Cesium migration in saturated silica sand and Hanford sediments as impacted by ionic strength

Large amounts of 137Cs have been accidentally released to the subsurface from the Hanford nuclear site in the state of Washington, USA. The cesium-containing liquids varied in ionic strengths, and often had high electrolyte contents, mainly in the form of NaNO3 and NaOH, reaching concentrations up to several moles per liter. In this study, we investigated the effect of ionic strengths on Cs migration through two types of porous media: silica sand and Hanford sediments. Cesium sorption and transport was studied in 1, 10, 100, and 1000 mM NaCl electrolyte solutions at pH 10. Sorption isotherms were constructed from batch equilibrium experiments and the batch-derived sorption parameters were compared with column breakthrough curves. Column transport experiments were analyzed with a two-site equilibrium-nonequilibrium model. Cesium sorption to the silica sand in batch experiments showed a linear sorption isotherm for all ionic strengths, which matched well with the results from the column experiments at 100 and 1000 mM ionic strength; however, the column experiments at 1 and 10 mM ionic strength indicated a nonlinear sorption behavior of Cs to the silica sand. Transport through silica sand occurred under one-site sorption and equilibrium conditions. Cesium sorption to Hanford sediments in both batch and column experiments was best described with a nonlinear Freundlich isotherm. The column experiments indicated that Cs transport in Hanford sediments occurred under two-site equilibrium and nonequilibrium sorption. The effect of ionic strength on Cs transport was much more pronounced in Hanford sediments than in silica sands. Effective retardation factors of Cs during transport through Hanford sediments were reduced by a factor of 10 when the ionic strength increased from 100 to 1000 mM; for silica sand, the effective retardation was reduced by a factor of 10 when ionic strength increased from 1 to 1000 mM. A two order of magnitude change in ionic strength was needed in the silica sand to observe the same change in Cs retardation as in Hanford sediments.     

中国南方某城市自来水厂处理工艺对多环芳烃的去除效果研究

讨论了中国南方某城市自来水厂饮用水中的多环芳烃残留规律以及现有净水工艺对多环芳烃的去除效果。研究结果表明,该自来水厂饮用水中检出多环芳烃以2~4环芳烃为主,强致癌性高环数多环芳烃均在检出限以下,且多环芳烃总量未超出中国供水行业标准(2000年)的相关限值。各处理工艺段中,砂滤过程对多环芳烃的去除效果最好,相较于原水对多环芳烃总量的去除率可达64%。     

基于精细化观测的沙尘通量分布特征

研究沙尘随高度的变化特征对揭示沙尘物质在近地层分布特征具有重要意义。为揭示0—80 m沙尘通量的垂直分布规律,在野外实测的基础上,选取2008年7月20日、8月7日、8月19日、8月29日4次沙尘天气,对贴地层（0—0.05 m）、中间层（0.05—2 m）、近地层（2—80 m）的沙尘通量进行对比分析。结果表明：贴地层（0—0.05 m）,沙尘通量随着高度的增高呈增加趋势,最大值为1604.29 g?mm^?2。中间层（0.05—2 m）,沙尘通量随高度分布的关系为幂函数关系,且随着高度的升高沙尘通量减小,决定系数R²值均在0.9以上。近地层（2—80 m）,沙尘通量随高度增加呈分段函数分布,32 m、48 m处为沙尘通量的拐点高度。由此看出,研究沙尘通量对阐明沙尘输送机制非常重要,不仅可加强对沙尘输送的定量研究,还可为沙尘输送的数值模拟提供重要参数。     

污染河流悬沙与铜、锌污染相关性研究

通过对矿区选矿废水污染的河流水样和悬沙进行采样,分析悬沙、铜、锌质量浓度,探讨河流悬沙与铜、锌之间的相关关系,是有重要现实意义的.研究结果表明:河流水质铜超标严重,丧失了作为农业用水的使用功能.水中铜污染物量与悬沙量相关关系,锌污染物量与悬沙量相关关系都是极显著的.经过曲线回归方程拟合,锌污染物量与悬沙量之间的回归关系比铜污染物量与悬沙量之间的回归关系显著,有3个曲线方程较优,即:对数方程、二次多项式方程、三次多项式方程.据此,通过测定污染河流悬沙量可以粗略地估算水中锌污染物量.     

