm?2 day?1 for outside (facing sea water) surfaces of exposed reef blocks. Tank leaching studies also showed that the presence or absence of hard biological cover (shells) had little or no effect on the calcium release rate. the diffusion model normally used in modelling the chemical behaviour of calcium cannot be used to predict the long term (five years) leaching of calcium. the core of the exposed blocks released calcium at a rate similar to new, unexposed reef block material. Overall, it appears that the calcium discontinuity zone is probably responsible for restricting the release of calcium and hence the failure of the diffusion model. 相似文献