流动注射在线富集原子吸收法测定痕量铅镉

在含铅、镉的试液中加入pH=5.72乙酸-乙酸钠缓冲溶液3.20 mL,泵的转速恒为5 mL/min,用自制的强酸性阳离子交换树脂柱对试液中的铅、镉在线富集150 s,1.50 mol/L HNO3溶液洗脱20 s,火焰原子吸收法测定铅、镉的含量。该方法的线性范围分别是0~80.0μg/L、0~40.0μg/L,检出限分别为3.0μg/L、1.0μg/L,富集倍数分别为40倍、35倍。用该方法测定地表水中铅、镉的含量,结果满意。     

锯齿形翅片对喷管流动及噪声特性的影响分析

喷注噪声理论表明,改变喷口形状会使喷注噪声发生改变.针对发动机排气系统,设计了锥型啧管及锯齿形出口的锥形喷管,建立相应的喷注射流模型,利用数值手段对2种喷管进行啧注流场分析和噪声预测,研究锯齿形翅片对流动和噪声特性带来的影响.     

中国和欧美国家环境影响评价流程对比分析

环境影响评价在环境保护中起着重要的作用,而中国环境影响评价工作起步较晚,环境影响评价的技术方法及导则在实践中不断更新;欧美国家作为环境影响评价工作实施较早的国家,对环境影响评价流程及报告内容作了详细规定,也为中国的环境影响评价工作提供了宝贵经验,为了切实发挥环境影响评价的作用,应根据中国的实际情况,在可行性方案比选、公众咨询及参与、项目实施后监测等方面进行改进。     

基于鱼类保护目标的太子河环境流量研究

环境流量是流域水资源合理配置的基础.因此,本文借鉴FLOWS法,以太子河重要鱼类为保护目标,构建了流量组分与鱼类生态需求关系模型.同时,结合栖息地指标与流量关系曲线,计算了包含基流、脉冲流、平滩流和漫滩流4种组分在内的太子河环境流量.结果表明：太子河本溪、辽阳、唐马寨河段鱼类保护年基流量分别为2.93×108、3.12×108、2.88×108m3;现状径流总体可以满足年基流量的要求,但水文过程需要通过水库调度以匹配鱼类生态过程.推荐的各河段脉冲流、平滩流和漫滩流的量级、频率、历时、出现时间等水文参数,可以体现环境流量组分与自然径流过程的一致性要求.该研究可为太子河流域水库生态调度提供理论依据.     

A review of rapid transport of pesticides from sloping farmland to surface waters:Processes and mitigation strategies

Pesticides applied to sloping farmland may lead to surface water contamination through rapid transport processes as influenced by the complex topography and high spatial variability of soil properties and land use in hilly or mountainous regions. However, the fate of pesticides applied to sloping farmland has not been sufficiently elucidated. This article reviews the current understanding of pesticide transport from sloping farmland to surface water. It examines overland flow and subsurface lateral flow in areas where surface soil is underlain by impervious subsoil or rocks and tile drains. It stresses the importance of quantifying and modeling the contributions of various pathways to rapid pesticide loss at catchment and regional scales. Such models could be used in scenario studies for evaluating the effectiveness of possible mitigation strategies such as constructing vegetated strips, depressions, wetlands and drainage ditches, and implementing good agricultural practices. Field monitoring studies should also be conducted to calibrate and validate the transport models as well as biophysical-economic models, to optimize mitigation measures in areas dominated by sloping farmland.     