Experimental investigation on effect of an absorber plate covered by a layer of sand on the efficiency of passive solar air collector

A passive flat-plate solar air collector was constructed in the laboratory of New and Renewable Energy in Arid Zones, Ouargla University, South East Algeria. The absorber of the passive flat-plate solar air collector was laminated with a thin layer of local sand. This acted as a thermal packed bed with a collecting area of 0.5 m² (1 m × 0.5 m). Three series of experiments were performed. The first consisted of choosing the best sand brought from three different places of the Algerian desert. The second consisted of studying the effect of the thickness of the sand layer on the daily efficacy of the collector. The influence of the sand diameter was investigated in the third series. The experimental results showed that: All collectors covered with sand had higher efficiency than those without. It was noticed that, for a fixed mass of sand (given thickness of the sand layer), the improvement of the collector was inversely proportional to the sand particle diameters. The maximum efficiency approximates 62.1% for a particle diameter 0.063 mm, compared to 41.71% for a diameter 0.250 mm.The efficiency of the collector for a fixed particle diameter increases with the increase in the thickness of the sand layer. The collector with thickness sand layer 0.84 mm gave the best efficiency of 46.14% compared to 27.8% for 0.28 mm of thickness sand layer.     

机械活性物质环境条件对产品的影响及对策

介绍了机械活性物质环境条件中的砂尘环境和影响砂尘环境的因素;分析了砂尘环境对产品的主要影响,如造成产品冲蚀和磨损,降低电子产品的性能等;最后提出了对砂尘防护的几点对策.通过分析研究,旨在为相关企业提供理论依据和技术参考,便于在产品生产过程中,注意增强产品对环境的适应性,从而提高产品的质量.     

基于无人机建模的尾矿库溃坝事故推演*

为诠释尾矿库溃坝后水砂演进过程,提升尾矿库事故灾害应急处置能力,采用无人机倾斜摄影技术获取尾矿库全息影像,建立尾矿库三维数字高程模型,导入三维流体计算软件对尾矿库进行溃坝事故推演。结果表明:尾矿库实景三维模型能高精度还原尾矿库实际情况,尾矿库溃坝将淹没库区临时厂房建筑及下游村落;其中,上游沟谷临时厂房建筑水位高程最大达8 m,尾砂淤积厚度最高达10.5 m,下游沟谷村落水位高程最大达10 m,尾砂淤积厚度最高达2.5 m;通过对库区下游布设监测点,得出各监测点处水位高程和尾砂淤积厚度变化规律,分析溃坝主要影响区域。研究结果可为尾矿库风险防控、应急响应工作提供借鉴。     

沙尘天气对北京市空气质量的影响及其预测预报

概述了北京市沙尘天气的分类、特征、判别方法,总结了2000—2002年沙尘天气对北京市空气质量的影响情况,提出了沙尘天气影响空气质量的短期(1～2d)预报方法。利用该方法预报了2002年4次主要沙尘天气过程,预报结果都比较准确。研究发现沙尘天气年际变化主要是受气候条件年际变化影响,提出根据气候条件年际变化预测来进行沙尘天气年际变化预测的初步方法。      

露天矿边坡岩体裂隙测量与卸荷破坏的数值模拟研究*

为探究露天矿不同高度边坡卸荷破坏模式的异同,以辽宁鞍山大孤山铁矿某岩质边坡为背景,利用边坡岩体内优势裂隙组产状、迹长和密度等随机分布参数,构建与边坡结构面具有相似分布规律的二维网络模型,借助PFC数值计算软件,探讨不同开采水平下坡体位移场和裂隙发展的时空演化规律以及边坡的破坏模式。研究结果表明:在边坡开挖过程中,出现的裂隙以张拉裂隙为主;裂隙主要出现在靠近坡面一定范围内,从坡面向里,裂隙数量减小,裂隙初始出现在坡脚区域,而后向坡顶发展;边坡开挖后,水平位移由负变为正,且突然增大,而后呈现阶跃型增长;边坡水平和竖向位移最大值发生在坡脚区域和靠近坡面位置,远离坡面,位移逐渐减小。     

天津市滨海新区地震地质灾害评价与分区研究

收集了天津市滨海新区大量的工程地质勘察资料,针对滨海新区场地工程地质条件,从地震地质背景、历史震害的影响出发,依照相应规范和地质类比等方法,通过滨海新区活动断层影响、砂土液化、软土震陷的评判,探讨了滨海新区在未来强震作用下可能出现的地震地质灾害类型及空间分布特征。