城市间运输货车行驶工况构建与应用

为研究城市间运输货车行驶工况特性与典型工况构建方法。运用车载数据采集系统采集了在珠三角区域城市间运输的货运车辆行驶车速等瞬态数据。基于13个工况特征参数解析工况特性,运用运动学片段理论将工况速度数据分成284个工况片,基于主成分分析和聚类分析法将工况片分成5类,选出12片代表工况片,按工况片平均速度从小到大的顺序排列,再将工况时长等比例压缩至1 800 s后最终构建出典型行驶工况。构建工况与实测样本的各项特征参数符合度大于80%,结果表明提出的典型工况构建方法可行,构建工况符合城市间货运车辆实际运行特性。构建工况的最大车速为80 km/h,主要分布在60~80 km/h,C-WTVC工况在0~90 km/h较均匀分布,平均车速为41.0 km/h,较构建工况低15.8%。基于构建工况进行重型货车排放性能仿真测算,得出CO_(2e)排放因子为764.81 g/km,较C-WTVC工况测算值低10.97%,表明运行工况不同导致碳排放测算值有较大差异。     

Synthesis of nickel nanoparticles by chemical and green route and their comparison in respect to biological effect and toxicity

Recent reports demonstrated an increase in the synthesis of nanoparticles (NP) and its applications. The chemical preparation of NP may be harmful. Thus, in this study, the biological activity and toxicology of nickel nanoparticles (NiNP) synthesized through chemical and green routes were compared. Chemical synthesis of NiNP was mediated by polyethylene glycol and hydrazine hydrate as stabilizing and reducing agent, respectively. Desmodium gangeticum aqueous root extract was used to prepare NiNP without any stabilizing and reducing agent. Nickel nanoparticles synthesized by both methods were characterized (ultraviolet–visible spectroscopy, X-ray diffractrometry, Fourier transform infrared spectroscopy, zeta potential and vibrating sample magnetometer) and compared. There was no major significant difference in the nature of the NP prepared by both methods. However, green synthesized NiNP showed reduced size and better monodispersity compared to chemical synthesized one. Free radical scavenging activities and antibacterial activities of NiNP prepared by chemical and green route suggest that these NP, prepared by green route possess reliable antioxidant and antibacterial activity. Evaluation of toxicity in animal and cell line suggests that NiNP synthesized by green route are nontoxic.     

不同劳动强度下人体呼吸参数变化实验研究

人体呼吸参数对呼吸防护装备内部微环境的稳定性至关重要，为获得不同劳动强度下人体呼吸参数及变化规律，以相对心率指数表征劳动强度等级并设计构建呼吸参数采集系统。通过开展多人次不同劳动强度呼吸实验，记录实时瞬时心率、呼吸压力、呼吸频率数据并采集呼出气样本，进行气相色谱分析。研究结果表明:相对心率指数能够消除劳动强度表征中的个体差异及劳动形式差异，对劳动强度具有良好表征作用；呼吸压力及频率随劳动强度增加呈现增强和变大的趋势；心率及呼吸压力信号的样本熵显示，心率稳定性随劳动强度的增加而降低，呼吸模式稳定性则增强；呼出气中O2含量随劳动强度增加而降低，CO2与H2O含量呈现增长趋势，绝对变化量及变化比例随劳动强度不同呈现明显差异。     

基于秀丽隐杆线虫的微量水样环境毒理学研究

目前,环境水样个体水平的毒理学检测成本较高、耗时长,且检测后的水样若处理不当易造成环境的二次污染。通过使用易于培养和观察、个体微小的模式生物—秀丽隐杆线虫作为实验对象,利用毛细玻璃管的虹吸原理将线虫暴露于微量的环境水样进行染毒培养,实现微量水样在个体水平的毒理学评价。为了验证该方法的可行性,检测了暴露组线虫与对照组线虫的生殖腺细胞损伤水平、活性氧自由基(ROS)产生量、氧化应激水平、脱氧核糖核酸(DNA)损伤水平等生物终点的差异性。研究结果有助于为微量环境水样在个体水平的毒理学分析提供一种快速、可行、廉价的评价手段。     