Hydrothermal fabrication and visible-light-driven photocatalytic properties of bismuth vanadate with multiple morphologies and/or porous structures for Methyl Orange degradation

Monoclinic BiVO₄ with multiple morphologies and/or porous structures were fabricated using the hydrothermal strategy. The materials were characterized by means of the XRD, Raman, TGA/DSC, SEM, XPS, and UV-Vis techniques. The photocatalytic activities of the BiVO₄ materials were evaluated for the degradation of Methyl Orange under visible-light irradiation. It is observed that pH value and surfactant exerted a great effect on the morphology and pore structure of the BiVO₄ product. Spherical BiVO₄ with porous structures, flower-cluster-like BiVO₄, and flower-bundle-like BiVO₄ were generated hydrothermally at 100℃ with poly(vinyl pyrrolidone) (PVP) and urea (pH = 2) and at 160℃ with NaHCO₃ (pH = 7 and 8), respectively. The PVP-derived BiVO₄ showed much higher surface areas (5.0-8.4 m²/g) and narrower bandgap energies (2.45-2.49 eV). The best photocatalytic performance of the spherical BiVO₄ material with a surface area of 8.4 m²/g was associated with its higher surface area, narrower bandgap energy, higher surface oxygen vacancy density, and unique porous architecture.     

鸡尾山高速远程崩滑碎屑流堆积特征研究

重庆市武隆县铁矿乡鸡尾山于2009年6月5日发生了一起大规模的山体崩滑灾害性事件,约500万m3崩滑物质从高约75m的陡坎沿铁匠沟作高速远程运动,形成了平均厚度约30m、纵向长度约2 500m的堆积区。本文在对鸡尾山山体崩滑堆积区进行大量地质调查的基础上,详细研究了鸡尾山高速远程崩滑碎屑流流动堆积的各向分选特征以及碎屑流的堆积成坝特征,以为该类地质灾害的防治提供依据。     

Flo—mate2000型流速仪快速测量水体流量的探讨

在日常环境监测工作中,测量水体流量变得越来越重要,而一些常用流量计不能满足各种水体的流量测量,使用流速仪法测量水体流速从而计算出流量成为常用手段。以桂林市环境监测中心站所使用的Flo-mate2000型流速仪为例,阐述如何使用流速仪测量并计算出各种排放方式下的水体流量,以及实际工作中经常遇到的一些问题及解决方法。     

寒冷地区人工湿地保温措施及运行方式优化研究

通过对垂直流人工湿地冬季运行保温效果的研究,得出这种湿地类型在冬季没有保温措施的情况下,也不会造成布水管道的冻结,有机物去除率在70%以上;在进行简单保温措施后,处理效果显著提高,有机物去除率普遍在80%以上,说明垂直流人工湿地在西北寒冷地区的应用没有问题。另外,冬季低温运行时可通过优化运行方式提高湿地的除污和抗冻能力。     

不同交通状况下道路边大气颗粒物数浓度粒径分布特征

研究了不同交通状况下北京交通环境大气颗粒物数浓度的污染特征.应用扫描电迁移率颗粒粒径谱仪(SMPS)测定了2009年8月常规交通状况和2008年8月奥运交通状况下北四环道路边大气颗粒物的数浓度,分析了数浓度的粒径分布特征及其逐时变化规律,目的为辨析交通流改变对交通环境中颗粒物数浓度的影响.常规交通状况下道路边超细颗粒物(10～100nm)和10～478 nm颗粒物总粒数浓度分别为(1.15±0.49)×104个.cm-3、(1.61±0.57)×104个.cm-3,奥运交通状况下分别下降到(0.55±0.14)×104个.cm-3、(1.21±0.24)×104个.cm-3,不同粒径段中超细颗粒物数浓度降幅最高,为52.2%.常规交通状况下道路边大气中颗粒物粒数浓度呈双峰分布,峰值粒径依次为22.5 nm和113.0 nm.奥运期间由于机动车单双号限行和黄标车禁行等措施的实施,22.5 nm处颗粒物数浓度峰值消失.粒径分布逐时变化显示,常规交通状况下00:00～04:00柴油车流量高峰、11:00～13:00高温强光照和17:00～20:00交通晚高峰这3个时段内超细颗粒物数浓度较高;而奥运期间受到交通流量下降、平均车速提高等因素影响,道路边颗粒物数浓度粒径分布逐时变化趋于平缓.