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231.
Di Guardo A Ferrari C Infantino A 《Environmental science and pollution research international》2006,13(1):50-58
- DOI: http://dx.doi.org/10.1065/espr2006.01.009
Background, Aims and Scope Most existing models used to describe the fate of chemicals in surface water and sediment generally consider a 'static scenario',
in which a contaminant is discharged at a constant rate and environmental input parameters do not change during the simulation
time. This approach is not suitable in environmental scenarios characterized by daily or periodic changes of several input
parameters. The aim of this study is to estimate approximate emissions of DDT lo Lake Maggiore using a new surface water model,
(DynA Model) that describes the fate of a chemical in a dynamic scenario.
Methods The model is developed on the grounds of an existing and validated model (QWASI). A numerical solution was adopted to build
the fully dynamic version of the model.
Results and Discussion The model was applied to Lake Maggiore emitting DDT at a constant rate until steady-state was reached. Emissions were stopped
and later sporadic 'pulse' emissions were added. This was done to calculate the amount of DDT needed to simulate concentrations
close to those measured in water and sediments. This allowed the evaluation of the order of magnitude of emissions. An uncertainty
analysis for sediment resuspension was also performed, given the lack of measured resuspension rates.
Conclusion The model showed the time response of the Lake Maggiore system to varying emission scenarios and provided what are regarded
as reasonable estimates of DDT emissions. The model demonstrated the importance of sediment-water exchange.
Recommendation and Outlook In order to better calculate DDT concentrations the model should be run with different discharge scenarios to clarify the
time trends of concentrations, possibly with the use of different sets of measured data (such as biota and sediment deposition/resuspension
rates). 相似文献
232.
Xunhong Chen 《Journal of the American Water Resources Association》2004,40(3):561-573
ABSTRACT: This paper presents hydraulic conductivities of streambeds measured in three rivers in south‐central Nebraska: the Platte, Republican, and Little Blue Rivers. Unlike traditional permeameter tests in streams that determine only the vertical hydraulic conductivity (Kv), the extended permeameter methods used in this study can measure K in both vertical and horizontal as well as oblique directions. As a result, the anisotropy of channel sediments can be determined from streambed tests of similar sediment volumes. Sandy streambeds with occasional silt/clay layers exist in the Republican and Platte Rivers. The average Kv values range from about 15 to 47 m/day for the sandy streambed and about 1.6 m/day for the silt/clay layers. Statistical analyses indicated that the Kv values of sand and gravel in the Platte and Republican Rivers essentially have the same mean; but the Kv values from the Little Blue River have a statistically different mean. Kv is about four times smaller than the horizontal hydraulic conductivity (Kh) for the top 40 cm of sandy streambed. Measured Kh values of the sandy streambed are in the same magnitude as the Kh of the alluvial aquifer determined using pumping tests. The smaller Kv value in the whole aquifer is the result of interbedded layers of silt and clay within the sand and gravel sediments. 相似文献
233.
We studied the concentrations of certain heavy metals in the total and labile fractions of sandy sediments from four embayments situated on the northwestern coast of Spain. In orderto compensate for the effects of the heterogeneity in texture ofthe different samples, data were normalized. Organic carbon was the most suitable normalizing factor for copper, lead and zinc inthe total fraction and copper in the labile fraction, and iron was the most suitable for the other metals in both fractions.Enrichment of copper, lead and zinc in these sediments may have been caused by sewage contamination. The percentages of extractability for chromiun were remarkable. 相似文献
234.