Isolation and Chemical Characterization of Dissolved and Colloidal Organic Matter

An overview of the methods used for the isolation and characterization of organic matter in natural waters is presented. Commonly used techniques for the concentration and isolation of organic matter from water, such as preparative chromatography, ultrafiltration and reverse osmosis, and the methods used to analyze the organic matter obtained by these methods are reviewed. the development of methods to obtain organic matter that is associated with fractions of the dissolved organic carbon other than humic substances, such as organic bases, hydrophilic organic acids and colloidal organic matter are discussed. Methods specifically used to study dissolved organic nitrogen and dissolved organic phosphorous are also discussed.     

Cadmium and chromium in human lung tissue in relation to smoking and lung cancer

The pulmonary Cd and Cr content was determined from 53 lung cancer patients operated for cancer and from 39 patients who died of non‐malignant diseases. The results were correlated with smoking habits, pulmonary emphysema and occupational history. Both the pulmonary Cd and Cr increased with the amount of smoking. In ex‐smokers the Cr content in lung tissue did not diminish with the time since stopping smoking, but the Cd did follow the half‐life of about 9 years. The pulmonary Cd, compared with smoking habits, behaved similarly in both the lung cancer and control patients, whereas Cr in the lung cancer patients could not be explained solely by smoking, but some of the cancer patients may have been occupationally exposed to Cr. Speciation was not studied.     

Seasonal behaviour of lead concentration in poplar leaves∗

Seasonal variation of lead concentration in urban area in poplar leaves, is discussed as part of the more general problem of the interactions of gaseous and nongaseous air pollutants with terrestrial vegetation.     

Predicting species distributions from samples collected along roadsides

Predictive models of species distributions are typically developed with data collected along roads. Roadside sampling may provide a biased (nonrandom) sample; however, it is currently unknown whether roadside sampling limits the accuracy of predictions generated by species distribution models. We tested whether roadside sampling affects the accuracy of predictions generated by species distribution models by using a prospective sampling strategy designed specifically to address this issue. We built models from roadside data and validated model predictions at paired locations on unpaved roads and 200 m away from roads (off road), spatially and temporally independent from the data used for model building. We predicted species distributions of 15 bird species on the basis of point-count data from a landbird monitoring program in Montana and Idaho (U.S.A.). We used hierarchical occupancy models to account for imperfect detection. We expected predictions of species distributions derived from roadside-sampling data would be less accurate when validated with data from off-road sampling than when it was validated with data from roadside sampling and that model accuracy would be differentially affected by whether species were generalists, associated with edges, or associated with interior forest. Model performance measures (kappa, area under the curve of a receiver operating characteristic plot, and true skill statistic) did not differ between model predictions of roadside and off-road distributions of species. Furthermore, performance measures did not differ among edge, generalist, and interior species, despite a difference in vegetation structure along roadsides and off road and that 2 of the 15 species were more likely to occur along roadsides. If the range of environmental gradients is surveyed in roadside-sampling efforts, our results suggest that surveys along unpaved roads can be a valuable, unbiased source of information for species distribution models.     

水质总氮空白实验分析及改进措施

在总氮测定过程中,空白测试是必不可少的分析试验.但在实际操作中,发现空白值经常存在偏高的情况,加大了系统误差.如何降低分析空白实验值,保证分析样品的精密度和准确度,成为测定过程的关键之一.本文从试剂影响、器皿影响、操作过程影响及环境影响等方面全面分析,并以实验数据予以验证.在此基础上提出降低空白值的手段和措施,以指导实验室操作实践.     

环境分析实验室管理样的含量估计及其应用

本文对自制管理样的定值及应用做了描述,样品采自新疆吐鲁番地区红、黄壤土,分析定值采用内检、外检方式,数据经统计检验处理,以多组均值求得总平均值作为元素的含量估计值,用±2S表示测量的单项不确定度.在土壤背景值研究等工作中应用的结果,各元素相对标准偏差(RSD)为:汞、镉大于 10％,铜、铅、锌、镍、氟均小于 10％。