The transformation of nitrate was investigated in diverse stream sediments from six areas of Southern Ontario, Canada. Laboratory Experiments conducted with intact 0-5 cm depth sediment cores overlain with aerated 5 mg/l nitrate-N solution reveald considerable nitrate depletion during a six-day period as a resuit of denitrification and nitrate reduction to ammonium. Nitrification and ammonification also occurred simultaneously with nitrate reduction in many stream sediments. Mixed 0-5 cm depth sediments collected from 81 stream sites were used to examine the relationship between microbial nitrate removal and sediment characteristics. Rates of nitrate-N loss from aerated 5 mg/l nitrate-N solutions overlying these sediments ranged between 11 and 171 mg/m2/day for a 24-hour incubation period. Rates of nitrate loss for the 24-hour period exhibited a significant positive correlation (r=0.72) with sediment ammonium content. Organic carbon, total nitrogen and sediment texture also had significant but weak correlations with nitrate loss. 相似文献
235.
Trace Element Concentrations in Fish, Surficial Sediments and Water from Northern Part of the Persian Gulf 总被引:1,自引:0,他引:1
Concentrations of cadmium, lead, nickel and vanadium were determined in water, surficial sediments and the muscle of three
demersal fish species (Epinephelus coioides, Psettodes erumei and Solea elongate) from 15 sampling sites in the northern part of Persian Gulf. Concentrations of the elements were determined using Inductively
Coupled Plasma Mass Spectrometer. There were no significant differences among the sampling sites in Cd and Pb levels in the
sediments. The highest concentrations of Ni and V in sediments were found near the southern coast of Qeshm Iland and Bandar
Lengeh. Concentrations of Cd, Pb and Ni in the sediments were notably higher than global baseline values. Nearly in all cases
the element concentrations in the sediments were considerably greater than RSA (ROPME Sea Area) and the ERL (Effects Range
Low) guidelines. Significant differences among the sampling sites could be found for concentrations of all the four metals
in water. The mean Ni, Pb and Cd levels in the water samples were relatively higher than those in some other regions of the
Persian Gulf. Except few cases, the mean concentrations of the elements in muscle of the selected fish species were markedly
below the international guidelines for human consumption. 相似文献
236.
东海特定海区沉积物-水界面附近P释放的实验研究 总被引:1,自引:0,他引:1
以采自长江口外东海表层沉积物为对象,对不同类型的沉积物在模拟海水环境中进行了释P实验。研究表明,在静态条件下,沉积物释P量的高点出现在摇晃后10min左右,大约3h后基本趋于平衡。释P动力学可用Elovich公式与双常数速率公式进行拟合。最大释P量与沉积物的组成密切相关,以粉砂、粘土为主的沉积物释P量高,而砂质为主者释P量低。在释P实验中,铁磷(Fe-P)最为活跃,释放比例最高,其次是吸附态磷(Ad-P)和有机态磷(OP)。它们均属于生物可获得P的范畴。实验结果表明,在合适的水动力条件下,沉积物中的P可以迅速释放到水体.并影响水体的营养状杰和初级生产力。 相似文献
237.
为探究高磷背景水库沉积物中有机磷(OP)的空间分布及OP释放动力学特征, 本文采用Ivannoff法对西北口水库沉积物中的OP进行分级提取, 通过沉积物OP释放动力学模拟实验, 探讨了表层沉积物OP的释放特征, 以及沉积物理化性质对其响应.结果表明, 西北口水库沉积物OP含量为210.3~455.2mg/kg, 平均含量为322.9mg/kg, 占总磷(TP)的18.3%.OP含量空间分布呈现库中(363.2mg/kg)>库首(339.3mg/kg)>库尾(266.1mg/kg)的变化规律, 垂向上随深度的增加而减小.西北口水库不同形态OP的含量表现为: 非活性有机磷(NOP)>中活性有机磷(MLOP)>活性有机磷(LOP), 其中NOP含量占OP的65.3%, 是西北口水库沉积物OP的主要存在形式.准一级动力学模型是描述西北口水库库首、库中和库尾沉积物OP释放动力学曲线的最优方程(R2=0.98~0.99, P < 0.01), 在0~1h表征为快速释放过程, 所释放的OP含量占最大释放量(Qmax)的55.68%~79.55%, 随后进入慢速释放过程, 逐渐达到Qmax, Qmax在1.4~3.1mg/kg之间.该水库沉积物中LOP和MLOP是主要向上覆水体释放的磷形态. 相似文献
238.
This study investigated particle size and density distributions of polycyclic aromatic hydrocarbons (PAHs) in two surface sediments (JZ and KF), collected from the Yellow River of Henan section, China. The concentrations of Σ15PAHs ranged from 35.6 to 45862?ng g?1 dry wt, which were greatly elevated in coarse particles and low-density fractions. The Σ15PAHs concentrations in low-density fractions were 533 (JZ) and 996 (KF) times higher than those in the corresponding high-density fractions. However, due to relatively less quantities of low-density fractions (0.27–2.33%), most of the PAHs were contributed by the high-density components. For both sediments, the influence factors of PAHs source in the environment were very complex, more so than the level of TOC and BC content. JZ sediment was dominated by 4-ring to 6-ring PAHs (61.5–75.1%), while, 2-ring to 3-ring PAHs were abundant in KF samples (39.8–72.6%). Ratios of specific PAHs reflected PAHs among the size- and density-fraction of each sediment may be contaminated by mixed of pyrolytic and petrogenic origin. Additionally, ecological risk assessment of PAHs suggested that total toxic equivalent values of PAHs in the low-density fractions were much higher than those of the corresponding high-density fractions in the studied area. 相似文献
239.
An international workshop held in the spring of 2002 convened a group of technical experts to address monitoring, modeling,
and management of PCBs within the Detroit River-Western Lake Erie basin. Participants shared and discussed a diverse set of
research data bases pertaining to PCB levels within the region, discussed observed changes within different components of
the local ecosystem, and identified several primary issues impacting future PCB management strategies. Results presented at
the workshop indicate dramatic reductions in PCB contamination levels have been observed in much of study area between the
late 1970s and mid-1990s. Estimates of loadings attributable to water and atmospheric sources have generally declined, as
have PCB concentrations in herring gull eggs, smelt and walleye. Nevertheless, additional improvements have not been observed
during recent years and elevated contamination levels remain a concern within local hot spots, particularly in the lower Detroit
River and Trenton Channel. A primary recommendation broadly supported by workshop participants is the need to maintain, support,
and coordinate a comprehensive ecosystem monitoring program for the Detroit River-Western Lake Erie basin, one that incorporates
both near-field and far-field monitoring elements. Such a program is crucial to provide necessary data in support of understanding
ecosystem trends, calculating annual mass loadings to the system, assessing impacts of remediation actions, developing improved
modeling frameworks, and formulating cost-effective management strategies for the future. 相似文献
240.
Heavy metal contamination in surface sediments of Yangtze River intertidal zone: An assessment from different indexes 总被引:4,自引:0,他引:4
Weiguo Zhang Jinna Chang Hongxia Xie 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1533-1543
Surface sediments (0-5 cm) from 59 stations within the Yangtze River intertidal zone (YRIZ) were sampled for metal contamination analysis in April and August 2005. The concentrations ranged (in mg kg−1 dry weight): Al, 40,803-97,213; Fe, 20,538-49,627; Cd, 0.12-0.75; Cr, 36.9-173; Cu, 6.87-49.7; Mn, 413-1,112; Ni, 17.6-48.0; Pb, 18.3-44.1; and Zn, 47.6-154; respectively. Among the 59 sampling stations, enrichment factors (EF) indicate enrichment of Cd (52 stations), Cr (54 stations), Cu (5 stations), Ni (26 stations), Pb (5 stations) and Zn (5 stations). Geoaccumulation indexes (Igeo) also suggest individual metal contamination in localized areas. This study indicates that Cd, Cr and Ni enrichment in the YRIZ sediment is widespread whereas Cu, Mn, Pb and Zn enrichment is localized or nonexistent. Factor and cluster analyses indicate that Cd is associated with total organic carbon whereas Cu, Cr, Ni, Pb and Zn have a close association with Mn. 相似文献